CAS: 1317-37-9; Black Iron Sulfide

该化合物是一种无机化合物,由铁和硫组成,通常以黑或深褐固体的形式出现,根据合成条件,呈现出六边形或四边形晶体结构,主要优势包括高热稳定性,半导体特性和作为消化剂的活性. 硫化铁作为脱硫剂和硫化氢合成(H2S)在钢生产中广泛用于冶金中. 其磁性使其与材料科学相关,而与工业工艺的兼容性则确保其具有成本效益的应用. 由于其电化学特性,还研究硫化物在腐蚀抑制和电池技术中的作用.

结构式图片

合成工艺路线路线简述

    白铁矿 反应生成硫化亚铁
    参考文献:Ma,Robert P.;Felder,Richard M.;Ferrell,James K.,Ind. And Eng. Chem. Res.,28,(1989) N,C. 27-33
    标题:Ma,Robert P.;Felder,Richard M.;Ferrell,James K.,Ind. And Eng. Chem. Res.,28,(1989) N,C. 27-33

    专利信息


    专利号:WO-2020215726-A1
    优先权日:2019-04-26
    标题:Recycling process of waste generated in synthesis of thioacetic acid
    发明人:ZHANG SHIJIN; ZHANG XIANGZHOU; LIU DUNSHENG; MA ZHAOFENG
    权利人:TENGZHOU TIANSHUI BIO TECH CO LTD
    摘要:A recycling process of waste generated in synthesis of thioacetic acid, comprising: in a thioacetic acid synthesis process, pretreating a thioacetic acid synthesis reaction solution, transferring the reaction solution to a filter device, separating a solid phase from a liquid phase in the reaction solution, and separating waste from the reaction solution in advance; and treating the separated solid phase: washing the solid phase, and performing separation after the washing; feeding the washed solid phase into a drier for drying, separating the dried solid, and condensing the liquid phase; adding the dried solid into a dissolving kettle, adding water into the kettle, stirring and heating to micro-boiling and reflux, so that the dried solid is fully dissolved; then adding a potassium hydroxide solution into the solution for neutralization, during which boiling should be prevented and which lasts for not shorter than 5 min; filtering a neutralization solution, and separating solid precipitate therefrom; neutralizing a filtrate obtained after the filtration to perform evaporative concentration, and primarily separating water from monopotassium phosphate; performing a further separation operation on a monopotassium phosphate concentrated solution, the solid obtained after the separation being a monopotassium phosphate product; and repeating the previous step for re-concentration.

    专利号:US-8394421-B2
    优先权日:2008-07-30
    标 题:Synthesis of nanoparticles by fungi
    发明人:MANSOORI G ALI
    权利人:MANSOORI G ALI; UNIV ILLINOIS
    摘要:Systems and methods for synthesizing silver nanoparticles (SNPs) using Trichoderma fungi have been developed. In an aspect, Trichoderma reesei was used for the extracellular synthesis of silver nanoparticles. In the biosynthesis of metal nanoparticle by a fungus, one or more enzymes or metabolites are produced that reduce a salt to its metallic solid nanoparticles through a catalytic process.

    专利号:US-4592814-A
    优先权日:1983-05-23
    标题:Electrochemical synthesis of humic acid and other partially oxidized carbonaceous materials
    发明人:VAUGHAN RONALD J; BY BANK OF AMERICA NT SA ADMIN
    权利人:CHEVRON RES
    摘要:A continuous cyclic electrolytic/carbon oxidation process wherein ferrous ion is oxidized at the anode and hydrogen is generated at the cathode of an electrolytic cell. The ferric ions produced at the anode are thereafter reduced to ferrous ions by contact with a solid carbonaceous material and the ferrous ions recycled for electrochemical reoxidation. The process produces partially oxidized organic products from the combustion process in high yield.

