CAS: 80952-71-2; (2R,3R,4S,5S,6R)-2-(((6R,8R,10R,12S,14S)-3,12-Dihydroxy-17-((R)-2-Hydroxy-6-Methylhept-5-En-2-yl)-4,4,8,10,14-Pentamethylhexadecahydro-1H-Cyclopenta[a]Phenanthren-6-yl)Oxy)-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-3,4,5-Triol

结构式图片

物理性质

MSDS等安全信息

上下游产品

1ginsenoside Rg1 ginsenoside Rf 1ginsenoside-Rg1 ginsenoside Re 6α-O-β-D-glucopyranosyl-(20S,24R)-epoxydammarane-3β,12β,25-triol

合成工艺路线路线简述

  • 80418-24-2 = 80952-71-2 + 63223-86-9 + 97744-96-2 + 948046-16-0 + 948046-15-9 + 174721-08-5 + 80418-25-3 + 948046-18-2
    反应条件:1.1 Solvents: Ethanol,Water; 4 D,26 °C
    标题:Microbial Transformation Of 20(S)-Protopanaxatriol-Type Saponins By Absidia Coerulea
    作者:Chen,Guangtong; Yang,Min; Lu,Zhiqiang; Zhang,Jinqiang; Huang,Huilian; Et Al
    参考文献:Journal Of Natural Products 日期:2007 卷标:70(7) 页码:1203-1206]

    63223-86-9 = 80952-71-2 [标题:Reaction Conditions
    标题:Biotransformation Of Ginsenosides In Fermented Ginseng Using Uplc-Q-Orbitrap Ms/ms
    作者:Qiao,Mengdan; Et Al
    参考文献:Gaodeng Xuexiao Huaxue Xuebao 日期:2018 卷标:39(2) 页码:219-225]

    52286-74-5 = 80952-71-2 + 34080-08-5 + 63223-86-9 + 1453-93-6
    反应条件:1.1 Reagents: Sodium Solvents: 1-Butanol
    标题:Alkaline Cleavage Of Ginsenosides
    作者:Chen,Yingjie; Et Al
    参考文献:Chemical & Pharmaceutical Bulletin 日期:1987 卷标:35(4) 页码:1653-5]

    22427-39-0 = 80952-71-2 [标题:Reaction Conditions
    标题:Biotransformation Of Ginsenosides In Fermented Ginseng Using Uplc-Q-Orbitrap Ms/ms
    作者:Qiao,Mengdan; Et Al
    参考文献:Gaodeng Xuexiao Huaxue Xuebao 日期:2018 卷标:39(2) 页码:219-225]

    52286-74-5 = 80952-71-2 [标题:Reaction Conditions
    标题:Biotransformation Of Ginsenosides In Fermented Ginseng Using Uplc-Q-Orbitrap Ms/ms
    作者:Qiao,Mengdan; Et Al
    参考文献:Gaodeng Xuexiao Huaxue Xuebao 日期:2018 卷标:39(2) 页码:219-225]

    52286-59-6 = 80952-71-2 [标题:Reaction Conditions
    标题:Biotransformation Of Ginsenosides In Fermented Ginseng Using Uplc-Q-Orbitrap Ms/ms
    作者:Qiao,Mengdan; Et Al
    参考文献:Gaodeng Xuexiao Huaxue Xuebao 日期:2018 卷标:39(2) 页码:219-225]

    22427-39-0 = 80952-71-2 + 63223-86-9 + 97744-96-2 + 174721-08-5
    反应条件:1.1 Solvents: Ethanol,Water; 4 D,26 °C
    标题:Microbial Transformation Of 20(S)-Protopanaxatriol-Type Saponins By Absidia Coerulea
    作者:Chen,Guangtong; Et Al
    参考文献:Journal Of Natural Products 日期:2007 卷标:70(7) 页码:1203-1206]

    22427-39-0 = 80952-71-2 + 63223-86-9 + 364779-15-7 + 53963-43-2 + 80952-73-4 + 2319608-29-0 + 340270-88-4
    反应条件:1.1 Catalysts: 12-Tungstosilicic Acid Solvents: Methanol,Water; 5 H,Ph 3,Rt -> 60 °C
    标题:A Novel Catalytic Application Of Heteropoly Acids: Chemical Transformation Of Major Ginsenosides Into Rare Ginsenosides Exemplified By Rg1
    作者:Cao,Jie; Et Al
    参考文献:Science China: Chemistry 日期:2017 卷标:60(6) 页码:748-753]

    52286-59-6 = 80952-71-2 + 63223-86-9 + 80928-46-7 + 97744-96-2 + 174721-08-5 + 52286-74-5 + 948046-19-3
    反应条件:1.1 Solvents: Ethanol,Water; 4 D,26 °C
    标题:Microbial Transformation Of 20(S)-Protopanaxatriol-Type Saponins By Absidia Coerulea
    作者:Chen,Guangtong; Et Al
    参考文献:Journal Of Natural Products 日期:2007 卷标:70(7) 页码:1203-1206

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合成参考文献


参考文献:10.5281/zenodo.5794106
摘要:The LOTUS Initiative for Open Natural Products Research: frozen dataset union wikidata (with metadata) | DOI:10.5281/zenodo.5794106
参考文献:10.1016/j.bmcl.2015.09.039
摘要:Ma LY, Zhou QL, Yang XW. New SIRT1 activator from alkaline hydrolysate of total saponins in the stems-leaves of Panax ginseng. Bioorg Med Chem Lett. 2015 Nov 15;25(22):5321–5. doi: 10.1016/j.bmcl.2015.09.039.
参考文献:10.5012/bkcs.2010.31.5.1381
摘要:Tung N, Cho K, Kim J, Song G, Kim Y. Dammarane-Type Glycosides from the Steamed Flower-Buds of Panax ginseng. Bulletin of the Korean Chemical Society. 2010 May 20;31(5):1381–4. doi: 10.5012/bkcs.2010.31.5.1381.
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