CAS: 1731-86-8; Methyl Undecanoate

该化合物是非十二硝酸和甲醇产生的酯,其特点是化学配方C12H24O2.它是一种无色的黄液,其色味令人愉快,有水果味,有助于调味和香味应用.甲基非十二硝酸酯在水中溶解,但在有机溶剂中可溶解,这是许多酯的典型特征.它的沸点相对较小的酯而言相对较高,反映了其较大的分子体积.该化合物具有中等的挥发性,可通过酯化过程合成,在酸催化剂的出现下,非十二酸与甲醇发生反应.甲基非十二硝酸盐也有益于生物柴油的生产领域,因为它可以从植物油中的脂肪酸中衍生出来.此外,它可用于表面活性剂的生产,并在各种化学过程中用作溶剂.安全数据表明,应谨慎处理,因为接触皮肤或眼睛时可能会引起刺激.

结构式图片

相似化合物

112-37-8 112-42-5 112-44-7

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号111-81-9 10-十一烯酸甲酯 | CAS号67-56-1 甲醇 | CAS号872-05-9 正癸烯 | CAS号201230-82-2 carbon monoxide | CAS号186581-53-3 重氮甲烷 | CAS号112-37-8 十一酸 | CAS号6287-90-7 11-溴代十一烷酸甲酯 | CAS号2050-77-3 1-碘癸烷 | CAS号7755-92-2 N-甲酰基哌嗪 | CAS号2834-05-1 11-溴十一酸 | CAS号4282-44-4 碘十一烷 | CAS号26902-72-7 1,1,1-trifluoro... | CAS号629-97-0 二十二烷 | CAS号1120-21-4 正十一烷 | CAS号112-42-5 十一醇 | CAS号176437-56-2 2-diazonio-1-me... | CAS号24724-07-0 Methyl 11-hydro... | CAS号1931-65-3 methyl 11-oxoun... | CAS号75584-12-2 1-dimethoxyphos... | CAS号89231-71-0 methyl 11-(°Cty...

合成工艺路线路线简述

    📜10-烯酸甲酯置于dichlorobis(2-(二苯基膦)乙胺)钌(II),氢气,Sodium Methylate体系中,化学反应生成十一酸甲酯
    参考文献:用钌催化剂选择性氢化不饱和酯和醛的可持续方法
    标题:用钌催化剂选择性氢化不饱和酯和醛的可持续方法
    摘要:温和条件下的选择性:比较了三种最先进的市售 Ru 催化剂在 40 oc 和 5 Bar 氢气条件下以苯甲醚用作溶剂选择性氢化含有 C=c 的酯和醛.
    Doi:10.1002/cctc.202300394

    海关参考信息

    专利信息


    专利号:US-2014194584-A1
    优先权日:2013-01-07
    标题 :Process for the synthesis of w-Unsaturated nitrile-acid/ester in which two types of cross metathesis are alternated consecutively swing process
    发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC
    权利人:ARKEMA FRANCE
    摘要:The invention relates to a process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound I comprising at least one trivalent nitrile, acid or ester functional group, characterized in that it comprises a stage in which two types of cross metathesis are alternated consecutively:n a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II comprising a nitrile functional group and the other of these compounds II or I comprising an acid or ester functional group, and a second type of cross metathesis cm2 with a light C 2 to C 4 alkene compound III, preferably with ethylene. nn The invention also relates to a process for the synthesis of an α,ω-amino ester (acid) obtained by a process comprising a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.

    专利号:WO-2025105947-A1
    优先权日:2023-11-15
    标 题 :Synthesis of polyols and polyesters by chemical degradation of industrial rubbers and natural rubbers for application in new polymer materials
    发明人:TREVIÑO QUINTANILLA CECILIA DANIELA; BURELO TORRES JOSÉ MANUEL
    权利人:INST TECNOLOGICO ESTUDIOS SUPERIORES MONTERREY
    摘要:The present invention relates to a process for synthesising and obtaining biobased hydroxyl-terminated telechelic oligomers, such as biobased hydroxyl-terminated polybutadiene, by means of a degradation reaction via metathesis of industrial rubbers and using fatty alcohols as chain transfer agents (CTA). In particular, the present invention relates to the synthesis and production of diols, polyols and polyesters based on a degradation reaction via metathesis between industrial rubbers or natural rubbers and essential oils, fatty acids, fatty alcohols and terpenes with R-OH and R-COO-R terminal groups, the chemical structure, molecular weight and properties of which can be controlled.

    专利号:EP-2134675-B1
    优先权日:2007-04-06
    标题 :Method for the co-production of cyclic carbonates and amino acids
    发明人:DUBOIS JEAN-LUC
    权利人:ARKEMA FRANCE
    摘要:The invention relates to a conjugated method for the production of ?-amino-alkanoic acids and polyol carbonates from a natural monounsaturated fatty acid, comprising the following zones: I) zone for methanolysis of a natural oil containing a triglyceride with at least one monounsaturated fatty acid, producing methanolate from the fatty acid and glycerol; II) zone for synthesis of the ?-amino-alkanoic acid, comprising the following steps, namely (a) transformation of the methanolate into a ?-unsaturated fatty ester, either by ethenolysis of the methanolate or pyrolysis of a methanolate including an OH, (b) hydrolysis of the ester formed, (c) hydrobromination of the ?-unsaturated acid obtained in step (b) and (d) amination with ammonia of the compound resulting from the hydrobromination in step (C); III) zone for synthesis of a polyol carbonate by reacting urea either directly on the glycerol or on a diol obtained by hydrogenation reduction of the glycerol, the reaction of the polyol with the urea producing ammonia; IV) zone for recovery of the ammonia produced in zone III as well as that produced in zone IId where the reaction is performed with excess ammonia, for use in the amination of step (d) of zone II.

