CAS: 933047-52-0; 4,4',4'',4'''-(Pyrene-1,3,6,8-Tetrayl)Tetrabenzoic Acid
- 英文名称4,4',4'',4'''-(Pyrene-1,3,6,8-Tetrayl)Tetrabenzoic Acid
- 中文名称1,3,6,8-四[对苯甲酸]芘
- IUPAC名称4,4',4'',4'''-(pyrene-1,3,6,8-tetrayl)tetrabenzoic acid
- 其它别名1,3,6,8-四(4-羧基苯)芘; 4,4',4'',4'''-(Pyrene-1,3,6,8-Tetrayl)Tetrabenzoic Acid
- CAS编号933047-52-0
- MFCD编号:MFCD30478418
- 分子式:C44H26O8分子量:682.67
- 产品CID: 1971354
- 产品分类有机原料→材料科学→MOF有机配体→羧酸MOF配体
- 相似结构搜索
- InChIKey: HVCDAMXLLUJLQZ-UHFFFAOYSA-N
- HVCDAMXLLUJLQZ-UHFFFAOYSA-N
- 计算化学: 氢键受体数4.0氢键供体数4.0可旋转键数8.0
相似化合物
1415238-25-3 1598415-56-5 1569900-72-6物理性质
MSDS等安全信息
合成工艺路线路线简述
- 933047-49-5 = 933047-52-0
反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Tetrahydrofuran,1,4-Dioxane,Water; 12 H,85 °C1.2 Solvents: Water; 2 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2
标题:Porous Hydrogen-Bonded Organic Framework Membranes For High-Performance Molecular Separation
作者:Jiang,Xiao-Tian; Yin,Qi; Liu,Bai-Tong; Chen,Jun-Yu; Wang,Rui; Et Al
参考文献:Nanoscale Advances 日期:2021 卷标:3(12) 页码:3441-3446]
933047-49-5 = 933047-52-0
反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Tetrahydrofuran,1,4-Dioxane,Water; 12 H,85 °C1.2 Reagents: Water; 2 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2,Rt
标题:Novel Hierarchical Meso-Microporous Hydrogen-Bonded Organic Framework For Selective Separation Of Acetylene And Ethylene Versus Methane
作者:Yin,Qi; Li,Yu-Lin; Li,Lan; Lu,Jian; Liu,Tian-Fu; Et Al
参考文献:Acs Applied Materials & Interfaces 日期:2019 卷标:11(19) 页码:17823-17827]
933047-49-5 = 933047-52-0
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Tetrahydrofuran,1,4-Dioxane,Water; Overnight,85 °C1.2 Solvents: Water; 2 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2,Rt
标题:A Guest-Responsive Fluorescent 3D Microporous Metal-Organic Framework Derived From A Long-Lifetime Pyrene Core
作者:Stylianou,Kyriakos C.; Heck,Romain; Chong,Samantha Y.; Bacsa,John; Jones,James T. A.; Et Al
参考文献:Journal Of The American Chemical Society 日期:2010 卷标:132(12) 页码:4119-4130]
933047-49-5 = 933047-52-0
反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Tetrahydrofuran,1,4-Dioxane,Water; 24 H,80 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 2,Rt
标题:An Electrochromic Hydrogen-Bonded Organic Framework Film
作者:Feng,Ji-Fei; Liu,Tian-Fu; Cao,Rong
参考文献:Angewandte Chemie 日期:2020 卷标:59(50) 页码:22392-22396]
933047-49-5 = 933047-52-0
反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Tetrahydrofuran,1,4-Dioxane,Water; 12 H,85 °C1.2 Solvents: Water; 2 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2
标题:An Ultra-Robust And Crystalline Redeemable Hydrogen-Bonded Organic Framework For Synergistic Chemo-Photodynamic Therapy
