专利号:US-2023416934-A1 优先权日:2022-06-27 标 题 :Acid-free pyrolytic synthesis of m-n-c catalyst 发明人:DELAFONTAINE LAURENT; ATANASSOV PLAMEN 权利人:UNIV CALIFORNIA 摘要:A method for making a catalyst includes a step of forming a first reaction mixture that includes a metal source, a nitrogen source, and at least one silica template. Characteristically, the at least one silica template including silica particles. A combination of the first reaction mixture and a fluorinated polymer is mechanochemically mixed to form a first pre-pyrolysis powder. A first pyrolysis of the first pre-pyrolysis powder is performed at a first temperature greater than about 800° C. under an inert atmosphere to form a first pyrolyzed composition. Advantageously, at least a portion of silica particles is removed and mesostructured carbon is formed. The first pyrolyzed composition is optionally mechanochemically mixing to form a second pre-pyrolysis powder. A second pyrolysis of the first first pyrolyzed composition or the second pre-pyrolysis powder is performed under a reductive atmosphere at a second temperature that is greater than about 800° C. to form a final catalyst powder.
专利号:US-2024327997-A1 优先权日:2023-03-28 标题 :Electrocatalytic Conversion of Nitrates and Nitrites to Ammonia 发明人:ATANASSOV PLAMEN; MURPHY EAMONN; LIU YUANCHAO; SPOERKE ERIK DAVID 权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC; UNIV CALIFORNIA 摘要:Electrocatalytic reduction of waste nitrates (NO3−) enables the synthesis of ammonia (NH3) in a carbon neutral and decentralized manner. The present invention uses atomically dispersed transition metal-nitrogen-carbon (M-N—C) catalysts with varying metal centers to uniquely favor mono-nitrogen products (e.g., NH3) via the electrochemical nitrate reduction reaction (NO3RR).
专利号:WO-2023192228-A1 优先权日:2022-03-28 标题:Electrocatalytic conversion of nitrates and nitrites to ammonia 发明人:ATANASSOV PLAMEN; MURPHY EAMONN; LIU YUANCHAO; SPOERKE ERIK 权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC; UNIV CALIFORNIA 摘要:Electrocatalytic reduction of waste nitrates (NO3') enables the synthesis of ammonia (NH3) in a carbon neutral and decentralized manner. The present invention uses atomically dispersed transition metal-nitrogen-carbon (M-N-C) catalysts with varying metal centers to uniquely favor mono-nitrogen products (e.g., NH3) via the electrochemical nitrate reduction reaction (NO3RR).
专利号:US-7846469-B2 优先权日:2006-08-04 标 题:Reversible inhibition of sperm receptor synthesis for contraception 发明人:BARBATO GUY F; MACDONALD ALEXANDER 权利人:PENN STATE RES FOUND; PHARMA SCIENCE INC 摘要:Methods and pharmaceutical compositions are disclosed for reversibly inhibiting sperm receptor activity in animals. Nicarbazin, its derivatives and modifications which retain pharmacological activity are shown to inhibit activity of zona pellucida proteins and concomitant synthesis and/or assembly of the sperm receptor on the oocyte surface necessary for fertilization. Nicarbazin is easily administered, for example by simple addition to feed of an animal and is and non-toxic to the animals, providing a safe and efficient means for controlling populations of mammals and avian species.
专利号:CN-1014518-B 优先权日:1988-09-23 标题:Process of direct synthesis of 4,4-dinitro-tripheryl urea
专利号:US-9673456-B2 优先权日:2013-01-16 标 题:Non-PGM catalysts for ORR based on charge transfer organic complexes 发明人:SEROV ALEXEY; ATANASSOV PLAMEN B 权利人:SEROV ALEXEY; ATANASSOV PLAMEN B 摘要:A sacrificial support-based method, a mechanosynthesis-based method, and a combined sacrificial support/mechanosynthesis support based method that enables the production of supported or unsupported catalytic materials and/or the synthesis of catalytic materials from both soluble and insoluble transition metal and charge transfer salt materials.
1: Bacila DM, Feddern V, Mafra LI, Scheuermann GN, Molognoni L, Daguer H. Current research, regulation, risk, analytical methods and monitoring results for nicarbazin in chicken meat: A perspective review. Food Res Int. 2017 Sep;99(Pt 1):31-40. doi: 10.1016/j.foodres.2017.07.011. Epub 2017 Jul 4. Review. doi: 10.1371/journal.pone.0181755. eCollection 2017. 3: Samiullah S, Roberts J, Wu SB. Downregulation of ALAS1 by nicarbazin treatment underlies the reduced synthesis of protoporphyrin IX in shell gland of laying hens. Sci Rep. 2017 Jul 24;7(1):6253. doi: 10.1038/s41598-017-06527-y. 4: Samiullah S, Roberts J, Wu SB. Reference gene selection for the shell gland of laying hens in response to time-points of eggshell formation and nicarbazin. PLoS One. 2017 Jul 3;12(7):e0180432. doi: 10.1371/journal.pone.0180432. eCollection 2017.
合成参考文献
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