CAS: 18829-55-5; (E)-Hept-2-Enal

该化合物是一种不饱和的藻类,其特点是线性链结构,以及第二和第三个碳原子之间存在双重联系,以及一端的正丁基功能组.其分子分子式为C7H12O,其特征为一种变性,影响其物理特性和反应力.该化合物一般是无色的,可粉色黄色液体,具有独特,愉快的香味,以绿色苹果或新鲜草为迷彩色,因此对口味和香味行业感兴趣.跨-2-希敏性在有机溶剂中溶解,但由于水中具有疏水性,其溶解性有限.它因其反应性,特别是在发生氧化和添加反应时,可导致形成各种衍生物.此外,它被用作有机合成的中间体,可在某些天然产品中找到.安全考虑包括其潜在的刺激效应,需要适当的处理和储存规程.

结构式图片

相似化合物

18999-28-5 2548-87-0 33467-76-4

欧盟法规

ECHA物质ECHA物质化妆品禁用物质清单C&L通报REACH预注册

上下游产品

c-ene-1,4-diolhept-2c-ene-1,4-diol (Z)-1,1-Diethoxy-2-hepten 2-bromo-1,1-diethoxy-heptane (Z)-hept-2-en-1-ol(E,E)-2,4-nonadienal (E)-1-phenyl-2-hepten-1-one -5-tetradecen-8-ol(7R,5E)-7-(benzyloxy)methoxy-5-tetradecen-8-ol -5-tetradecen-9-yn-8-ol(7R,5E)-7-(benzyloxy)methoxy-5-tetradecen-9-yn-8-ol

合成工艺路线路线简述

  • 合成目标产物 Trans-2-Heptenal 主要起始原料 1-Hexene And Crotonaldehyde
  • (文献来源)合成步骤主要原料 1-Hexene 和 Crotonaldehyde
2-Bromoheptanal置于硫酸体系中,化学反应生成(E)-2-庚烯醛
参考文献:Duhamel,L.; Valnot,J.-Y.,Comptes Rendus Des Seances De L'Academie Des Sciences,Serie C: Sciences Chimiques,1978,Vol. 286,P. 47-50
标题:Duhamel,L.; Valnot,J.-Y.,Comptes Rendus Des Seances De L'Academie Des Sciences,Serie C: Sciences Chimiques,1978,Vol. 286,P. 47-50

海关参考信息

专利信息


专利号:US-2005004225-A1
优先权日:2003-04-16
标题:Oxidoreductase inhibitors and methods of screening and using thereof
发明人:BALENDIRAN GANESARATNAM K
摘要:The present invention relates to 1) the design and synthesis of analogs to glutathione conjugates which bind to or interact with aldose reductase (AR) through unique conformations that are distinctly different from the substrates and inhibitors of AR which are members of sugar metabolism; 2) the screening of the analogs to identify those that interact with or inhibit or enhance the activity of AR; and 3) the use of AR ligands, AR inhibitors (AR antagonsits) or AR enhancer (AR agonists) in the detection of AR activity, the modulation of AR activity, and the treatment of conditions in a subject in need of modulating AR activity. Such conditions include but not limited to cardiovascular disease, diabetes, artheriosclerosis, cancer, neoplasm, obesity, cataract, retinopathy, keratopathy, nephropathy, neurosis, thrombosis, faulty union of corneal injury and neuropathy. Examples of the treatment include the use of fibrates as AR inhibitors to treat these conditions.

专利号:US-11639418-B2
优先权日:2018-09-27
标 题:Synthesis process for one-step production of monomeric polyether for polycarboxylic acid water reducing agents
发明人:MA CAIFENG; LAI KE; LI YUBO
权利人:JIAHUA CHEMICALS FUSHUN NEW MAT CO LTD
摘要:Provided is a synthesis process for the one-step production of a monomeric polyether for polycarboxylic acid water reducing agents, wherein the monomeric polyether is synthesized in one step by mixing an initator and a catalyst at a temperature and a pressure, and then introducing same into a reaction kettle together with an epoxide at a certain ratio for ring opening polymerization. The synthesis process of the present invention realizes continuous production without the need of first synthesizing a prepolymer and then synthesizing a macromolecular monomeric polyether step by step, thereby improving the production efficiency. By separating four links, i.e. displacement, polymerization, curing and neutralization, in conventional monomeric polyether production processes, the present invention more effectively controls each of the links and increases the utilization efficiency of the reaction kettle; in addition, the process is easy to control, the structure of the product is stable, and the retention of double-bonds is high.

