📜对溴戊基联苯置于盐酸,正丁基锂体系中,用 乙醚,水 用作溶剂,化学反应 2.0H,反应生成4-戊基联苯硼酸
参考文献:Synthesis Of Cyclic Compounds Consisting Of Face-To-Face P-Oligophenyls
标题:Synthesis Of Cyclic Compounds Consisting Of Face-To-Face P-Oligophenyls
摘要:Facile Synthesis Of Xanthene-Based Pi-Stacked Compounds Consisting Of Face-To-Face P-Oligophenyls Has Been Described. Just By Mixing Xanthene-4,5-Diboronic Acid And P-Oligophenyls Containing A Benzenetetraol Unit Yielded Cyclic Compounds Selectively Due To The Reversibility Of The Boronate Esterification. In The Ground State,Weak Pi-Pi Interactions Between Two P-Oligophenyl Moieties Were Observed,Whereas Their Pi-Pi Interactions Were Clearly Shown In The Excited State. (C) 2014 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Tetlet.2014.01.093