    专利号:WO-2022168062-A1
    优先权日:2021-02-08
    标题:Variants of hyperthermophilic carboxylesterase for polymer synthesis
    发明人:PIRES CARVALHO ALEXANDRA TERESA; LOPES COLUMBANO MARQUES ALMEIDA BEATRIZ; REIS FIGUEIREDO PEDRO MIGUEL; ANDRADE RIBEIRO DOURADO DANIEL FERNANDO; PAUL STEPHANIE; QUINN DEREK JOHN; MOODY THOMAS S; FERNANDES DE SOUSA PAULA ANDREIA; DOMINGUES SILVESTRE ARMANDO JORGE DOMINGUES SILVESTRE
    权利人:UNIV DE COIMBRA; UNIV AVEIRO
    摘要:The present invention discloses enzymatic variants comprising a sequence comprising at least one amino acid substitution at a position selected from the group consisting of mutations located close to the oxyanion hole region, mutations close to the catalytic His-Asp pair and/or mutations close to residues that interact with the lactone-ring and mutations outside the active site. A process for the synthesis of polymers comprising the step of using an enzymatic variant according to the invention is also disclosed, as well as the use of the enzymatic variants of the invention in biotechnology, in particular in polymer synthesis, in material industry and/or for biomedical applications.

    专利号:US-12172152-B1
    优先权日:2024-05-10
    标 题 :Synthesis and application of zinc cobalt oxide/sulfide nanorods for photocatalytic water splitting and carbon dioxide reduction
    发明人:TAHIR MUHAMMAD
    权利人:UNIV UNITED ARAB EMIRATES
    摘要:There is disclosed photoactive, one-dimensional zinc and cobalt-based bimetallic oxide and sulfide nanorods (ZnCo2O4 NRs, ZnCo2S4 NRs) and their heterojunction composites (1D/1D ZnCo2O4/ZnCo2S4) to be used as photocatalysts for hydrogen production and carbon dioxide reduction using solar energy. Also disclosed herein, is a method of synthesizing these compounds via hydrothermal processes and a self-assembly approach. 1D/1D heterojunctions of ZnCo2O4/ZnCo2S4 composites exhibit favourable interface interactions. The photocatalytic performance of both pure and composite materials is evaluated through water splitting to produce hydrogen and CO2 reduction to yield CO and CH4 using slurry phase and fixed bed photoreactor systems. ZnCo2S4 NRs demonstrate superior hydrogen production whereas CO2 reduction is more pronounced with ZnCo2O4. The highest photocatalytic efficiency is achieved using the heterojunction composites attributed to efficient charge carrier separation facilitated by a suitable band structure. The invention underscores the successful synthesis of highly efficient 1D structured materials for photocatalytic applications.

    专利号:US-11932966-B2
    优先权日:2020-04-16
    标 题 :Metal sulfide filled carbon nanotubes and synthesis methods thereof
    发明人:LI WENZHI; POUDEL YUBA
    权利人:LI WENZHI; POUDEL YUBA; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES
    摘要:Filled carbon nanotubes (CNTs) and methods of synthesizing the same are provided. An in situ chemical vapor deposition technique can be used to synthesize CNTs filled with metal sulfide nanowires. The CNTs can be completely and continuously filled with the metal sulfide fillers up to several micrometers in length. The filled CNTs can be easily collected from the substrates used for synthesis using a simple ultrasonication method.
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    主要参考文献

    [参考文献]: Amnorzahira Amir, Et Al. Enhanced Reductive Dechlorination Of Tetrachloroethene During Reduction Of Cobalamin (Iii) By Nano-Mackinawite. J Hazard Mater. 2012 Oct 15:235-236:359-66.
    [参考文献]: Bin Huang, Et Al. Removal Of Highly Elevated Nitrate From Drinking Water By Ph-Heterogenized Heterotrophic Denitrification Facilitated With Ferrous Sulfide-Based Autotrophic Denitrification. Bioresour Technol. 2011 Nov;102(21):10154-7.
    [参考文献]: Mahesh Sundararajan, Et Al. The Mechanism Of The Reduction Of [参考文献]: N Finck, Et Al. Selenide Retention By Mackinawite. Environ Sci Technol. 2012 Sep 18;46(18):10004-11.
    [参考文献]: Romain Guilbaud, Et Al. Abiotic Pyrite Formation Produces A Large Fe Isotope Fractionation. Science. 2011 Jun 24;332(6037):1548-51.
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