CAS: 81-30-1; 1,4,5,8-Naphthalenetetracarboxylic Dianhydride

该化合物是一种高纯度有机化合物,主要用作包括聚酰胺,染料和颜料在内的先进材料合成中的关键中间体.其硬性,平板结构和反应性六氢化物组体对于生产具有极佳机械和电特性的热稳定聚合物很有价值. NTCDA还因其电子接受能力而被用于制造n型有机半导体,有助于有机电子和光电装置的应用.该化合物的高热稳定性和化学抗药性进一步增强了其对要求工业和研究应用的适宜性. 需要妥善处理,因为其具有湿度和氨的再活性.

结构式图片

相似化合物

83204-68-6 299962-88-2 846-20-8

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

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合成工艺路线路线简述

  • 合成目标产物 1,4,5,8-Naphthalenetetracarboxylic Dianhydride 主要起始原料 1,4,5,8-Naphthalenetetracarboxylic Acid 1,8-Monoanhydride And 1,4,5,8-Naphthalenetetracarboxylic Acid
  • 128-97-2 = 81-30-1
    反应条件:1.1 Solvents: Acetic Acid; 16 H,Reflux
    标题:Dinaphtho[1,8-Bc:1',8'-Fg][1,5]Dithiocine Bisimide
    作者:Tanaka,Yuki; Et Al
    参考文献:Asian Journal Of Organic Chemistry 日期:2021 卷标:10(3) 页码:541-544]

    129-00-0 = 81-30-1
    反应条件:1.1 Reagents: Sodium Dichromate Catalysts: Sulfuric Acid Solvents: Water2.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13]

    102117-67-9 = 81-30-1
    反应条件:1.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13]

    102117-68-0 = 81-30-1
    反应条件:1.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13]

    35147-76-3 = 81-30-1
    反应条件:1.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13]

    65593-62-6 = 81-30-1
    反应条件:1.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13]

    = 81-30-1
    反应条件:1.1 Reagents: Oxygen Solvents: Dichloromethane; 12 - 60 Min2.1 Reagents: Oxygen Solvents: Dichloromethane
    标题:Ntcda-Ttf First Axial Fusion: Emergent Panchromatic,Nir Optical,Multi-State Redox And High Optical Contrast Photooxidation
    作者:Asthana,Deepak; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2012 卷标:48(52) 页码:6475-6477]

    1785-51-9 = 81-30-1
    反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Water2.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13]

    128-97-2 = 81-30-1
    反应条件:1.1 Reagents: Sulfur Tetrafluoride
    标题:Fluorination By Sulfur Tetrafluoride
    作者:Wang,Chia-Lin J.
    参考文献:Organic Reactions (Hoboken 日期:1985 卷标:34]

    129-00-0 = 81-30-1
    反应条件:1.1 Reagents: Acetic Acid,Cobalt Diacetate; 110 °C; 10 Min,40 °C1.2 Reagents: Acetic Acid,Peracetic Acid; 50 °C1.3 Reagents: Potassium Hydroxide,Sodium Hypochlorite; Ph 10,50 °C1.4 Reagents: Sodium Bicarbonate; Ph 1,80 °C1.5 Reagents: Hydrochloric Acid; Cooled
    标题:New Xanthene Structures
    作者:Iscrulescu,Lucian; Et Al
    参考文献:Revista De Chimie (Bucharest 日期:2008 卷标:59(5) 页码:578-581]

    17273-80-2 = 81-30-1
    反应条件:1.1 Reagents: Sodium Iodide,Cadmium Chloride; > 3 H,3 Mpa,430 - 450 °C; Cooled1.2 Reagents: Water1.3 Reagents: Hydrochloric Acid Solvents: Water; Rt; 1 H,Ph 1 - 2,Rt1.4 Solvents: Methanol; Rt; > 6 H,150 °C
    标题:Synthesis And Structural Characterization Of Organic Semiconductor Ntcda
    作者:Li,Jian-Feng; Et Al
    参考文献:Gongneng Cailiao Yu Qijian Xuebao 日期:2007 卷标:13(6) 页码:630-634]

    = 81-30-1
    反应条件:1.1 Reagents: Oxygen Solvents: Dichloromethane
    标题:Ntcda-Ttf First Axial Fusion: Emergent Panchromatic,Nir Optical,Multi-State Redox And High Optical Contrast Photooxidation
    作者:Asthana,Deepak; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2012 卷标:48(52) 页码:6475-6477]

    2304-85-0 + 1785-51-9 = 81-30-1
    反应条件:1.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13]

