CAS: 901-44-0; Ethanol, 2,2'-[(1-Methylethylidene)Bis(4,1-Phenyleneoxy)]Bis-

该化合物是一种高纯度化学化合物,通常用作聚合物,树脂和特殊涂层合成的中间体,其主要优点包括:由于存在氢氧基组,具有极好的回活动性,使聚氨酯和环氧制剂能够高效地交叉连接;该化合物具有良好的热稳定性,与各种工业溶剂相容,适合需要耐用和高性能材料的应用;其定义明确的分子结构确保聚合工艺取得一致的结果;此外,它作为生产粘合剂,弹性体和阻燃材料的多用途建筑块,有助于提高最终产品的机械和化学抗药性.

英文名称Ethanol, 2,2'-[(1-Methylethylidene)Bis(4,1-Phenyleneoxy)]Bis-
中文名称4,4-异丙亚基(2-苯氧乙醇)
IUPAC名称2,2'-((propane-2,2-diylbis(4,1-phenylene))bis(oxy))bis(ethan-1-ol)
其它别名2,2’-[(1-Methylethylidene)Bis(4,1-Phenyleneoxy)]Bis-Ethano; 2,2’-[(1-Methylethylidene)Bis(4,1-Phenyleneoxy)]Bis-Ethanol; 2,2’-[isopropylidenebis(P-Phenyleneoxy)]Diethanol; 4,4'-Bis-(Hydroxyethoxy)Diphenyldimethylmethane; Ethanol,2,2’-[(1-Methylethylidene)Bis(4,1-Phenyleneoxy)]Bis-; 2-[4-[1-[4-(2-Hydroxyethoxy)Phenyl]-1-Methyl-Ethyl]Phenoxy]Ethanol; 2-[4-[2-[4-(2-Hydroxyethoxy)Phenyl]Propan-2-Yl]Phenoxy]Ethanol; 1,1'-Isopropylidenebis(P-Phenyleneoxy-2-Ethanol)
CAS编号901-44-0
MFCD编号:MFCD00084808
EINECS号:212-985-6
分子式:C19H24O4分子量:316.4
产品CID: 1933194
产品分类有机原料 → 醇、酚、酚醇类化合物及衍生物

相似结构搜索
产品信息参考;;
InChIKey: UUAGPGQUHZVJBQ-UHFFFAOYSA-N
InChI=1S/C19H24O4/c1-19(2,15-3-7-17(8-4-15)22-13-11-20)16-5-9-18(10-6-16)23-14-12-21/h3-10,20-21H,11-14H2,1-2H3
计算化学: 氢键受体数4.0氢键供体数2.0可旋转键数8.0

MSDS等安全信息

GHS象形图
GHS符号GHS09;
注释: Environment
危险类别水生慢性毒性类别2
特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
水生慢性毒性类别3
警示词Warning
危险描述H411 |对水生生物有毒并具有长期持续影响.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H412 |对水生生物有害并具有长期持续影响.
防范说明P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

合成工艺路线路线简述

107-21-1 + 80-05-7 + 463-79-6 = 901-44-0
反应条件:1.1 Catalysts: Sodium Carbonate; 20 Min,180 °C1.2 Reagents: Urea Catalysts: Zinc Oxide (Zno); 2 H,180 °C; 180 °C -> Rt
标题:Novel Chemical Recycling Of Polycarbonate (Pc) Waste Into Bis-Hydroxyalkyl Ethers Of Bisphenol A For Use As Pu Raw Materials
作者:Lin,Chao-Hsing; Lin,Hsing-Yo; Liao,Wei-Zhi; Dai,Shenghong A.
参考文献:Huaxue 日期:2007 卷标:65(4) 页码:367-376]

96-49-1 + 80-05-7 = 901-44-0
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylacetamide; Rt -> 140 °C; 5 H,140 °C
标题:Mechanically Robust,Creep-Resistant,Intrinsic Antibacterial And Reprocessable Dynamic Polyurethane Networks Based On Azine Moieties
作者:Han,Jinshi; Zhou,Yawei; Bai,Guanghang; Wei,Wei; Liu,Xiaoya; Et Al
参考文献:Materials Chemistry Frontiers 日期:2022 卷标:6(4) 页码:503-511]

107-21-1 + 80-05-7 = 901-44-0
反应条件:1.1 Reagents: Urea Catalysts: Sodium Carbonate,Zinc Oxide (Zno); Rt -> 120 °C; 120 °C -> 190 °C; 4 - 6 H,170 - 190 °C; 190 °C -> 50 °C
标题:One-Pot Alkoxylation Of Phenols With Urea And 1,2-Glycols
作者:Lin,Hsing-Yo; Dai,Shenghong A.
参考文献:Journal Of The Chinese Chemical Society (Taipei 日期:2010 卷标:57(2) 页码:167-173]

