CAS: 11113-63-6; Difluorine--Methane (1/1)

该化合物是石墨通过氟化过程产生的一种化学化合物,其特征是其层结构,类似于石墨结构,但氟原子取代了岩层中的一些碳原子.这种替代对石墨氟具有独特的特性,包括化学稳定性提高,与母体材料相比,电绝缘增强.石墨氟化物通常非导体性,具有高热稳定性,适合各种用途,包括润滑剂和氟化材料的生产.此外,该化合物在电池和其他氟化化合物的前体中具有潜在用途.该化合物一般在环境条件下稳定,但可以与强氧化剂发生反应.其独特的特性来自碳框架与氟化亚化物的相互作用,影响其再活性和物理特性.

结构式图片

合成工艺路线路线简述

    专利信息


    专利号:US-2007144897-A1
    优先权日:2003-03-31
    标 题:Method for the electrolytic synthesis of peracetic acid and sterilizing-cleaning method and apparatus
    发明人:OHSAKA TAKEO; SAHA MADHU S; UNO MASAHARU; NISHIKI YOSHINORI; FURUTA TSUNETO
    权利人:PERMELEC ELECTRODE LTD
    摘要:Simple and economic electrolytic synthesis of peracetic acid is performed, and cold drink containers, etc., are sterilized/cleaned with an aqueous solution of peracetic acid thus obtained. Peracetic acid is electrolytically synthesized from acetic acid and/or acetate and an oxygen-containing gas as starting materials in the presence of a solid acid catalyst in an electrolytic cell. An object to be cleaned is sterilized/cleaned with an aqueous solution of peracetic acid thus obtained. Peracetic acid can be simply obtained at a reduced cost. The sterilizing/cleaning of an object to be cleaned with peracetic acid can be conducted efficiently.

    专利号:US-4886921-A
    优先权日:1988-04-18
    标题 :Synthesis of carbon fluoride and carbon fluoride chloride
    发明人:NALEWAJEK DAVID
    权利人:ALLIED SIGNAL INC
    摘要:An improved synthesis of carbon fluoride CFx, and carbon fluoride chloride, (CyFxClz)n, is described. Direct fluorination of the intermediate (CyFxClz)n (x/=1) or (CyFxClz)n (x>/=0.9, y=1, z
    专利号:US-7070757-B2
    优先权日:2000-10-02
    标 题:Method for producing catalysts consisting of metal of the platinum group by means of electroless deposition and the use thereof for the direct synthesis of hydrogen peroxide
    发明人:FISCHER MARTIN; BUTZ THOMAS
    权利人:BASF AG
    摘要:Catalysts produced by electroless deposition of at least one platinum metal on a nonporous nonmetallic support can be used for the synthesis of hydrogen peroxide from the elements and for the hydrogenation of organic compounds.

    专利号:US-11518780-B2
    优先权日:2019-07-31
    标 题:Sensitive oligonucleotide synthesis using sulfur-based functions as protecting groups and linkers
    发明人:FANG SHIYUE
    权利人:FANG SHIYUE
    摘要:Embodiments for the synthesis of sensitive oligonucleotides as well as insensitive oligonucleotides are provided. Sulfur-based groups are used for the protection of exo-amino groups of nucleobases, phosphate groups and 2′—OH groups, and as cleavable linker for linking oligonucleotides to a support. Oligonucleotide syntheses are achieved under typical conditions using phosphoramidite chemistry with important modifications. To prevent replacing sulfur-based protecting groups by acyl groups via cap-exchange, special capping agents are used. To retain hydrophobic tag to assist RP HPLC purification, special phosphoramidites are used in the last synthetic cycle. With the sulfur-based groups for protection and linking, oligonucleotide deprotection and cleavage are achieved via oxidation followed by beta-elimination under mild conditions. Therefore, besides for insensitive oligonucleotide synthesis, the embodiments of the invention are capable for the synthesis of oligonucleotide analogs containing sensitive functional groups that cannot survive the harsh conditions used in prior art oligonucleotide synthesis technologies.

    专利号:WO-2024224841-A1
    优先权日:2023-04-27
    标 题 :Method for manufacturing anode for fluorine gas electrolytic synthesis
    发明人:FUKUCHI Yohsuke; TO KATSUAKI; KOBAYASHI HIROSHI; OGURO Shinya
    权利人:RESONAC CORP
    摘要:Provided is a method for manufacturing an anode in which an anode effect does not easily occur, even if used when electrolyzing an electrolytic solution containing hydrogen fluoride and a metal fluoride to electrolytically synthesize fluorine gas. The method for manufacturing an anode for electrolytic synthesis of fluorine gas comprises a positive polarization treatment step. In the positive polarization treatment step, an anode base material having a carbon material is immersed as an anode (21) in a mixed liquid (10) for anode production, the mixed liquid (10) containing hydrogen fluoride, a metal fluoride, and potassium hexafluoronickelate(IV) together with immersing a cathode (22) therein, a current is passed between the anode (21) and the cathode (22) to subject the anode base material to a positive polarization treatment, and nickel fluoride is caused to adhere to the surface of the anode base material.

    专利号:US-10465033-B2
    优先权日:2016-11-10
    标题:One step synthesis of ultrahigh molecular weight block copolymers
    发明人:URBAN MAREK W
    权利人:UNIV CLEMSON; UNIV CLEMSON RES FOUNDATION
    摘要:Single-step synthesis processes for production of ultrahigh molecular weight block copolymers are described. The ultrahigh molecular weight copolymers can have a molecular weight of about 10 6 or greater and can be formed within a few hours in a surfactant-free environment. The formation process is controlled by initiator-starvation conditions in a sequential polymerization of monomers exhibiting different solubility in the solvent.
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    合成参考文献


    摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.
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