CAS: 75996-29-1; 5-Fluorobenzene-1,3-Diol

上下游产品

3,5-dimethoxyfluorobenzene ethyl 3,5-dimethoxybenzoate 3,5-Dihydroxybenzoic acid 3,5-dimethoxybenzamide 6H3(OP(C(CH3)3)2)2FC6H3(OP(C(CH3)3)2)2

📜1,3-二甲氧基-5-氟苯置于三溴化硼体系中,用 二氯甲烷 作为反应溶剂,化学反应 48.0H,以87.5%的收率获得产物5-氟间苯二酚
参考文献:Ferroelectric And Antiferroelectric "banana Phases" Of New Fluorinated Five-Ring Bent-Core Mesogens
标题:Ferroelectric And Antiferroelectric "banana Phases" Of New Fluorinated Five-Ring Bent-Core Mesogens
摘要:提出了两种具有横向氟取代基的同源非手性五环介晶,这些取代基分别位于核心和外环上.这两种化合物都表现出两种b5相和b2相.高温b5相具有反铁电基态.低温b5相被发现是铁电的,这一点通过双稳态开关得到证实.介晶相的分配和表征基于xrd测量,1H-,19F-,13C-NMR和电光测量.
DOI:10.1039/b111421B

专利信息

专利号:US-6229055-B1
优先权日:1996-04-12
标题 :Synthesis of fluorinated xanthene derivatives
发明人：KLAUBERT DIETER H; GEE KYLE R
权利人:MOLECULAR PROBES INC
摘要:Facile syntheses for fluorinated resorcinol and aminophenol derivatives are provided that yield isomer-free products in good yield. These novel methods use generally available precursors and standard laboratory reagents and equipment to reproducibly produce these synthetically useful reagents in relatively large quantities. The resulting fluorinated resorcinols and aniinophenols possess utility in the preparation of fluorinated fluorescein and rhodol dyes.