CAS: 14059-33-7; Bismuth Vanadium Oxide

该化合物是一种以其独特的黄色颜色而闻名的无机化合物,主要用作包括油漆和涂层在内的各种应用中的色素;它是具有四角晶体结构的半导体材料,具有光催化特性,在光辐照下,在水分和污染物降解等环境应用中具有价值;BiVO4具有相对较高的稳定性,并且不有毒,因此它是其他可能含有有害元素的色素的有吸引力的替代物;该化合物的特点是能够吸收可见光,从而提高其光催化效率;此外,它有一个带间隔,使其能够在太阳能转换过程中有效发挥作用;Bismuth vanate可以通过各种方法合成,包括固态反应和软凝胶过程,其特性可以受到温度和多球的存在等因素的影响;

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

bismuth(III) oxide (17)Odioxygen-(17)O 0852V0.148O1.648Bi0852V0.148O1.648 bismuth vanadate0913V0.087(17)O1.587Bi0913V0.087(17)O1.587 0852V0.148(17)O1.648Bi0852V0.148(17)O1.648

合成工艺路线路线简述

    Bi2Mg0.16O(X)V0.84,γ' 以 Solid 用作溶剂,化学反应生成四氧化钒铋
    参考文献:Phase Transitions As A Function Of Temperature In Bimgvox
    标题:Phase Transitions As A Function Of Temperature In Bimgvox
    摘要:Phase Transitions In Bimgvox,Bi2Mgxv1-Xo5.5-3X/2-Delta,Have Been Studied Using A Combination Of A.C. Impedance Spectroscopy,Differential Thermal Analysis And Variable Temperature X-Ray Powder Diffraction. Two Composition Regions Were Examined. In The First,Below X = 0.10,Phase Transitions Associated With The Alpha,Beta And Gamma-Phases Are Observed. In The Second Region Above X = 0.10 The Gamma' <----> Gamma Transition Is Clearly Observable. Trends In The Refined Unit Cell Parameters Were Particularly Indicative Of The Phase Transitions. The Results Are Compared To Those Obtained For Parent Compound Bi4V2O11-Delta.
    Doi:10.1002/pssa.200306622

    专利信息


    专利号:US-2014342254-A1
    优先权日:2013-05-17
    标 题 :Photo-catalytic Systems for Production of Hydrogen
    发明人:JENNINGS TRAVIS; LANDRY DANIEL
    权利人:SUNPOWER TECHNOLOGIES LLC
    摘要:A system for splitting water and producing hydrogen for later use as an energy source may include the use of a photoactive material including PCCN and plasmonic nanoparticles. A method for producing the PCCN may include a semiconductor nanocrystal synthesis and an exchange of organic capping agents with inorganic capping agents. The PCCN may be deposited between the plasmonic nanoparticles and may act as photocatalysts for redox reactions. The photoactive material may be used in presence of water and sunlight to split water into hydrogen and oxygen. Production of charge carriers may be triggered by photo-excitation and enhanced by the rapid electron resonance from localized surface plasmon resonance of plasmonic nanoparticles. By combining different semiconductor materials for PCCN and plasmonic nanoparticles and by changing their shapes and sizes, band gaps may be tuned to expand the range of wavelengths of sunlight usable by the photoactive material. The system may include elements for collecting, transferring, and storing hydrogen and oxygen, for subsequent transformation into electrical energy.

    专利号:US-2011198530-A1
    优先权日:2010-02-18
    标题:Method of Producing a Bismuth Vanadium Oxide Derivative of Bi4V2O11 Using Molten Salt Synthesis, and Product Produced
    发明人:ROY BANASRI
    权利人:NEW MEXICO TECHNICAL FOUNDATION
    摘要:A method comprising mixing a bismuth precursor, a vanadium precursor, and at least one metal dopant precursor together with a salt or salt mixture having a eutectic melting temperature of no greater than 680° C. to form a homogeneous mixture, which is heated to a temperature of from 550° C. to 700° C. to produce a molten state of the salt or salt mixture and to obtain a metal doped bismuth vanadium oxide product that is a derivative of Bi 4 V 2 O 11 , which is then cooled. The thus-produced metal doped bismuth vanadium oxide product is present in loose platelet form, with the platelets capable of being aligned such that their planes are substantially parallel to one another.

