CAS: 41744-39-2; (2R,3R)-2-(3,4-Dimethoxyphenyl)-7-Methoxy-3-Methyl-5-((E)-Prop-1-En-1-yl)-2,3-Dihydrobenzofuran
- 英文名称(2R,3R)-2-(3,4-Dimethoxyphenyl)-7-Methoxy-3-Methyl-5-((E)-Prop-1-En-1-yl)-2,3-Dihydrobenzofuran
- 中文名称粗毛淫羊藿苷
- IUPAC名称(2R,3R)-2-(3,4-dimethoxyphenyl)-7-methoxy-3-methyl-5-((E)-prop-1-en-1-yl)-2,3-dihydrobenzofuran
- 其它别名(2R)-2β-(3,4-Dimethoxyphenyl)-2,3-Dihydro-7-Methoxy-3α-Methyl-5-[(E)-1-Propenyl]Benzofuran; Benzofuran, 2-(3,4-Dimethoxyphenyl)-2,3-Dihydro-7-Methoxy-3-Methyl-5-(1E)-1-Propen-1-Yl-, (2R,3R)-; (2R,3R)-2-(3,4-Dimethoxyphenyl)-7-Methoxy-3-Methyl-5-[(E)-Prop-1-Enyl]-2,3-Dihydro-1-Benzofuran; (+)-Acuminatin
- CAS编号41744-39-2
- MFCD编号:MFCD20274968
- FDA UNII编号:JA2WFP75V2
- 分子式:C21H24O4分子量:340.42
- 产品CID: 1431414
- 产品分类天然产物 → 木脂素
物理性质
- 沸点438.4±45.0 °C(预测)
- 闪点119 °C
- 密度1.109±0.06 g/cm3(预测)
- PSA:36.92
- LogP:4.9827
- 折射率1.569
- 蒸汽压1.78E-07 mmHg at 25 °C
- 溶解性Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
- 外观形态结晶
- 储存条件Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
- 产品应用该化合物用作加强和骨头,消除风潮,并净化肾脏,加强阳;表现出药理效应,包括免疫化,心血管和肾循环改善,促进核酸新陈代谢,抗癌活动以及冠状血流增加.
MSDS等安全信息
上下游产品
-1-propene(E)-1-(2RS,3SR)-2,3-dihydro-2-(4-hydroxy-3-methoxyphenyl)-7-methoxy-3-methyl-1-benzofuran-5-yl-1-propene dimethyl sulfate (+/-)-carinatol (E)-propenyl-tri-n-butylstannane 2-[2-(3,4-dimethoxy-phenyl)-1-methyl-ethyl]-6-methoxy-4-propyl-phenol合成工艺路线路线简述
📜(-)-Menthoxyacetyldehydrodi-Isoeugenol置于sodium Hydroxide体系中,用 1,4-二氧六环,乙醇 作为反应溶剂,化学反应 5.0H,反应生成 粗毛淫羊藿苷
参考文献:Optical Resolution Of (+/-)-Dehydrodiisoeugenol: Structure Revision Of Acuminatin
标题:Optical Resolution Of (+/-)-Dehydrodiisoeugenol: Structure Revision Of Acuminatin
摘要:
DOI:10.1016/s0031-9422(00)82431-0
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2902500000-苯乙烯
2902600000-乙苯 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Tsai IL, Chen JH, Duh CY, Chen IS. Cytotoxic neolignans and butanolides from Machilus obovatifolia. Planta Med. 2001 Aug;67(6):559-61. doi: 10.1055/s-2001-16480.
129:36-44. doi: 10.1016/j.phytochem.2016.07.004. Epub 2016 Jul 21. 27(5):397-400. Chinese. 52(9):1163-9. doi: 10.1211/0022357001774949. 67(10):3242-8. doi: 10.1021/jo010857u. 72(8):1529-32. doi: 10.1021/np900203y. 27(7):1147-50. doi: 10.1248/bpb.27.1147. 27(10):1043-7. doi: 10.1007/BF02975429. 54(2):359-75. doi: 10.1111/famp.12105. Epub 2014 Oct 6.
10: Barros LF, Ehrenfried CA, Riva D, Barison A, de Mello-Silva R, Stefanello ME. Essential oil and other constituents from Magnolia ovata fruit. Nat Prod Commun. 2012 Oct;7(10):1365-7. 28(5):370-3. Chinese. 38(5):661-5. 38(12):1942-6. Chinese.
合成参考文献
参考文献:10.1021/jo010857u
摘要:Roy SC, Rana KK, Guin C. Short and stereoselective total synthesis of furano lignans (+/-)-dihydrosesamin, (+/-)-lariciresinol dimethyl ether, (+/-)-acuminatin methyl ether, (+/-)-sanshodiol methyl ether, (+/-)-lariciresinol, (+/-)-acuminatin, and (+/-)-lariciresinol monomethyl ether and furofuran lignans (+/-)-sesamin, (+/-)-eudesmin, (+/-)-piperitol methyl ether, (+/-)-pinoresinol, (+/-)-piperitol, and (+/-)-pinoresinol monomethyl ether by radical cyclization of epoxides using a transition-metal radical source. J Org Chem. 2002 May 17;67(10):3242–8. doi: 10.1021/jo010857u.
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