CAS: 25276-70-4; Pentadecane-1-Thiol

上下游产品

pentadecyl bromiden-Pentadecylthiomyristat

📜溴代十五烷置于盐酸体系中,用 四氢呋喃,甲醇,水 用作溶剂,化学反应生成N-十五烷基硫醇
参考文献:Intrinsic And Extrinsic Control Of The Pka Of Thiol Guests Inside Yoctoliter Containers
标题:Intrinsic And Extrinsic Control Of The Pka Of Thiol Guests Inside Yoctoliter Containers
摘要:Despite Decades Of Research,There Are Still Many Open Questions Surrounding The Mechanisms By Which Enzymes Catalyze Reactions. Understanding All The Noncovalent Forces Involved Has The Potential To Allow De Novo Catalysis Design,And As A Step Toward This,Understanding How To Control The Charge State Of Ionizable Groups Represents A Powerful Yet Straightforward Approach To Probing Complex Systems. Here We Utilize Supramolecular Capsules Assembled Via The Hydrophobic Effect To Encapsulate Guests And Control Their Acidity. We Find That The Greatest Influence On The Acidity Of Bound Guests Is The Location Of The Acidic Group Within The Yoctoliter Space. However,The Nature Of The Electrostatic Field Generated By The (Remote) Charged Solubilizing Groups Also Plays A Significant Role In Acidity,As Does Counterion Complexation To The Outer Surfaces Of The Capsules. Taken Together,These Results Suggest New Ways By Which To Affect Reactions In Confined Spaces.
Doi:10.1021/jacs.0C00907

专利信息

专利号:US-10730904-B2
优先权日:2012-11-14
标 题:Method for liquid-phase synthesis of nucleic acid
发明人：NONOGAWA MITSURU; NAGATA TOSHIAKI; SAITO HIDEKI; YASUMA TSUNEO
权利人:TAKEDA PHARMACEUTICALS CO
摘要:In this method, an oligonucleotide represented by formula (II) [wherein Y 1 , Q, Base, r and r′ are each as defined in claim 1 ] is prepared by using, as a synthesis unit, a novel nucleoside monomer compound represented by formula (I) [wherein X, R 1 , Y, Base, Z, Ar, R 2 , R 3 and n are each as defined in claim 1 ]. The novel nucleoside monomer compound is a nucleoside, the base moiety of which is substituted with an aromatic-hydrocarbon-ring-carbonyl or -thiocarbonyl group having at least one hydrophobic group. The method can dispense with column-chromatographic purification in every reaction, and enables base elongation not only in the 3′-direction but also in the 5′-direction, thus attaining efficient liquid-phase mass synthesis of an oligonucleotide.

专利号:US-2016244546-A1
优先权日:2013-10-11
标 题 :Direct synthesis of ph-responsive polymer particles and application in control release of hydrophobic therapeutic compounds
发明人：HE TAO; KIM SANGGU; STUBBS LUDGER PAUL
权利人:AGENCY SCIENCE TECH & RES
摘要:The present disclosure relates to a process for making a branched copolymer comprising reacting polymer monomers with macro-azo polyethylene glycol (PEG) initiators and cross-linkers, in the presence of a chain transfer agent, wherein said process comprises the step of traditional radical polymerization. The process further comprises a step of dialysis to obtain polymer nano-particles. The process further comprises the step of loading the polymer nanoparticles with a hydrophobic compound. The present disclosure also relates to the use of the polymer nanoparticles for the slow release of a hydrophobic compound in a neutral or alkaline environment or the fast release of a hydrophobic compound in an acidic environment.

专利号:WO-2023113033-A1
优先权日:2021-12-16
标题 :Gas diffusion electrode
发明人：KONDO SHOICHI; MAEDA SHINICHI; SHIGA NORIHITO
权利人:NISSAN CHEMICAL CORP
摘要:[Problem] The present invention addresses the problem of increasing the rate of reaction by controlling ammonium ions, which are generated by ammonia as the objective of the electrolytic synthesis of ammonia and protons that are supplied to the cathode, by means of the cathode and the cathode catalyst layer. [Solution] The present invention provides a gas diffusion electrode which is integrated with a catalyst layer that uses a material selected from the group consisting of cathode catalyst layer materials. Examples of the cathode catalyst layer materials include a fired body and an ionic liquid.

专利号:EP-0713488-B1
优先权日:1993-08-10
标题 :[1,3,4]triazolo [1,5-al]pyridines used as intermediate products for the synthesis of dyes

专利号:US-11192908-B2
优先权日:2018-08-17
标题:Octamolybdate compounds exhibiting bright emission
发明人：DANIELS STEVEN; PICKETT NIGEL; SAVJANI NICKY; GAVRILIUC VIRGIL
权利人:NANOCO 2D MAT LIMITED; UNIV MANCHESTER
摘要:Methods for the synthesis of a polyoxometalate compounds include heating a metal precursor in the presence of an organic salt. The polyoxometalate compounds produced herein display high photoluminescence quantum yields and photoluminescence maximums in the blue and/or violet regions of the electromagnetic spectrum.

专利号:US-2015315229-A1
优先权日:2012-11-14
标 题 :Method for liquid-phase synthesis of nucleic acid