CAS: 842-07-9; 1-(Phenyldiazenyl)Naphthalen-2-Ol

• ⚠️《化妆品禁用原料目录》
• 英文名称1-(Phenyldiazenyl)Naphthalen-2-Ol
• 中文名称苏丹I
• IUPAC名称(E)-1-(phenyldiazenyl)naphthalen-2-ol
• 其它别名苏丹i; 苏丹红i; 苏丹红一号; Solvent Yellow 14
• CAS编号842-07-9
• MFCD编号:MFCD00003911
• EINECS号:212-668-2
• 分子式:C16H12N2O
• 分子量:248.28
• 产品CID: 1830368
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: MRQIXHXHHPWVIL-UHFFFAOYSA-N
• InChI=1S/C16H12N2O/c19-15-11-10-12-6-4-5-9-14(12)16(15)18-17-13-7-2-1-3-8-13/h1-11,19H/b18-17+…
• 计算化学: 氢键受体数3.0氢键供体数1.0可旋转键数2.0

物理性质

• 熔点131-133°C
• 沸点443.7±28.0 °C at 760 mmHg
• 闪点290.2±13.3 °C
• 密度1.2±0.1 g/cm3
• PH:10.2 (26°C)
• pKa:13.50±0.40(预测)
• PSA:44.95
• LogP:4.9608
• 折射率1.634
• 蒸汽压0.0±1.1 mmHg at 25°C
• 溶解性DMSO (Slightly), Ethyl Acetate (Slightly)
• 敏感性常温常压下稳定，避免氧化剂接触
• 外观形态橙色至红色或棕色粉末
• 储存条件密封, 常温干燥保存
• 产品应用用途:本品主要用于油脂着色,亦可用于皮鞋油,板蜡.还用作生物染色剂和石油着色剂等.
• 性质描述熔点131-133°C

MSDS等安全信息

• GHS象形图
• GHS符号GHS08 & GHS07;
  注释: Health hazard & Exclamation mark
• 危险类别致癌性 类别2
  致突变性 类别2
  皮肤致敏 类别1
  水生慢性毒性 类别4
• 警示词Warning(警告)
• 危险描述H351 |怀疑致癌.
  H341 |怀疑导致遗传缺陷.
  H317 |可能引起皮肤过敏反应.
  H413 |可能对水生生物造成长期有害影响.
• 防范说明P261-P272-P280-P302+P352-P363-P405-P501
• UN编号NONH for all modes of transport
• 危险品标志Xn,Xi
• 安全声明61-46-36/37-22-36-26
• 危险类别码68-53-43-40-36/37/38
• WGK Germany2

欧盟法规

上下游产品

合成工艺路线路线简述

• 875-83-2 = 842-07-9 + 85-86-9
  反应条件:1.1 Reagents: Sodium Nitrite Catalysts: Boron Trifluoride Solvents: Water; 2 Min,Rt1.2 2 Min,Rt
  标题:Bf3.Sio2: An Efficient Catalyst For The Synthesis Of Azo Dyes At Room Temperature
  作者:Mirjalili,Bi Bi Fatemeh; Et Al
  参考文献:Current Chemistry Letters 日期:2012 卷标:1(3) 页码:109-114]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Sodium Nitrite,Hydrochloric Acid,Polytetrafluoroethylene Solvents: Water; 20 Min,Rt1.2 40 Min,Rt
  标题:A Quantitative One-Pot Synthesis Method For Industrial Azo Pigments With Recyclable Wastewater
  作者:Feng,Guangyuan; Zhu,Meiling; Liu,Lei; Li,Chunbao
  参考文献:Green Chemistry 日期:2019 卷标:21(7) 页码:1769-1776]
  
