CAS: 16326-32-2; (6Z,9Z,12Z)-Methyl Octadeca-6,9,12-Trienoate

该化合物是通过对γ-林丹甲基化获得的脂肪酸衍生物,一种聚酰胺-聚饱脂肪酸,该化合物广泛用于生化研究,制药应用和作为专门脂质合成的前体,其高纯度和浓度的酯型稳定性增强了其适合分析标准和脂代谢研究.GLA甲基酯因其在调查反炎和免疫聚合物途径方面的作用而特别受到重视.甲基酯的改变提高了有机溶剂的溶解性,便于其在染色学和光谱分析中的使用.其明确界定的结构确保了实验和工业应用中的再生性.

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506-26-3 112-63-0 301-00-8

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CAS号30964-00-2 6-Hept炔酸 | CAS号2067-33-6 5-溴戊酸 | CAS号56909-02-5 6-Heptynoic aci... | CAS号209860-40-2 methyl 11-bromo... | CAS号67-56-1 甲醇 | CAS号186581-53-3 重氮甲烷 | CAS号506-26-3 γ-亚麻酸 | CAS号4184-93-4 °Ctadeca-6,9,12... | CAS号506-26-3 γ-亚麻酸

合成工艺路线路线简述

    📜5-溴戊酸置于p-2 Ni Copper(L) Iodide,四溴化碳,氨,氢气,Potassium Carbonate,乙二胺,三苯基膦,Sodium Iodide体系中,用 乙醇,二氯甲烷,N,N-二甲基甲酰胺 用作溶剂,化学反应 13.0H,反应生成R-亚麻酸甲酯
    参考文献:A Large Scale And Concise Synthesis Of γ-Linolenic Acid From 4-Chlorobut-2-Yn-1-Ol
    标题:A Large Scale And Concise Synthesis Of γ-Linolenic Acid From 4-Chlorobut-2-Yn-1-Ol
    摘要:
    Doi:10.1055/s-1998-2104

    海关参考信息

    专利信息


    专利号:US-5959175-A
    优先权日:1997-04-09
    标题 :Sunflower albumin 5' regulatory region for the modification of plant seed lipid composition
    发明人：THOMAS TERRY L; NUNBERG ANDREW N; BEREMAND PHILLIP D
    摘要:The present invention is directed to 5' regulatory regions of a sunflower albumin gene. The 5' regulatory regions, when operably linked to either the coding sequence of a heterologous gene or a sequence complementary to a native plant gene direct expression of the coding sequence or complementary sequence in a plant seed. The regulatory regions are useful in expression cassettes and expression vectors for the transformation of plants. n Also provided are methods of modulating the levels of a heterologous gene or native plant gene such as a fatty acid synthesis or lipid metabolism gene by transforming a plant with the subject expression cassettes and expression vectors.

    专利号:US-5605929-A
    优先权日:1992-05-27
    标题:Methods and compositions for inhibiting 5α-reductase activity
    发明人：LIAO SHUTSUNG; LIANG TEHMING
    权利人:ARCH DEV CORP
    摘要:Disclosed are a novel class of antiandrogenic compounds including saturated and unsaturated fatty acids, catechin gallates, their derivatives, and synthetic analogs, their method of synthesis, and their use in treating disorders associated with androgenic activities. Also disclosed is the use of known compounds not previously known for their antiandrogenic activity in treating disorders related to androgenic activities and cancers.

    专利号:CN-109879905-A
    优先权日:2019-02-18
    标题 :A kind of preparation method of naphthyl sulphonic acids base modified SBA-15 and in synthesis rich in the application in unsaturated fatty acid structure phosphatide

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    主要参考文献

    [参考文献]: Hiyamuta, Et Al. Melanoma Cell Proliferation Inhibitors Containing γ-Linolenic Acid Or Its Derivatives: Japan, Jp2014141427[参考文献]: 2014-08-07.
    [参考文献]: Jubie S, Et Al. Isolation Of Methyl Gamma Linolenate From Spirulina Platensis Using Flash Chromatography And Its Apoptosis Inducing Effect. Bmc Complement Altern Med. 2015 Aug 4;15:263.
    [参考文献]: Segarnick Dj, Et Al. Gamma-Linolenic Acid Inhibits The Development Of The Ethanol-Induced Fatty Liver. Prostaglandins Leukot Med. 1985 Mar;17(3):277-82.
    [参考文献]: Williams, Et Al. Antithrombosis Agent Containing γ-Linolenic Acid Or A Functional Derivative Of It: Federal Republic Of Germany, De2749492[参考文献]: 1978-05-11.
    [参考文献]: Xiuqin K, Et Al. Studies On The Hypolipidemic Effects Of Gamma-Linolenic Acid Methyl Ester Derived From Spirulina Maxima[参考文献]: Zhongguo Hai Yang Yao Wu= Chinese Journal Of Marine Drugs, 2003, 22(6): 30-34.

    合成参考文献


    参考文献:10.1007/s11746-013-2372-3
    摘要:Guil‐Guerrero JL, Gómez‐Mercado F, Ramos‐Bueno RP, Rincón‐Cervera MÁ, Venegas‐Venegas E. Restricted‐Range Boraginaceae Species Constitute Potential Sources of Valuable Fatty Acids. J Americ Oil Chem Soc. 2013 Oct 25;91(2):301–8. doi: 10.1007/s11746-013-2372-3.
    参考文献:10.1007/bf02533508
    摘要:Sinclair AJ, McLean JG, Monger EA. Metabolism of linoleic acid in the cat. Lipids. 1979 Nov;14(11):932–6. doi: 10.1007/bf02533508.
    参考文献:10.1007/s12649-024-02603-3
    摘要:Alprol AE, Thabet WM, Khedawy M, Essam HM, Ashour M. The Revolutionary Applications of Seaweed Liquid Extract (TAM®): A Multi-Purpose Solution for Antimicrobial Activity and Phytoremediation. Waste Biomass Valor. 2024 Jun 14;15(11):6367–83. doi: 10.1007/s12649-024-02603-3.
    参考文献:10.1007/s12161-024-02652-3
    摘要:Wenming C, Yuyang Z, Tingting W, Tong L, Guolong Y. Determination of Free Fatty Acids in Foodstuff by Solid Phase Extraction and Gas Chromatography-Flame Ionization Detection Using H2SO4-MeOH Derivatization. Food Anal. Methods. 2024 Jul 19;17(10):1446–54. doi: 10.1007/s12161-024-02652-3.
    参考文献:10.1007/s42690-024-01311-8
    摘要:Yadav DS, Bhoyar ES, Shabeer T.P. A, Ajabe SS, Pardeshi AR. Characterization of fatty acid composition in wax produced by grapevine mealybug, Maconellicoccus hirsutus (Green). Int J Trop Insect Sci. 2024 Aug 06;44(4):2169–76. doi: 10.1007/s42690-024-01311-8.
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