    专利号:US-2014262806-A1
    优先权日:2013-03-15
    标题 :Method for Increasing Efficiency of Semiconductor Photocatalysts
    发明人:JENNINGS TRAVIS
    权利人:SUNPOWER TECHNOLOGIES LLC; SUNPOWER TECHNOLOGIES LLC
    摘要:A method and composition for producing a photoactive material including photocatalytic capped colloidal nanocrystals (PCCN) and plasmonic nanoparticles are disclosed. The PCCN may include a semiconductor nanocrystal synthesis and an exchange of organic capping agents with inorganic capping agents. Additionally, the PCCN may be deposited between the plasmonic nanoparticles, and may act as photocatalysts for redox reactions. The photoactive material may be used in a plurality of photocatalytic energy conversion applications, such as water splitting and CO 2 reduction. By combining different semiconductor materials for PCCN and plasmonic nanoparticles, and by changing their shapes and sizes, band gaps may be tuned to expand the range of wavelengths of sunlight usable by the photoactive material. Higher light harvesting and energy conversion efficiency may be achieved.

    专利号:US-2014272623-A1
    优先权日:2013-03-15
    标题:System for increasing efficiency of semiconductor photocatalysts employing a high surface area substrate
    发明人:JENNINGS TRAVIS
    权利人:SUNPOWER TECHNOLOGIES LLC; SUNPOWER TECHNOLOGIES LLC
    摘要:A system for energy production may include a photoactive material with photocatalytic capped colloidal nanocrystals (PCCN) and plasmonic nanoparticles over a high surface area gridded substrate for increasing light harvesting efficiency. The formation of PCCN may include a semiconductor nanocrystal synthesis and an exchange of organic capping agents with inorganic capping agents. Additionally, the PCCN may be deposited between the plasmonic nanoparticles, and may act as photocatalysts for redox reactions. The photoactive material may be used in a plurality of photocatalytic energy conversion applications such as water splitting or CO 2 reduction. Higher light harvesting and energy conversion efficiency may be achieved by combining the plasmonic nanoparticles and PCCN over the high surface area gridded substrate. The system may also include elements necessary to collect, transfer and store hydrogen and oxygen, for subsequent transformation into electrical energy.

    专利号:KR-20150125952-A
    优先权日:2013-03-11
    标 题:Hydrothermal synthesis of zinc phlogopite

    专利号:US-2014339072-A1
    优先权日:2013-05-17
    标 题 :Photocatalytic CO2 Reduction System
    发明人:JENNINGS TRAVIS; LANDRY DANIEL
    权利人:SUNPOWER TECHNOLOGIES LLC
    摘要:A system employing sunlight energy for reducing CO 2 into methane and water is disclosed. The system may include the use of a photoactive material including plasmonic nanoparticles and photocatalytic capped colloidal nanocrystals (PCCN). A method for producing the PCCN may include a semiconductor nanocrystal synthesis and an exchange of organic capping agents with inorganic capping agents. Additionally, the PCCN may be deposited between the plasmonic nanoparticles, and may act as photocatalysts for redox reactions. The CO 2 reduction system may use inorganic capping agents that cap the surface of semiconductor nanocrystals to form PCCN, which may be deposited on a substrate and treated to form a photoactive material. The photoactive material may be employed in the system to harvest sunlight and produce energy necessary for carbon dioxide reduction. The system may also include elements necessary to collect and transfer methane, for subsequent transformation into electrical energy.
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    合成参考文献


    摘要:S47 | ECHAPLASTICS | A list from the Plastic Additives Initiative Mapping Exercise by ECHA | DOI:10.5281/zenodo.2658139
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