CAS: 994-31-0; Triethyltin Chloride

该化合物是有机锡化合物,其特征是附于氯化离子的三乙基化合物,它看起来无色无色,是黄色液体,以其高毒性和潜在的环境危害著称;该化合物在有机溶剂中溶解,但在水中溶解性有限;三乙基氯主要用于各种工业用途,包括生物杀灭剂,海洋油漆中的防污剂和其他有机锡化合物的合成;其化学结构允许它与生物系统互动,导致重大的生态问题,特别是其持久性和在水生环境中的生物累积问题;由于其毒理学特征,处理三乙基氯需要严格的安全措施,以尽量减少接触和环境影响;其使用经常受到监管,反映了对有机锡化合物进行认真管理的必要性,以减轻其对人类健康和生态系统的不利影响.

结构式图片

上下游产品

CAS号7787-60-2 氯化铋 | CAS号997-50-2 triethyltin | CAS号75-29-6 2-氯丙烷 | CAS号597-64-8 四乙基锡 | CAS号100-44-7 氯化苄 | CAS号1015-27-6 triethyl(2-phen... | CAS号993-63-5 Hexaethyldistannane | CAS号7646-78-8 四氯化锡 | CAS号7784-34-1 三氯化砷 | CAS号7727-18-6 三氯氧钒 | CAS号1067-21-6 triethyl(methox... | CAS号1015-27-6 triethyl(2-phen... | CAS号15238-97-8 triethylstannyl... | CAS号17973-82-9 Distannoxane,1,... | CAS号79349-30-7 chlorodiethyl(h... | CAS号2117-47-7 Triethyl(vinyl)... | CAS号597-64-8 四乙基锡 | CAS号1461-25-2 四丁基锡 | CAS号17582-53-5 butyl triethyltin | CAS号20525-62-6 Dibutyldiethyls...

合成工艺路线路线简述

    📜四乙基锡置于silver Tetrafluoroborate,Sodium Chloride体系中,用 水,乙腈 作为反应溶剂,化学反应生成 三乙基氯化锡
    参考文献:Reactions Of Peralkyl Organotin And Organomercury Compounds With Di-And Triarylmethyl Salts
    标题:Reactions Of Peralkyl Organotin And Organomercury Compounds With Di-And Triarylmethyl Salts
    摘要:
    DOI:10.1007/bf00948069

    海关参考信息

    专利信息


    专利号:US-5502126-A
    优先权日:1993-06-17
    标 题 :Process for the synthesis of isoprene butadiene rubber
    发明人:BELL ANTHONY J; MATRANA BARRY A; HALASA ADEL F
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component; (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component; and (3) adding a compound which contains at least one labile halogen atom to the Group III-B metal containing catalyst component.

    专利号:US-8933181-B2
    优先权日:2006-10-06
    标题:Branched polymers and methods for their synthesis and use
    发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
    权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
    摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

    专利号:WO-2005051943-A1
    优先权日:2003-11-28
    标题:Processes for the preparation of highly pure irbesartan
    发明人:KUMAR YATENDRA; PRASAD MOHAN; NATH ASOK; ARORA SURINDER KUMAR
    权利人:RANBAXY LAB LTD; KUMAR YATENDRA; PRASAD MOHAN; NATH ASOK; ARORA SURINDER KUMAR
    摘要:The present invention relates to processes for synthesis of highly pure irbesartan or pharmaceutically acceptable salts thereof.

    专利号:US-6624116-B1
    优先权日:1998-09-03
    标 题 :On-line synthesis and regeneration of a catalyst used in autothermal oxidation
    发明人:BHARADWAJ SAMEER S; MAJ JOSEPH J; SIDDALL JONATHAN H
    权利人:DOW GLOBAL TECHNOLOGIES INC
    摘要:An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.

    专利号:US-2003125487-A1
    优先权日:2001-12-31
    标题 :Group III-B metal catalyst system
    发明人:HSU WEN-LIANG; HALASA ADEL FARHAN; JASIUNAS CHAD AARON
    权利人:HSU WEN-LIANG; HALASA ADEL FARHAN; JASIUNAS CHAD AARON
    摘要:The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system that is comprised of (I) a compound which contains at least one labile halogen atom and (II) a Group III-B metal containing catalyst component which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component, and (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component.

    专利号:US-11767388-B1
    优先权日:2019-09-18
    标 题 :Silicon-functionalized rubber
    发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 166.
    摘要:Tchabanenko, K., Science of Synthesis Knowledge Updates, (2013) 1, 3.
    摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 191.
    摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 190.
    摘要:Ielo, L.; Pace, V., Science of Synthesis: Knowledge Updates, (2025) 2.
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