CAS: 103068-20-8; 5'-Bromo-1,1':3',1''-Terphenyl

相似化合物

95962-62-2 83909-22-2 98905-03-4

上下游产品

CAS号626-39-1 1,3,5-三溴苯 | CAS号98-80-6 苯硼酸 | CAS号108-86-1 溴苯 | CAS号21521-51-7 2,4,6-三溴碘苯 | CAS号100-58-3 苯基溴化镁 | CAS号24388-23-6 苯硼酸频呐醇酯 | CAS号147-82-0 2,4,6-三溴苯胺 | CAS号10346-08-4 3,5-diphenyl-2-... | CAS号28023-86-1 3,5-diphenylphenol | CAS号63006-66-6 [1,1':3',1''-te... | CAS号128388-54-5 [1,1'：3',1''-三联... | CAS号561068-06-2 tris(3,5-diphen...

2,4,6-三溴苯胺置于盐酸,Sodium Nitrite体系中,用 四氢呋喃,水 用作溶剂,化学反应 2.5H,反应生成1-溴-3,5二苯基苯
参考文献:A Practical And Efficient Synthesis Of 5'-Substituted M-Terphenyls
标题:A Practical And Efficient Synthesis Of 5'-Substituted M-Terphenyls
摘要:下面概述了一种简单,便捷,可扩展的合成方法,用于从市售原料制备多种5'-取代的m-三联苯化合物.基于m-三联苯骨架,生成了一系列新颖化合物.此外,我们还提供了3,5-二苯基苯甲醛(1,1':3',1''-三联苯-5'-甲醛)的全面完整表征,包括晶体结构.
Doi:10.1055/s-2007-983722

专利信息

专利号:WO-2024185814-A1
优先权日:2023-03-06
标题:Method for producing aryl compound containing tritylsulfanyl group
发明人：OKAZOE TAKASHI; NOZAKI KYOKO; GATZENMEIER Tim; LIU YUE
权利人:AGC INC; UNIV TOKYO
摘要:The present invention provides: a substrate for achieving the highly efficient synthesis of an aryl compound containing a tritylsulfanyl group; a method for producing a compound containing an SF 5 group using the substrate; and others. The present invention is a method for producing an aryl compound containing a tritylsulfanyl group, the method comprising thiotritylating a halogenated aryl compound represented by general formula (1) [wherein A 1 represents an aryl group that may have a substituent or a heteroaryl group that may have a substituent; and X represents a halogen atom] using [(triphenylmethyl)sulfanyl]potassium or [(triphenylmethyl)sulfanyl]sodium to produce an aryl compound containing a tritylsulfanyl group, the aryl compound being represented by general formula (2) [wherein A 1 is the same as A 1 in general formula (1); and Ph represents a phenyl group].

专利号:CN-115340503-B
优先权日:2022-04-15
标题 :Synthesis method and application of chiral semicorrinoid compound