CAS: 90770-88-0; [2,2'-Bipyridine]-4,4'-Diol
该化合物是一种有机化合物,其特征为双丙烯结构,由碳-碳联系连接的两只环组成,其特征为二丙烯框架4和4位置的羟基(-OH)组,有助于极地溶剂中的溶解性并提高其氢联结潜力.它一般在室温中看上去是固体,可能根据纯度和形态表现出各种颜色. 氢丙烯基组的存在还表明,它可能参与各种化学反应,包括氧化和与金属离子的复合,使其对化学和材料科学的协调感兴趣.此外,其结构特征可能带来具体的生物活动,尽管对任何此类特性都要进行详细研究.
- 英文名称[2,2'-Bipyridine]-4,4'-Diol
- 中文名称[2,2'-联吡啶]-4,4'-二醇
- IUPAC名称[2,2'-bipyridine]-4,4'-diol
- 其它别名2,2'-联吡啶]-4,4'-二醇; 4,4'-Dihydroxy-2,2'-Bipyridine
- CAS编号90770-88-0
- MFCD编号:MFCD08704189
- 分子式:C10H8N2O2分子量:188.19
- 产品CID: 1941308
- 产品分类有机原料→材料科学→MOF有机配体→MOF有机框架配体砌块
相似化合物
17217-57-1 2326-78-5 36145-03-6物理性质
MSDS等安全信息
上下游产品
CAS号17217-57-1 4,4'-二甲氧基-2,2'-联吡啶 | CAS号17228-69-2 2-氯-4-甲氧基吡啶 | CAS号18511-71-2 4,4'-二溴-2,2'-联吡啶合成工艺路线路线简述
- 17217-57-1 = 90770-88-0
反应条件:1.1 Acidified
标题:Bipyridine Based Metallogels: An Unprecedented Difference In Photochemical And Chemical Reduction In The In Situ Nanoparticle Formation
作者:Tatikonda,Rajendhraprasad; Bertula,Kia; Nonappa; Hietala,Sami; Rissanen,Kari; Et Al
参考文献:Dalton Transactions 日期:2017 卷标:46(9) 页码:2793-2802]
17217-57-1 = 90770-88-0
反应条件:1.1 Reagents: Hydrogen Bromide Solvents: Acetic Acid,Water; 120 °C
标题:Luminescent Gold Surfaces For Sensing And Imaging: Patterning Of Transition Metal Probes
作者:Adams,Samuel J.; Lewis,David J.; Preece,Jon A.; Pikramenou,Zoe
参考文献:Acs Applied Materials & Interfaces 日期:2014 卷标:6(14) 页码:11598-11608]
17217-57-1 = 90770-88-0
反应条件:1.1 Reagents: Hydrogen Bromide Solvents: Acetic Acid; 72 H,Reflux
标题:New Ternary Bipyridine-Terpyridine Copper(Ii) Complexes As Self-Activating Chemical Nucleases
作者:Gama,Sofia; Rodrigues,Ines; Marques,Fernanda; Palma,Elisa; Correia,Isabel; Et Al
参考文献:Rsc Advances 日期:2014 卷标:4(106) 页码:61363-61377]
17217-57-1 = 90770-88-0
反应条件:1.1 Reagents: Acetic Acid,Hydrogen Bromide Solvents: Water; 47 H,Reflux; Reflux -> Rt1.2 Reagents: Ammonium Hydroxide Solvents: Water; Basified
标题:Aqueous Reductive Amination Using A Dendritic Metal Catalyst In A Dialysis Bag
作者:Willemsen,Jorgen S.; Van Hest,Jan C. M.; Rutjes,Floris P. J. T.
参考文献:Beilstein Journal Of Organic Chemistry 日期:2013 卷标:9 页码:960-965]
17217-57-1 = 90770-88-0
反应条件:1.1 Reagents: Hydrogen Iodide; 9 H,Reflux; Reflux -> Rt1.2 Reagents: Ammonia Solvents: Water; Ph 13
标题:High-Effective Synthesis Of 2,2'-Bipyridinyl-4,4'-Diol
作者:Zhang,Xinyu; Tang,Hongying; Zhang,Zhongbiao
参考文献:Tianjin Shifan Daxue Xuebao 日期:2011 卷标:31(4) 页码:92-94]
17217-57-1 = 90770-88-0
反应条件:1.1 Reagents: Hydrogen Bromide Solvents: Acetic Acid,Water; Overnight,Reflux1.2 Reagents: Ammonium Hydroxide Solvents: Water; Neutralized,Rt
标题:Synthetic Approaches To An Isostructural Series Of Redox-Active,Metal Tris(Bipyridine) Core Dendrimers
作者:Hong,Young-Rae; Gorman,Christopher B.
