CAS: 6126-50-7; 4-Hexen-1-Ol
该化合物是分子式C6H12O的不饱和脂性酒精.该化合物具有终端氢氧化物组和4位置的双联,使其在有机合成中成为多功能中间体.其结构允许进一步功能化,包括氢化,氧化或衍生,使其在香味,口味和特殊化学品的生产中发挥作用.由于存在氢化物和烷的功能,它能够应用于聚合和交叉反应.Hex-4-en-1-ol通常是无色液体,有温和的气味,在普通有机溶剂中溶解,但水中可分溶解.其反应性和中度稳定使其在精细化学合成中成为有价值的试剂.
- 相似结构搜索
- 产品信息参考
;;;; - InChIKey: VTIODUHBZHNXFP-UHFFFAOYSA-N
- InChI=1S/C6H12O/c1-2-3-4-5-6-7/h2-3,7H,4-6H2,1H3
- 计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数3.0
相似化合物
928-92-7 35194-36-6 57074-37-0物理性质
- 熔点22.55 °C
- 沸点152.63 °C at 760 mmHg
- 闪点59.9 °C
- 密度0.843 g/cm3
- PSA:20.23
- LogP:1.335
- 折射率1.4402
- 蒸汽压0.929 mmHg at 25 °C
- 外观形态液体
- 储存条件室温，密封保存，干燥环境
- 产品应用4-己烯-1-醇(6126-50-7)的用途:GB 2760―1996规定为允许使用的食品用香料.
- 性质描述4-己烯-1-醇(6126-50-7)的性状:1.有顺式和反式两种异构体.无色至淡黄色油状液体,呈辛辣的刺激性油质气味,似芥菜,番茄,草药似香气,有煮熟蔬菜气味.2.沸点,顺式158～159°C,反式159～159.4°C.相对密度(d204)0.8513;折射率,顺式(n20D)1.4420,反式(n20D)1.4402.不溶于水,溶于乙醇.3.天然品存在于香蕉,大豆,鸡蛋果等中.4.毒性:GRAS(FEMA).
MSDS等安全信息
欧盟法规
C&L通报上下游产品
CAS号110-82-7 环己烷 | CAS号111-28-4 2,4-已二烯-1-醇 | CAS号701-75-7 but-3-en-2-ylsu... | CAS号540-51-2 2-溴乙醇 | CAS号35194-36-6 4-己烯酸 | CAS号928-95-0 反式-2-己烯-1-醇 | CAS号17102-64-6 反式-2,4-己二烯-1-醇 | CAS号142-83-6 2,4-己二烯醛 | CAS号629-11-8 1,6-己二醇 | CAS号27925-22-0 7,8-dioxabicycl... | CAS号629-30-1 1,7-庚二醇合成工艺路线路线简述
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905121000-正丙醇
2905130000-正丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-11807617-B2
优先权日:2017-05-08
标题 :Highly efficient synthesis of Z-macrocycles using stereoretentive, ruthenium-based metathesis catalysts
发明人：AHMED TONIA S; GRUBBS ROBERT H
权利人:CALIFORNIA INST OF TECHN
摘要:A highly efficient, Z-selective ring-closing metathesis system for the formation of macrocycles using a stereoretentive, ruthenium-based catalyst supported by a dithiolate ligand is reported. This catalyst is demonstrated to be remarkably active as observed in initiation experiments showing complete catalyst initiation at −20° C. within 10 min. Using easily accessible diene starting materials bearing a Z-olefin moiety, macrocyclization reactions generated products with significantly higher Z-selectivity in appreciably shorter reaction times, in higher yield, and with much lower catalyst loadings than in previously reported systems. Macrocyclic lactones ranging in size from twelve-membered to seventeen-membered rings are synthesized in moderate to high yields (68-79% yield) with excellent Z-selectivity (95%-99% Z).
专利号:US-2020102285-A1
优先权日:2017-05-08
标 题:A highly efficient synthesis of z-macrocylces using stereoretentive, ruthenium-based metathesis catalysts
专利号:CN-110536748-A
优先权日:2017-05-08
标 题 :Highly Efficient Synthesis of Z-Macrocycles Using Steremaintaining Ruthenium-Based Metathesis Catalysts
专利号:US-11053209-B2
优先权日:2017-05-08
标 题:Highly efficient synthesis of z-macrocycles using stereoretentive, ruthenium-based metathesis catalysts
专利号:EP-3621729-B1
优先权日:2017-05-08
标 题 :A highly efficient synthesis of z-macrocycles using stereoretentive, ruthenium-based metathesis catalysts
专利号:CN-110536748-B
优先权日:2017-05-08
标 题:Highly efficient synthesis of Z-macrocycles using a sterically retentive ruthenium-based metathesis catalyst
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Celik, I.; Hummel, S.; Kirsch, S. F., Science of Synthesis Knowledge Updates, (2019) 1, 56.
摘要:Hennecke, U., Science of Synthesis Knowledge Updates, (2015) 2, 452.
摘要:Andries-Ulmer, A.; Gulder, T., Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (2017) 1, 423.
摘要:Hopkinson, M. N.; Dix, S., Science of Synthesis: Photocatalysis in Organic Synthesis, (2018) 1, 299.
摘要:Barriault, L.; Zidan, M.; Rohe, S., Science of Synthesis, (2019) , 400.
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