📜Phenylmagnesium Bromide 反应生成烯丙基三苯基硅烷 参考文献:Selective Reactions Of The Silicon-Hydrogen Group With Grignard Reagents. The Preparation Of Some Unsymmetrical Silane Derivatives 标题:Selective Reactions Of The Silicon-Hydrogen Group With Grignard Reagents. The Preparation Of Some Unsymmetrical Silane Derivatives 摘要: Doi:10.1021/ja01531A021
专利号:US-11767388-B1 优先权日:2019-09-18 标 题 :Silicon-functionalized rubber 发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING 权利人:GOODYEAR TIRE & RUBBER 摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.
专利号:US-6787601-B2 优先权日:2001-03-26 标题 :Polymer synthesis 发明人:LAMOLA ANGELO A; BLANKENSHIP ROBERT M 权利人:SHIPLEY CO LLC 摘要:Disclosed is a method of preparing emulsion polymers and a method of preparing porous dielectric materials using the emulsion polymers.
专利号:US-6903175-B2 优先权日:2001-03-26 标 题 :Polymer synthesis and films therefrom 发明人:GORE ROBERT H; GALLAGHER MICHAEL K; YOU YUJIAN 权利人:SHIPLEY CO LLC 摘要:Disclosed are methods of preparing solution polymers and compositions derived therefrom.
专利号:CN-109836047-B 优先权日:2018-12-26 标 题 :Organosilicon-rare earth derivative, synthesis method thereof and application of organosilicon-rare earth derivative in preparation of rare earth doped optical fiber
专利号:CN-109836047-A 优先权日:2018-12-26 标 题:Organosilicon-rare earth derivatives, synthesis method and application of rare earth doped optical fibers
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