    52671-72-4 = 81-30-1
    反应条件:1.1 Solvents: Acetic Anhydride; 18 H,140 °C
    标题:Electronic And Assembly Properties Of A Water-Soluble Blue Naphthalene Diimide
    作者:Welsh,Thomas A.; Et Al
    参考文献:New Journal Of Chemistry 日期:2021 卷标:45(31) 页码:14005-14013]

    52671-72-4 = 81-30-1
    反应条件:1.1 Solvents: Toluene,Dimethylacetamide; 2 H,111 °C; 111 °C -> 10 °C; Overnight,10 °C
    标题:Conformationally Rigid Molecular And Polymeric Naphthalene-Diimides Containing C6H6N2 Constitutional Isomers
    作者:Abbinante,Vincenzo Mirco; Et Al
    参考文献:Journal Of Materials Chemistry C: Materials For Optical And Electronic Devices 日期:2021 卷标:9(33) 页码:10875-10888]

    81-30-1 = 81-30-1 [标题:Reaction Conditions
    标题:Stack Exchange Strategies For The Synthesis Of Covalent Double-Channel Photosystems By Self-Organizing Surface-Initiated Polymerization
    作者:Sakai,Naomi; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2011 卷标:133(46) 页码:18542-18545]

    102117-70-4 = 81-30-1
    反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water2.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13]

    65593-63-7 = 81-30-1
    反应条件:1.1 Reagents: Sulfuric Acid2.1 Reagents: Potassium Hypochlorite Solvents: Water
    标题:Derivatives Of 1,4,5,8-Naphthalenetetracarboxylic Acid. Iv. Oxidation Of 1,6- And 1,8-Pyrenequinones With Alkali Metal Hypochlorites
    作者:Shigalevskii,V. A.; Et Al
    参考文献:Zhurnal Organicheskoi Khimii 日期:1985 卷标:21(7) 页码:1506-13
1,4,5,8-萘四甲酸 以 N,N-二甲基乙酰胺 作为反应溶剂,化学反应 2.0H,反应生成 1,4,5,8-萘四甲酸酐
参考文献:Method For Producing Carboxylic Acid Anhydride,Method For Producing Carboxylic Imide,And Method For Manufacturing Electrophotographic Photosensitive Member
标题:Method For Producing Carboxylic Acid Anhydride,Method For Producing Carboxylic Imide,And Method For Manufacturing Electrophotographic Photosensitive Member
摘要:生产羧酸酐的方法包括加热含有特定化合物的溶剂中的混合物,以产生羧酸酐.该溶剂是具有沸点为50oc或更高的无水极性溶剂.

海关参考信息

专利信息


专利号:US-2008146772-A1
优先权日:2006-11-02
标题 :Materials and methods for co-crystal controlled solid-state synthesis of imides and imines
发明人:ZAWOROTKO MICHAEL J; CHENEY MIRANDA L
权利人:UNIV SOUTH FLORIDA
摘要:The subject invention pertains to methods for solid-state synthesis of imides and imines using co-crystals. The co-crystal formers utilized are substrates of condensation reactions and co-crystals can be obtained in high yield via methods such as slurrying, solvent evaporation, solvent crystallization, treatment with supercritical fluid(s), melting plus crystallization, slurry conversion, grinding of solids, blending of powders, heating of solids, solvent-drop grinding, or grinding plus melting.

专利号:WO-2024208875-A1
优先权日:2023-04-03
标题:Organic reinforcement of a polyamide with the in situ synthesis of a polyimide phase by reactive extrusion
发明人:CASSAGNAU PHILIPPE; DELAGE KARIM; BOUNOR-LEGARE VÉRONIQUE; MARESTIN CATHERINE; DUBOIS CHARLOTTE; GAROIS NICOLAS
权利人:TOTALENERGIES ONETECH; UNIV CLAUDE BERNARD LYON 1 UCBL; CENTRE NAT RECH SCIENT; UNIV JEAN MONNET SAINT ETIENNE UJM; INSTITUT NAT DES SCIENCES APPLIQUEES DE LYON INSA LYON
摘要:The disclosure relates to a reinforced polyamide and to a process to produce a reinforced polyamide comprising providing components being one or more polyamides, one or more dianhydrides, and one or more diamines; wherein the one or more polyamides are provided at a content of at least 60 wt.% based on the total weight of the components and wherein the one or more polyamides comprise at least one polyamide having amide groups separated by at least 10 CH2 groups; performing in situ synthesis of a polyimide by reactive extrusion of the components wherein the residence time is less than 10 minutes; and recovering a polyamide-polyimide blend being a reinforced polyamide comprising a continuous polyamide phase and a polyimide dispersed phase.