    专利号:EP-2137133-B1
    优先权日:2007-04-06
    标题 :Method for the co-production of non-cyclic carbonates and amino acids
    发明人:DUBOIS JEAN-LUC
    权利人:ARKEMA FRANCE
    摘要:The invention relates to a conjugated method for the production of ?-amino-alkanoic acids and dialkylcarbonates having formula R1O-CO-OR1,in which R1 has between 1 and 4 carbon atoms, from an unsaturated fatty acid ester, comprising the following reaction zones: I) zone for synthesis of the ?-amino-alkanoic acid with transformation of the fatty acid ester into a ?-unsaturated fatty ester, either by ethenolysis or pyrolysis, followed by hydrolysis of the ester into acid with formation of alcohol R1OH which is recovered and sent to zone III, subsequent hydrobromination of the ?-unsaturated acid obtained, followed by amination with excess ammonia to form the ?-amino-alkanoic acid, the excess ammonia being recycled in zone IV; II) zone for synthesis of a dialkylcarbonate having formula R1O-CO-OR1 by reaction with urea of R1OH originating from zone I via zone III, the ammonia produced being sent to zone IV; III) zone for recovery and purification of alcohol R1OH; and IV) zone for recovery and purificaiton of the ammonia originating from zones I and II for use as a reagent for the amination of zone I.

    专利号:US-4233128-A
    优先权日:1978-05-05
    标 题:Photosynthesis of mercaptans
    发明人:OLLIVIER JEAN; SOULOUMIAC GUY; SUBERLUCQ JEANNINE
    权利人:ELF AQUITAINE
    摘要:Synthesis of mercaptans by the photochemical reaction of an olefin with hydrogen sulphide in the presence of an initiator constituted by benzophenone, thiobenzophenone or a mixture of the two, preferably accompanied by an organic compound of an element of Group VA of the Periodic Classification. These initiators can carry substituents on either or both of the two benzene rings. The light utilized can have a wavelength of 300 to 600 nm. The process allows various mercaptans to be obtained with good yields.

    专利号:US-6368831-B1
    优先权日:1998-06-29
    标题 :Treatment of hyperproliferative disorders
    发明人:MAURER BARRY J; REYNOLDS C PATRICK
    权利人:LOS ANGELES CHILDRENS HOSPITAL
    摘要:A method of treating a hyperproliferative disorder in a subject in need of such treatment, comprising administering to said subject, in combination, a treatment effective amount of: (a) a ceramide-generating retinoid such as fenretinide or a pharmaceutically acceptable salt thereof; and (b) at least one (and in certain embodiments at least two) ceramide degredation inhibitor, such as compounds selected from the group consisting of (i) glucosylceramide synthesis inhibitors and/or 1-acylceramide synthesis inhibitors, (ii) sphingosine-1-phosphate synthesis inhibitors, and (iii) protein kinase C inhibitors. A preferred glucosyl ceramide synthesis inhibitor is 1-phenyl-2-palmitoylamino-3-morpholino-1-propanol. A preferred sphingosine-1-phosphate synthesis inhibitor is D-erythro-N,N-dimethylsphingosine. A preferred protein kinase C inhibitor is L-threo-dihydrosphingosine.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Cristina Cruz-Hernandez, Et Al. Direct Quantification Of Fatty Acids In Human Milk By Gas Chromatography. J Chromatogr A. 2013 Apr 5;1284:174-9.
    [参考文献]: Jana Orsavova, Et Al. Fatty Acids Composition Of Vegetable Oils And Its Contribution To Dietary Energy Intake And Dependence Of Cardiovascular Mortality On Dietary Intake Of Fatty Acids. Int J Mol Sci. 2015 Jun 5;16(6):12871-90.

    合成参考文献


    参考文献:10.1007/s10068-019-00558-z
    摘要:Lee NK, Jang KH, Lee JT, Kim JB, Han ST, In G. Studies on the physicochemical characteristics of the New Zealand deer’s tail, Cervus elaphus var. scoticus (III). Food Science and Biotechnology. 2019 Mar 02;28(4):1013–25. doi: 10.1007/s10068-019-00558-z.
    摘要:Journal of the Reticuloendothelial Society., 3(250), 1966
    摘要:Evano, G., Science of Synthesis, (2007) 20, 797.
    摘要:Yus, M.; Nájera, C.; Chinchilla, R., Science of Synthesis, (2007) 20, 782.
    摘要:Yus, M.; Nájera, C.; Chinchilla, R., Science of Synthesis, (2007) 20, 643.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知