CAS: 307-24-4; Perfluorohexanoic Acid

相似化合物

424-18-0 2706-90-3 423-46-1

上下游产品

CAS号355-43-1 全氟己基碘 | CAS号106-95-6 烯丙基溴 | CAS号762-72-1 烯丙基三甲基硅烷 | CAS号591-87-7 乙酸烯丙酯 | CAS号106-96-7 溴代丙炔 | CAS号31143-13-2 1,1,1,2,3,4,4,5... | CAS号2923-26-4 十一氟代己酸钠 | CAS号673-32-5 1-苯基-1-丙炔 | CAS号2809-67-8 2-辛炔 | CAS号423-46-1 1H,1H-十一氟-1-己醇 | CAS号2708-07-8 甲基十一氟戊基酮 | CAS号754-79-0 1H-全氟己烷-1,1-二醇

Sodium Undecafluorohexanoate置于硫酸体系中,用94%的收率获得产物全氟己酸
参考文献:一种制备全氟羧酸的新方法
标题:一种制备全氟羧酸的新方法
摘要:伯全氟烷基碘化物和含3到12个碳原子的溴化物[cf 3(cf 2)n X,N = 2-11,X = Br,I]与rongalite-Nahco 3试剂在偶极非质子传递溶剂中的反应,例如dmf或dmso,已经过调查.反应以51-86%的收率得到全氟羧酸钠[cf 3(cf 2)n-1 Co 2 Na,N = 2〜11],并将它们转化为相应的全氟羧酸[cf 3(cf 2)n-1 Co 2H,N = 2 11]通过硫酸处理.这提供了合成全氟羧酸的新方法.
DOI:10.1016/s0022-1139(00)82053-9

专利信息

专利号:US-11485804-B2
优先权日:2017-10-17
标题:Method for the synthesis of fluoropolymers
发明人：D'APRILE FIORENZA; KAPELYUSHKO VALERIY; KENT BRADLEY LANE; BRINATI GIULIO; PONTA LAURA
权利人:SOLVAY SPECIALTY POLYMERS IT
摘要:The present invention relates to a fluorosurfactant-free emulsion polymerization method for the synthesis of a fluoropolymer, more in particular of a VDF-based polymer.

专利号:US-11400438-B2
优先权日:2018-12-05
标 题 :Synthesis and immobilization of a ferrous sulfite catalyst and method of degrading fluorinated organic chemicals in aqueous media
发明人：DIONYSIOU DIONYSIOS D; ABDELRAHEEM WAEL H M; NADAGOUDA MALLIKARJUNA N
权利人:UNIV CINCINNATI; THE US ADMINISTRATOR OF THE U S ENVIRONMENTAL PROTECTION AGENCY
摘要:A composition includes an aqueous solution including at least one fluorinated organic compound; and a reaction product of a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. A method of making a catalyst includes reacting a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. The water may include less than or equal to 1 weight percent dissolved molecular oxygen. The catalyst may be used for degrading fluorinated organic chemicals in aqueous media.

专利号:US-4273947-A
优先权日:1979-01-31
标 题:Hydrogenation of fluorine-containing carboxylic acids
发明人：NOVOTNY MIROSLAV
权利人:ALLIED CHEM
摘要:A process is described for the heterogeneous hydrogenation of fluorine-containing alkyl, cycloalkyl, and benzene carboxylic acids to the corresponding primary alcohols. The hydrogenation can be carried out in the liquid or vapor phase in the presence of a solid rhodium or iridium catalyst, employed as the metal, metallic oxide, or mixture thereof. In the liquid phase, the hydrogenation can be carried out batchwise under mild conditions of temperature and pressure, preferably at about 50°-150° C. and about 5-15 atmospheres, in an atmosphere containing hydrogen gas. A preferred embodiment is the hydrogenation of trifluoroacetic acid in the liquid phase to 2,2,2-trifluoroethanol, said alcohol being useful as an intermediate in the synthesis of the anesthetic, isoflurane, CF 3 CHClOCHF 2 .

专利号:US-8999189-B2
优先权日:2010-03-09
标 题 :Ferroelectric fluoride compositions and methods of making and using same
发明人：HALASYAMANI P SHIV; CHANG HONG-YOUNG
权利人:HALASYAMANI P SHIV; CHANG HONG-YOUNG; UNIV HOUSTON SYSTEM
摘要:A method for synthesis of a ferroelectric material characterized by the general formula A x B y F z where A is an alkaline earth metal, B is transition metal or a main group metal, x and y each range from about 1 to about 5, and z ranges from about 1 to about 20 comprising contacting an alkaline earth metal fluoride, a difluorometal compound and a fluoroorganic acid in a medium to form a reaction mixture; and subjecting the reaction mixture to conditions suitable for hydrothermal crystal growth.

专利号:EP-3697823-A1
优先权日:2017-10-17
标 题 :Method for the synthesis of fluoropolymers

专利号:EP-3697823-B1
优先权日:2017-10-17
标 题:Method for the synthesis of fluoropolymers