参考文献:Journal Of Organic Chemistry 日期:2003 卷标:68(23) 页码:9019-9025]
17217-57-1 = 90770-88-0
反应条件:1.1 Reagents: Acetic Acid,Hydrogen Bromide Solvents: Water; Overnight,Reflux; Reflux -> Rt1.2 Reagents: Ammonium Hydroxide Solvents: Water; Ph 6 - 7
标题:Hydroxyl And Amino Functionalized Cyclometalated Ir(Iii) Complexes: Synthesis,Characterization And Cytotoxicity Studies
作者:Wu,Zhaozhen; Mu,Juanjuan; Wang,Qiong; Chen,Xing; Jensen,Lasse; Et Al
参考文献:Journal Of Organometallic Chemistry 日期:2015 卷标:791 页码:175-182]
17217-57-1 = 90770-88-0
反应条件:1.1 Reagents: Hydrogen Bromide Solvents: Acetic Acid,Water; Rt; 15 H,Reflux1.2 Reagents: Ammonium Hydroxide Solvents: Water; Neutralized,Rt
标题:Synthesis Of Phosphonic Acid Derivatized Bipyridine Ligands And Their Ruthenium Complexes
作者:Norris,Michael R.; Concepcion,Javier J.; Glasson,Christopher R. K.; Fang,Zhen; Lapides,Alexander M.; Et Al
参考文献:Inorganic Chemistry 日期:2013 卷标:52(21) 页码:12492-12501]
17217-57-1 = 90770-88-0
反应条件:1.1 Reagents: Hydrogen Bromide Solvents: Acetic Acid; 10 H
标题:Ruthenium(Ii) Complex-Based Fluorescent Sensor For Peroxynitrite
作者:Ma,Jingjin; Wu,Jiasheng; Liu,Weimin; Wang,Pengfei; Fan,Zhiyuan
参考文献:Spectrochimica Acta 日期:2012 卷标:94 页码:340-345
📜2,2'-联吡啶置于sodium Dihydrogenphosphate,四丁基溴化铵,Sodium Molybdate,Potassium Ferrate(Vi)体系中,用 水,异丙醇 作为反应溶剂,化学反应 8.33H,以99.1%的收率获得产物4,4'-二羟基-2,2'-联吡啶
参考文献:一种4,4'-二羟基-2,2'-联吡啶的合成方法
标题:一种4,4'-二羟基-2,2'-联吡啶的合成方法
摘要:一种4,4'‑二羟基‑2,2'‑联吡啶的合成方法,包括以下步骤:1)将2,2'‑联吡啶加入到有机溶剂与水的混合溶剂中混合,加入磷酸二氢盐和表面活性剂于30~35oc下搅拌20~35Min;2)加入高铁酸盐和钼酸钠的混合物a,通入保护气,将体系温度升至50~60°C,反应5~8H;3)反应液冷却,分离提纯得到产物4,4'‑二羟基‑2,2'‑联吡啶.采用本发明时,反应步骤较短,为一步反应,操作简单,产率高,工艺成本低;且后处理简单,水污染少.
海关参考信息
- 2933310010-吡啶
2905199090-其他饱和一元醇
2939800000-其他生物碱
2905590090-其他无环醇的卤化衍生物 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-9527066-B2
优先权日:2011-08-30
标题 :Dihydroxybipyridine complexes of ruthenium and iridium for water oxidation and hydrogenation
发明人：PAPISH ELIZABETH T; NIETO ISMAEL
权利人:PAPISH ELIZABETH T; NIETO ISMAEL; UNIV ALABAMA
摘要:The present invention discloses a class of organometallic catalysts for both hydrogenation and water oxidation. The synthesis and the use of these catalysts for hydrogenation, hydrogen production and water oxidation reactions is also disclosed.
专利号:US-2003198960-A1
优先权日:2002-04-01
标 题 :Signal amplifying targeted reporters for biological and chemical sensor applications
发明人：FAN WENHONG; LI JUN; HAN JIE
摘要:The present invention provides targeted dendrimeric reporter molecules that provide amplified signals at electrochemical sensors, and methods of synthesis and methods of use thereof. The reporter molecules comprise a targeting moiety and at least one dendritic signal amplifier; the dendritic amplifier comprises a plurality of dendritic branches and a plurality of indicator moieties, typically pendant therefrom. The targeting moiety serves to concentrate the dendritic amplifier at a selected target, where the plural indicator provide increased signals.
专利号:CN-103421486-B
优先权日:2012-05-22
标题 :A kind of fluorescent probe and its synthesis method and application
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📌 第三方产品分析报告
合成参考文献
摘要:Wu, X.; Xiao, J., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 262.
参考文献:10.1007/s41061-017-0107-x
摘要:Dong K, Razzaq R, Hu Y, Ding K. Homogeneous Reduction of Carbon Dioxide with Hydrogen. Top Curr Chem (Cham). 2017 Apr;375(2):23. doi: 10.1007/s41061-017-0107-x.
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