专利号:WO-2024170663-A1
优先权日:2023-02-15
标 题:Organic reinforcement of an elastomer with the in situ synthesis of a polyimide phase by reactive extrusion
发明人:CASSAGNAU PHILIPPE; DELAGE KARIM; BOUNOR-LEGARE VÉRONIQUE; MARESTIN CATHERINE; DUBOIS CHARLOTTE; GAROIS NICOLAS
权利人:TOTALENERGIES ONETECH; UNIV CLAUDE BERNARD LYON 1 UCBL; CENTRE NAT RECH SCIENT; UNIV JEAN MONNET SAINT ETIENNE; INSTITUT NAT DES SCIENCES APPLIQUEES DE LYON INSA LYON
摘要:The present disclosure relates to a process to produce a reinforced elastomeric material and to the reinforced elastomeric material. The process comprises the steps of providing components comprising a grafted elastomer, one or more dianhydrides, and one or more diamines; wherein the grafted elastomer is provided at a content of at least 60 wt.% based on the total weight of the components; performing in situ synthesis of a polyimide phase in the grafted elastomer by reactive extrusion of the components in a twin-screw extruder comprising main hopper wherein the screw profile comprises two or more reverse conveying elements forming two or more hot zones to form an elastomer-polyimide blend; and recovering said elastomer-polyimide blend being a reinforced elastomeric material.

专利号:WO-2024208876-A1
优先权日:2023-04-03
标题 :Ductile polyamide with the in situ synthesis of a polyimide phase by reactive extrusion
发明人:CASSAGNAU PHILIPPE; DELAGE KARIM; BOUNOR-LEGARE VÉRONIQUE; MARESTIN CATHERINE; DUBOIS CHARLOTTE; GAROIS NICOLAS
权利人:TOTALENERGIES ONETECH; UNIV CLAUDE BERNARD LYON 1 UCBL; CENTRE NAT RECH SCIENT; UNIV JEAN MONNET SAINT ETIENNE UJM; INSTITUT NAT DES SCIENCES APPLIQUEES DE LYON INSA LYON
摘要:The disclosure relates to a ductile polyamide and to a process to produce a ductile polyamide comprising providing components comprising one or more polyamides, one or more dianhydrides, and one or more diamines; wherein the one or more polyamides are provided at a content of at least 60 wt.% based on the total weight of the components; and wherein the one or more polyamides comprise at least one polyamide having amide groups separated by less than 10 carbon atoms; performing in situ synthesis of a polyimide by reactive extrusion of the components wherein the residence time is less than 10 minutes; and recovering a polyamide-polyimide blend being a ductile polyamide comprising a continuous polyamide phase and a dispersed polyimide phase.

专利号:EP-4428168-A1
优先权日:2023-03-08
标 题 :Polyurethane/oligomeric urethane synthesis method by radiation
发明人:AKBULUT HÜSEYIN; ÇEL KBA SENA; ENADA SEHER; U AKLI MÜGE; DEM RBAY DUYGU
权利人:CHT TURKEY KIMYA SANAYI VE TICARET A S
摘要:In particular, the invention relates to the synthesis of radiation-curable polyurethane/oligomeric urethane dispersions of anionic and cationic characters, containing neutralization techniques characterized by the selection of counter ions as monomers and/or agents which can be polymers acting as promoters under radiation, to a radiation polyurethane/oligomeric urethane synthesis method that enables the creation of radiation curable binder systems without using cosolvents, surfactants, emulsifiers, defoamers, stabilizers and additives, wherein all components of the radiation-curable binder systems can be polymerized.

专利号:US-2024408567-A1
优先权日:2023-06-09
标 题:Synthesis of porous carbon-based materials from expanded polystyrene
发明人:SAHA DIPENDU; GRAPPE HIPPOLYTE A
权利人:Eco Carbon LLC
摘要:A process for synthesizing a carbon molecular sieve and an activated carbon from expanded polystyrene is provided. The process includes sulfonating the expanded polystyrene with sulfuric acid in the presence of a solvent, for example, chloroform, to obtain sulfonated polystyrene; carbonizing the sulfonated polystyrene to obtain a carbon molecular sieve (CMS) with a substantially high degree of porosity; and activating the CMS by adding an activating agent to the CMS to obtain an activated carbon with a substantially high degree of porosity. The activating agent is selected from one or more of steam, potassium hydroxide, carbon dioxide, zinc chloride, phosphoric acid, sodium carbonate, aluminum chloride, magnesium chloride, and sodium hydroxide. A low temperature of, for example, about 50 degrees Celsius, is employed for sulfonating the expanded polystyrene. Heating and cooling operations in the steps of synthesizing and activating the CMS are performed under a nitrogen gas atmosphere.
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供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(90), 1982
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