专利号:US-7329767-B2
优先权日:2003-10-03
标 题:Conjugated dienamides, methods of production thereof, compositions containing same and uses thereof
发明人:DEWIS MARK L; JOHN THUMPLASSERIL V; ECKERT MARKUS A; COLSTEE JAN HERMAN; DA COSTA NEIL C; PEI TAO
权利人:INT FLAVORS & FRAGRANCES INC
摘要:Described are mixtures of at least four of the alkadienamides defined according to the structure: n nwherein R represents C 1 -C 2 n-alkyl; R 1 is 2-methyl-1-propyl and R 2 is hydrogen, or R 1 and R 2 taken together is a moiety having the formulan n nwherein n is 4 or 5, or compositions containing substantial concentrations of such mixtures, prepared according to novel processes: (a) extraction of a ground substantially dried fruit of one of the Piper species, Piper longum Linn or Piper peepuloides ; (b) natural product-forming synthesis; or (c) synthetic product-forming synthesis. Also described are uses of the thus-formed products for augmenting, enhancing or imparting an aroma, taste, chemesthetic effect and/or antibacterial effect in or to a consumable material and/or in the oral cavity and/or on the mammalian epidermis.

专利号:US-8007841-B2
优先权日:2003-10-03
标 题 :Conjugated dienamides, methods of production thereof, compositions containing same and uses thereof
发明人:JOHN THUMPLASSERIL V; ECKERT MARKUS A; DEWIS MARK L; COLSTEE JAN HERMAN; DA COSTA NEIL C
权利人:INT FLAVORS & FRAGRANCES INC
摘要:Described are mixtures of at least four of the alkadienamides defined according to the structure: n nwherein R represents C 1 -C 2 n-alkyl; R 1 is 2-methyl-1-propyl and R 2 is hydrogen, or R 1 and R 2 taken together is a moiety having the formula —(CH 2 ) n —, wherein n is 4 or 5, or compositions containing substantial concentrations of such mixtures, prepared according to novel processes: (a) extraction of a ground substantially dried fruit of one of the Piper species, Piper longum Linn or Piper peepuloides ; (b) natural product-forming synthesis; or (c) synthetic product-forming synthesis. Also described are uses of the thus-formed products for augmenting, enhancing or imparting an aroma, taste, chemesthetic effect and/or antibacterial effect in or to a consumable material and/or in the oral cavity and/or on the mammalian epidermis.

专利号:US-2025109161-A1
优先权日:2021-11-30
标 题 :Heme, compositions and method of synthesis thereof
发明人:LEONG TAI WEI DAVID; ANG WEE HAN; LEONG LAI PENG; THAM JING RUI
权利人:NAT UNIV SINGAPORE
摘要:The present disclosure concerns heme and methods of synthesis thereof. The present disclosure also concerns to compositions and products thereof. The heme composition comprises heme at about 0.05% w/w to about 1% w/w relative to the heme composition and an antioxidant at about 0.25% w/w to about 5% w/w relative to the heme composition, wherein the heme is derived from protoporphyrin IX extracted from a plant, algal, bacterial and/or animal source.

专利号:US-10099987-B2
优先权日:2014-12-16
标 题:Process for preparing synthesis intermediates using products of natural origin and use of the intermediates obtained
发明人:GRISON CLAUDE; ESCANDE VINCENT; STANOVYCH ANDRII
权利人:CENTRE NAT RECH SCIENT; UNIV MONTPELLIER
摘要:Disclosed is a process for preparing a product of formula I: wherein the reaction is catalyzed both by thiamine or a thiamine salt and by ascorbic acid in a form which is free or salified or an organic acid salt of an alkaline metal, preferably sodium acetate, potassium tartrate, sodium succinate, or a reductone, preferably 2-hydroxypropanedial or 2,3-dihydroxycyclopent-2-ene-1-one in an organic solvent.
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主要参考文献

参考标题:A Lanthanide(III) Triflate Mediated Macrolactonization/solid-Phase Synthesis Approach For Depsipeptide Synthesis
作者:Jordan D. Goodreid,Eduardo Da Silveira Dos Santos,Robert A. Batey |发布日期:2015.5.1
摘要:The Effect Of Dysprosium(III) Triflate On Macrolactonization Reactions To Form Depsipeptides Using Mnba (Shiina'S Reagent) Is Reported. Improved Yields Were Obtained For The Formation Of 16-Membered Depsipeptides Using Lanthanide Triflate Additives. The Use Of A Macrocyclization Strategy Permits The Use Of A Semiautomated Solid-Phase Synthesis Approach For The Rapid Synthesis Of Analogues Of The Antibacterial

合成参考文献


摘要:Nahm Garrett, M.; Johnson, J. S., Science of Synthesis Knowledge Updates, (2012) 2, 76.
摘要:Araki, S.; Hirashita, T., Science of Synthesis Knowledge Updates, (2010) 4, 144.
摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 222.
摘要:Delvos, L. B.; Oestreich, M., Science of Synthesis Knowledge Updates, (2017) 1, 122.
摘要:Khartulyari, A.; Maier, M. E., Science of Synthesis Knowledge Updates, (2010) 3, 100.
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