  586-96-9 + 135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Nitric Oxide
  标题:Reactions Of Nitrosobenzenes With Nitrogen Monoxide
  作者:Iida,Hirotada; Sato,Toshiyasu; Kawamoto,Hiroshi; Takahashi,Kazumasa; Yamada,Kazutoshi
  参考文献:Nippon Kagaku Kaishi 日期:1978 卷标:(7) 页码:1003-6]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Sodium Nitrite,Hydrochloric Acid Solvents: Water; 0 °C; 0 - 5 °C1.2 Reagents: Acetic Acid Solvents: Water; 12 Min,0 - 5 °C1.3 Reagents: Sodium Nitrite Solvents: Water; Ph 3 - 4,0 - 5 °C
  标题:Process Intensification In Azo Dyes
  作者:Shankarling,Ganapati S.; Deshmukh,Pratik P.; Joglekar,Amruta R.
  参考文献:Journal Of Environmental Chemical Engineering 日期:2017 卷标:5(4) 页码:3302-3308]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Catalysts: Graphene (Carboxyl- And Nitrite-Functionalized,Reaction Products With Quantum Dots); 10 Min,Rt1.2 Solvents: Water; 10 Min,Rt
  标题:Carboxyl And Nitrite Functionalized Graphene Quantum Dots As A Highly Active Reagent And Catalyst For Rapid Diazotization Reaction And Synthesis Of Azo-Dyes Under Solvent-Free Conditions
  作者:Valizadeh,Hassan; Shomali,Ashkan; Nourshargh,Saideh; Mohammad-Rezaei,Rahim
  参考文献:Dyes And Pigments 日期:2015 卷标:113 页码:522-528]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Acetonitrile; 30 Min,0 - 5 °C1.2 Solvents: Acetonitrile; 0 - 5 °C; 12 H,0 - 5 °C
  标题:Diazotization Of Anilines And Diazo Coupling With A Coupling Component Mediated By A Polymer-Supported Sodium Nitrite And A Polymeric Acid
  作者:Karimi Zarchi,Mohammad Ali; Karimi,Mohammad
  参考文献:Journal Of Applied Polymer Science 日期:2012 卷标:123(5) 页码:2762-2767]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Sodium Nitrite,Hydrochloric Acid Solvents: Water; 0 °C; 10 Min,0 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; 20 S,0 °C
  标题:Continuous Flow Solvent Free Organic Synthesis Involving Solids (Reactants/products) Using A Screw Reactor
  作者:Sharma,Brijesh M.; Atapalkar,Ranjit S.; Kulkarni,Amol A.
  参考文献:Green Chemistry 日期:2019 卷标:21(20) 页码:5639-5646]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Sodium Nitrite,Hydrochloric Acid Solvents: Acetonitrile; 0.5 H,0 - 5 °C1.2 Solvents: Acetonitrile; 0 - 5 °C; 45 Min,0 - 5 °C
  标题:Synthesis Of Azo Chromophores By Using A Polymer-Supported Sodium Nitrite
  作者:Zarchi,Mohammad Ali Karimi; Karimi,Mohammad
  参考文献:Journal Of Applied Polymer Science 日期:2011 卷标:120(1) 页码:538-543]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Sodium Nitrite Catalysts: Montmorillonite ((Al1.33-1.67Mg0.33-0.67)(Ca0-1Na0-1)0.33Si4(Oh)2O10.Xh2O) (Copper,Iron,Or Zinc-Exchanged) Solvents: Water; 30 Min,Rt; 30 Min,Rt; 1 H,Rt
  标题:Application Of Modified Clays In Diazotization And Azo Coupling Reactions In Water
  作者:Chermahini,Alireza Najafi; Doukheh,Maryam; Hassan,Hassan Zadeh; Bostanian,Mehdi
  参考文献:Journal Of Industrial And Engineering Chemistry (Amsterdam 日期:2012 卷标:18(2) 页码:826-833]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Sodium Nitrite,Hydrochloric Acid Catalysts: 1H-Imidazolium,3-Ethenyl-1-(4-Hydroxybutyl)-,Chloride (1:1),Homopolymer (Silica Nanoparticle-Bound) Solvents: Water; 0 - 5 °C; 10 Min,0 - 5 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 5 Min,0 - 5 °C1.3 5 Min,0 - 5 °C
  标题:New Generation Of Nitrite Functionalized Star-Like Polyvinyl Imidazolium Compound: Application As A Nitrosonium Source And Three Dimensional Nanocatalyst For The Synthesis Of Azo Dyes
  作者:Shomali,Ashkan; Valizadeh,Hassan; Noorshargh,Saeideh
  参考文献:Letters In Organic Chemistry 日期:2017 卷标:14(6) 页码:409-418]
  
  135-19-3 = 842-07-9
  反应条件:1.1 Catalysts: Graphene (Oxide,Nitrite-Functionalized); 5 Min,0 - 5 °C1.2 Solvents: Methanol; 0 - 5 °C; 5 Min,0 - 5 °C
  标题:Graphene Derivative As A Highly Efficient Nitrosonium Source: A Reusable Catalyst For Diazotization And Coupling Reaction
  作者:Pethsangave,Dattatray A.; Khose,Rahul V.; Chaskar,Atul C.; Jun,Seong Chan; Some,Surajit
  参考文献:Chemistryselect 日期:2016 卷标:1(21) 页码:6933-6940]
  
  100-34-5 + 135-19-3 = 842-07-9
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water
  标题:Synthesis And Characteristics Of Some Organic Dyes
  作者:Khobrani,Salihah Hussain A.
  参考文献:Journal Of Chemical 日期:2023 卷标:13(1) 页码:1-11]
  
  58367-01-4 = 842-07-9 + 85-83-6 + 64-75-5
  反应条件:1.1 Solvents: Ethanol; 8 H,180 °C
  标题:Multifunctional Carbon Dots-Based Fluorescence Detection For Sudan I,Sudan Iv And Tetracycline Hydrochloride In Foods
  作者:Zhang,Min; Et Al
  参考文献:Nanomaterials 日期:2022 卷标:12(23)

海关参考信息

• 2902902000-精萘
  2908199090-其他酚的卤化衍生物
  2908999090-其他酚的硝化衍生物
  2918290000-其他含酚基羧酸
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管