作者:Yin,Qi; Zhao,Peng; Sa,Rong-Jian; Chen,Guang-Cun; Lue,Jian; Et Al
参考文献:Angewandte Chemie 日期:2018 卷标:57(26) 页码:7691-7696]
933047-49-5 = 933047-52-0
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Tetrahydrofuran,1,4-Dioxane,Water; Overnight,Reflux1.2 Solvents: Water; 2 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 1,Rt
标题:Exclusive Recognition Of Acetone In A Luminescent Biomof Through Multiple Hydrogen-Bonding Interactions
作者:Huang,Yong-Liang; Qiu,Pei-Li; Bai,Jian-Ping; Luo,Dong; Lu,Weigang; Et Al
参考文献:Inorganic Chemistry 日期:2019 卷标:58(12) 页码:7667-7671
📜1,3,6,8-四溴芘置于potassium Phosphate,四(三苯基膦)钯,Sodium Hydroxide体系中,用 四氢呋喃,1,4-二氧六环,水 作为反应溶剂,化学反应 94.0H,反应生成 1,3,6,8-四(4-羧基苯基)芘
参考文献:具有超高质子传导性的咪唑连接结晶二维聚合物
标题:具有超高质子传导性的咪唑连接结晶二维聚合物
摘要:由于具有绿色特性,高功率密度和温和的操作条件,质子交换膜燃料电池是未来可持续发展的有前途的能源设备.简单的质子传导膜在提高燃料电池的效率方面起着关键作用,因此非常需要在该领域进行重点研究.与 Nafion 的成功例子相关的主要问题导致寻找替代质子传导材料.尽管载有质子载体的结晶多孔有机骨架已被用于质子传导,但弱的主客体相互作用限制了其实际应用.在此,我们开发了一种由苯并咪唑单元作为组成部分的结晶二维聚合物,由芳酸和二胺在多磷酸介质中缩合制备.咪唑连接的二维聚合物在原始状态下表现出超高的质子电导率(3.2 x 10-2 Scm-1)(在 95% 的相对湿度和 95oc 下),这是迄今为止报道的未掺杂多孔有机框架中最高的.晶体质子传导二维聚合物的当前策略将导致新的高性能晶体固体质子导体的开发.
DOI:10.1021/jacs.9B06080
专利信息
专利号:CN-105218359-A
优先权日:2015-09-16
标 题 :A kind of K-substituted pyrene derivative carboxylic acid compound and its synthesis method
专利号:CN-116606446-A
优先权日:2023-05-19
标 题:A kind of 4-(pyridine-2-methyleneamino) benzoic acid functionalized NU-1000 and its synthesis method
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合成参考文献
参考文献:10.1007/s40843-023-2834-1
摘要:Wang Z, Zou Y, Fang Z, Li J, Li Y, Zhang A, Liu T. Partitioning of pore space in hydrogen-bonded organic frameworks for enhanced CO2 photoreduction. Sci. China Mater. 2024 May 21;67(6):1846–50. doi: 10.1007/s40843-023-2834-1.
参考文献:10.1007/s11426-025-2608-4
摘要:Liu J, Li T, Liao P, Ruan Z, Wang Z, Jia J, Tong M. Integrating stable radical hydrogen-bonded organic frameworks with silver nanoparticles for highly efficient solar-driven water evaporation. Sci. China Chem. 2025 Apr 14;68(10):4847–55. doi: 10.1007/s11426-025-2608-4.
参考文献:10.1007/s42114-025-01548-y
摘要:Sruthi VP, Thenmozhi K, Satija J, Senthilkumar S. Unravelling the multifaceted insights on covalent organic frameworks based electrochemical sensors towards healthcare and environmental analysis. Adv Compos Hybrid Mater. 2025 Dec 04;9(1). doi: 10.1007/s42114-025-01548-y.
参考文献:10.1007/s42114-026-01638-5
摘要:Zeng T, Li Z, Sun Y, Liu Y, Xu J, Huang X, Liang Y, Shi H, Wu S, Li G, Yin Y. Co-optimization of algorithm and sensor array for precise diagnosis of HER2-positive breast cancer and trastuzumab response prediction. Adv Compos Hybrid Mater. 2026 Feb 09;9(2). doi: 10.1007/s42114-026-01638-5.
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