107-21-1 + 80-05-7 = 901-44-0
反应条件:1.1 Reagents: Potassium Iodide; 1 H,80 - 120 °C; 120 °C -> 170 °C; 5 H,170 °C
标题:Synthesis And Characterization Of Poly(Ether Carbonate)S By Melt-Phase Interchange Reactions Of Dihydroxy Compounds With Alkylene And Arylene Diphenyl Dicarbonates Containing Ether Groups
作者:Al-Qalawi,Hussam R.; Sweileh,Bassam A.; Kailani,Mohammad H.
参考文献:Journal Of Applied Polymer Science 日期:2012 卷标:126(5) 页码:1650-1663]

96-49-1 + 80-05-7 = 901-44-0
反应条件:1.1 Catalysts: Triphenylphosphine,Dibutyltin Oxide; 4 H,180 °C
标题:A Nonphosgene Process For Bisphenol-A Polycarbonate With Ethylene Units And Characterization Of The Polymer
作者:Xun,Hongdi; Wang,Xiaomei; Wang,Jiaxi
参考文献:Gaofenzi Xuebao 日期:2010 卷标:(11) 页码:1276-1282]

96-49-1 + 80-05-7 = 901-44-0
反应条件:1.1 8 H,150 °C
标题:Oligoesters On The Basis Of Hydroxyethylated Derivatives Of 4,4'-(Propan-2,2-Diyl)Diphenol
作者:Paserb,M. A.; Bakirova,I. N.
参考文献:Russian Journal Of General Chemistry 日期:2014 卷标:84(6) 页码:1091-1094]

96-49-1 + 24936-68-3 = 901-44-0
反应条件:1.1 Catalysts: Potassium Carbonate; 1 H,200 °C; 200 °C -> 100 °C1.2 Reagents: Sodium Hydroxide Solvents: Methanol; 1 H,100 °C; 100 °C -> 25 °C1.3 Reagents: Hydrochloric Acid Solvents: Methanol; 25 °C
标题:Chemical Recycling Of Post-Consumer Compact Discs Towards Novel Polymers For Powder Coating Applications
作者:Gioia,Claudio; Vannini,Micaela; Celli,Annamaria; Colonna,Martino; Minesso,Alessandro
参考文献:Rsc Advances 日期:2016 卷标:6(37) 页码:31462-31469]

96-49-1 + 24936-68-3 = 901-44-0
反应条件:1.1 Reagents: Sodium Phenoxide; Rt -> 250 °C; 250 °C -> Rt1.2 Reagents: Potassium Hydroxide Solvents: Water; 3 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Water; Neutralized
标题:Sustainable Polycarbonates From A Citric Acid-Based Rigid Diol And Recycled Bpa-Pc: From Synthesis To Properties
作者:Pang,Chengcai; Jiang,Xueshuang; Yu,Yan; Liu,Xiaohan; Lian,Jingyan; Et Al
参考文献:Acs Sustainable Chemistry & Engineering 日期:2018 卷标:6(12) 页码:17059-17067]

96-49-1 + 80-05-7 = 901-44-0
反应条件:1.1 Catalysts: Tetrabutylammonium Bromide; 5 H,150 °C
标题:Synthesis And Characterization Of Low Viscosity Dimethacrylic Resin Based On Isosorbide
作者:Lukaszczyk,Jan; Janicki,Bartosz; Kozuch,Justyna; Wojdyla,Henryk
参考文献:Journal Of Applied Polymer Science 日期:2013 卷标:130(4) 页码:2514-2522]

96-49-1 + 80-05-7 = 901-44-0
反应条件:1.1 Catalysts: Sodium Carbonate; 2 H,165 - 170 °C
标题:Dynamic Enamine-One Bond Based Vitrimer Via Amino-Yne Click Reaction
作者:Guo,Xinru; Gao,Fei; Chen,Fengbiao; Zhong,Jiang; Shen,Liang; Et Al
参考文献:Acs Macro Letters 日期:2021 卷标:10(10) 页码:1186-1190]

96-49-1 + 80-05-7 = 901-44-0
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 3 H,145 °C
标题:Exploring Thiol-Yne Based Monomers As Low Cytotoxic Building Blocks For Radical Photopolymerization
作者:Oesterreicher,Andreas; Ayalur-Karunakaran,Santhosh; Moser,Andreas; Mostegel,Florian H.; Edler,Matthias; Et Al
参考文献:Journal Of Polymer Science 日期:2016 卷标:54(21) 页码:3484-3494

📜碳酸乙烯酯,双酚a置于四乙基碘化铵体系中,化学反应生成双酚-A聚氧乙烯醚
参考文献:使用碳酸盐的合成研究.三,氢化锂或四乙基卤化铵催化碳酸乙烯酯与多种酚类的缩合反应
标题:使用碳酸盐的合成研究.三,氢化锂或四乙基卤化铵催化碳酸乙烯酯与多种酚类的缩合反应
摘要:研究了碳酸亚乙酯与多种酚类在四乙基卤化铵存在下的缩合反应;发现它们以非常好的收率获得产物相应的芳基β-羟乙基醚.为了比较,还检查了在氢化锂代替卤化四乙基铵存在下的反应,并讨论了这些结果.
DOI:10.1246/bcsj.46.553