143-08-8 = 124-19-6 + 112-05-0 + 87310-12-1 反应条件:1.1 Reagents: Sodium Bromate Catalysts: Hydrochloric Acid,4-(Benzoylamino)-2,2,6,6-Tetramethyl-1-Piperidinyloxy Solvents: Dimethylformamide,Water; 2 H,Rt 标题:4-Benzamido-Tempo Catalyzed Oxidation Of A Broad Range Of Alcohols To The Carbonyl Compounds With Nabro3 Under Mild Conditions 作者:Shen,Jiaxuan; Et Al 参考文献:Chinese Journal Of Chemistry 日期:2014 卷标:32(5) 页码:405-409]
143-08-8 = 124-19-6 + 87310-12-1 反应条件:1.1 Reagents: Pyridine Catalysts: Iodine,4-Acetamido-Tempo Solvents: Dichloromethane,Water; 3 H,20 - 25 °C1.2 Reagents: Sodium Thiosulfate Solvents: Water 标题:Oxidative Dimerization Of Alcohols In The Presence Of Nitroxyl Radical-Iodine Catalytic System 作者:Kashparova,V. P.; Et Al 参考文献:Russian Journal Of General Chemistry 日期:2016 卷标:86(11) 页码:2423-2426]
143-08-8 = 124-19-6 + 87310-12-1 反应条件:1.1 Reagents: Oxygen Catalysts: Palladium Solvents: (Trifluoromethyl)Benzene; 24 H,1 Atm,60 °C 标题:Non-Plasmonic Metal Nanoparticles As Visible Light Photocatalysts For The Selective Oxidation Of Aliphatic Alcohols With Molecular Oxygen At Near Ambient Conditions 作者:Tana,Tana; Et Al 参考文献:Chemical Communications (Cambridge 日期:2016 卷标:52(77) 页码:11567-11570]
143-08-8 = 124-19-6 + 87310-12-1 反应条件:1.1 Reagents: Sodium Bicarbonate,Iodine Catalysts: 4-Acetamido-Tempo Solvents: Dichloromethane,Water; 20 - 22 °C; 3 H,20 - 22 °C1.2 Reagents: Sodium Thiosulfate Pentahydrate Solvents: Water; 5 Min,20 - 22 °C 标题:A Tempo-Like Nitroxide Combined With An Alkyl-Substituted Pyridine: An Efficient Catalytic System For The Selective Oxidation Of Alcohols With Iodine 作者:Kashparova,Vera P.; Et Al 参考文献:Tetrahedron Letters 日期:2017 卷标:58(36) 页码:3517-3521]
143-08-8 = 124-19-6 + 1680-36-0 + 112-05-0 + 87310-12-1 反应条件:1.1 Reagents: Sodium Bicarbonate,Potassium Iodide,4-Acetamido-Tempo Catalysts: 2,6-Lutidine Solvents: Dichloromethane,Water; Ph 8.6,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 5,Rt 标题:One-Pot Electrochemical Synthesis Of Acid Anhydrides From Alcohols 作者:Kashparova,V. P.; Et Al 参考文献:Russian Journal Of General Chemistry 日期:2017 卷标:87(11) 页码:2733-2735
专利号:US-2010099894-A1 优先权日:2006-10-09 标 题 :Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution 发明人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO 权利人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO 摘要:A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.
专利号:WO-2023102600-A1 优先权日:2021-12-06 标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom 发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI 权利人:NEWSOUTH INNOVATIONS PTY LTD 摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.
专利号:US-6512081-B1 优先权日:1997-07-21 标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents 发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME 权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG 摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.
专利号:US-2024076303-A1 优先权日:2022-09-07 标 题:Green Synthesis of Salicylaldehydate-Metal-Organic Frameworks and Applications Thereof 发明人:SHETTY DINESH; MOHAMMED ABDUL KHAYUM 权利人:UNIV KHALIFA SCIENCE & TECHNOLOGY 摘要:Embodiments of the present disclosure generally describe two-dimensional/three-dimensional conjugated salicylaldehydate metal organic framework (2D/3D-c-SA MOF) compositions, method for green synthesis of the two-dimensional/three-dimensional conjugated salicylaldehydate metal organic framework (2D/3D-c-SA MOF) compositions, applications of the said compositions in supercapacitors, lithium-ion batteries, electrocatalytic conversion reactions, photocatalytic reduction of CO 2 and other uses.
专利号:US-11999757-B2 优先权日:2017-11-01 标 题:Synthesis of boronate ester derivatives and uses thereof 发明人:BOYER SERGE HENRI; HECKER SCOTT J; VERZIJL GERARDUS K M; HERMSEN PETRUS J 权利人:MELINTA SUBSIDIARY CORP 摘要:Disclosed herein are methods for the preparation of boronate derivatives in the synthesis of antimicrobial compounds and uses thereof. Disclosed herein includes method of making a compound of Formula (B) by reducing the ketone group of the keto-ester compound of Formula (A), and the reduction can be performed using a Ruthenium based catalyst system or using an alcohol dehydrogenase bioreduction system.
专利号:US-10730904-B2 优先权日:2012-11-14 标 题:Method for liquid-phase synthesis of nucleic acid 发明人:NONOGAWA MITSURU; NAGATA TOSHIAKI; SAITO HIDEKI; YASUMA TSUNEO 权利人:TAKEDA PHARMACEUTICALS CO 摘要:In this method, an oligonucleotide represented by formula (II) [wherein Y 1 , Q, Base, r and r′ are each as defined in claim 1 ] is prepared by using, as a synthesis unit, a novel nucleoside monomer compound represented by formula (I) [wherein X, R 1 , Y, Base, Z, Ar, R 2 , R 3 and n are each as defined in claim 1 ]. The novel nucleoside monomer compound is a nucleoside, the base moiety of which is substituted with an aromatic-hydrocarbon-ring-carbonyl or -thiocarbonyl group having at least one hydrophobic group. The method can dispense with column-chromatographic purification in every reaction, and enables base elongation not only in the 3′-direction but also in the 5′-direction, thus attaining efficient liquid-phase mass synthesis of an oligonucleotide.
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