CAS: 13701-67-2; Diboron Tetrachloride
- 英文名称Diboron Tetrachloride
- 中文名称1,1,2,2-四氯-二硼烷
- 其它别名Boron chloride(B2Cl4) (6CI,8CI); Diborane(4), tetrachloro- (9CI); Diborane tetrachloride; Diboron tetrachloride; Tetrachlorodiborane; Tetrachlorodiborane(4)
- CAS编号13701-67-2
- FDA UNII编号:3KKJ90L3I5
- 分子式:B2Cl4分子量:0.0
- 产品CID: 577052
- 产品分类无机化合物 → 混合金属/非金属化合物 → 类金属盐
- 相似结构搜索
- 产品信息参考
- InChIKey: LCWVIHDXYOFGEG-UHFFFAOYSA-N
- 1S/B2Cl4/c3-1(4)2(5)6
- 计算化学: 氢键受体数*氢键供体数0.0可旋转键数0.0
物理性质
MSDS等安全信息
合成工艺路线路线简述
- 合成目标产物 Dichloroborane 主要起始原料 Hydrogen And Boron Trichloride
- (文献来源)合成步骤主要原料 Hydrogen 和 Boron Trichloride
📜三氯化硼置于cu体系中,用 Neat (No Solvent,Gas Phase) 用作溶剂,化学反应生成1,1,2,2-四氯-二硼烷
参考文献:卤化多面体磷化硼烷的合成.Closo-1,7-P2B10Cl10的晶体结构.
标题:卤化多面体磷化硼烷的合成.Closo-1,7-P2B10Cl10的晶体结构.
摘要:在400oc以上的温度下,B2Cl4与pcl3的热解反应以低收率制备了12个顶点的closo-Phosphaborane 1,7-P2B10Cl10(1).单晶x射线结构测定为1(单斜空间) P2(1)/ N组的a = 9.239(2)a,B = 16.786(3)a,C = 15.739(3)a,Beta = 93.25(3)度,Z = 4)确认与磷硼烷具有26个骨架电子数,采用扭曲的二十面体结构,磷原子位于1,7位.1晶体包含以1:1摩尔比嵌入相邻簇分子的每个p原子之间的甲苯.热解条件的改变导致形成了磷酸化的磷硼烷p4B8Cl6(2)和p2B8Cl8(3).用pcl3和ascl3的混合物在450oc下对b2Cl4的共水解生成六顶点的asaphosphaborane Aspb4Cl4(4)和痕量二十面体的asaphosphaborane Aspb10Cl10.这些化合物是在单个分子中包含两个不同的15族原子的杂硼烷的实例.
Doi:10.1021/ic990112V
专利信息
专利号:US-3772389-A
优先权日:1971-06-24
标 题:Process for the synthesis of phenyl esters
发明人：LOWRANCE W
权利人:EASTMAN KODAK CO
摘要:A PROCESS FOR THE SYNTHESIS OF PHENYL ESTERS DIRECTLY FROM THE CORRESPONDING PHENOLS AND CARBOXYLIC ACIDS WHICH COMPRISES CONTACTING A PHENOLIC COMPOUND HAVING AT LEAST ONE HYDROGEN ATOM ADJACENT THE ACTIVE HYDROXYL GROUP WITH A CARBOXYLIC ACID COMPOUND CONTAINING AT LEAST ONE ACTIVE CARBOXYLIC GROUP IN THE PRESENCE OF A CATALYTIC AMOUNT OF A BORATE-SULFURIC ACID CATALYST COMPLEX. THE PROCESS IS CARRIED OUT IN A SINGLE STAGE REACTOR WHICH MAY BE OPERATED AT FROM 75*C. TO 285*C. UNDER ATMOSPHERIC, SUBATMOSPHERIC OR SUPERATMOSPHERIC PRESSURE. IF DESIRABLE, A SOLVENT CAN BE EMPLOYED.
专利号:WO-2025124974-A1
优先权日:2023-12-11
标题:Synthesis of fumed nanostructured lithium borate powder
发明人：TAKATA Ryo; SCHMIDT FRANZ; SCHÄFER DURDU; WIEGAND ARMIN; HEINDL NICO; KANEEDA MASANOBU; ESKEN DANIEL; HERZOG MARCEL; KANNO RYOJI; NOMOTO KUNIHARU
权利人:EVONIK OPERATIONS GMBH
摘要:A method for making fumed lithium borate, the method comprising: preparing a solution of a lithium precursor, preferably a lithium carboxylate containing 5 to 20 carbon atoms, and a boron source, preferably an organic boron compound, feeding the solution to a flame burning in a flame reaction zone to produce a fumed product comprising fumed lithium borate particles; and obtaining the fumed product.
专利号:CN-115109257-B
优先权日:2022-07-21
标 题 :Synthesis method of high molecular weight linear polyborosilazane precursor
