CAS: 532-65-0; (S)-2-Methyl-6-(P-Tolyl)Hept-2-En-4-One

上下游产品

(S)-4-(4-methylphenyl)pentan-2-one sodium ethanolate acetone (2)H6]acetone[(2)H6]acetoneS)-ar-turmerone semicarbazone(S)-ar-turmerone semicarbazone (+)-(S)-dihydro-ar-turmerone (+)-(S)-dihydro-ar-curcumene (S)-4-(4-methylphenyl)pentan-2-one

📜P-Methyl-Zimtaldehyd置于四丙基高钌酸铵,Copper(II) Bis(Trifluoromethanesulfonate),N-甲基吗啉氧化物,三苯基膦体系中,用 四氢呋喃,二氯甲烷,甲苯 作为反应溶剂,化学反应 15.0H,反应生成 芳姜黄酮,来源于姜黄
参考文献:过渡金属和氨基催化相结合的α,β-不饱和醛的催化对映选择性β-烷基化:杂没药烷倍半萜的全合成
标题:过渡金属和氨基催化相结合的α,β-不饱和醛的催化对映选择性β-烷基化:杂没药烷倍半萜的全合成
摘要:分支出!通过简单的手性胺和铜催化剂的组合,α,β-不饱和醛的第一个共催化对映选择性(可达98:2 Er)的β-烷基化可在单反应釜协议中提供β-支化醛(参见方案).该方法适用于短波半萜倍半萜烯(S)-(+)-姜黄素,(e)-(S)-(+)-3-脱氢姜黄素和(S)-(+)-肿瘤酮的短总合成.
DOI:10.1002/chem.201100756

专利信息

专利号:US-2010316631-A1
优先权日:2006-10-19
标题 :Water Soluble Curcumin-Based Compounds
发明人：SAFAVY AHMAD
权利人:UAB RESEARCH FOUNDATION
摘要:The present disclosure describes the design and synthesis of a novel class of water soluble curcumin-based compounds. These water soluble curcumin-based compounds are shown to provide superior cell killing activity and exhibit increased and cell internalization solubility in aqueous solutions as compared to the free (unconjugated) curcumin. The present disclosure provides compositions for the treatment or prevention of a variety of disease states or conditions, such as but not limited to, cancer, other cell hyperproliferative disorders and chronic inflammatory conditions, said compositions comprising a water soluble curcumin-based compound.

专利号:CN-103787855-B
优先权日:2014-01-17
标题:A New Method for the Synthesis of (S)-Aromatic Curcumones by Asymmetric Catalysis

专利号:CN-103787855-A
优先权日:2014-01-17
标题 :A New Method for the Synthesis of (S)-Aromatic Curcumones by Asymmetric Catalysis