CAS: 87188-51-0; Tert-Butyl (4-Vinylphenyl) Carbonate

该化合物是一种有机化合物,其特点是碳酸盐功能组,该物质具有一种附于一个苯环的异丁基组(1,1-二甲基乙基),该物质被进一步替换成一个苯乙烯组(乙烯组),碳酸盐运动的存在表明它可以参与各种化学反应,包括聚合和酯化.通常,这种化合物具有中度至高热稳定性,可用于涂层,粘合剂或有机合成的中间体等应用,其结构允许在特定条件下进行可能的再活动,使其在工业和研究环境中都具有意义.在处理和储存准则方面,应参考安全数据表,如任何化学物质,以确保采取适当的安全措施.

英文名称Tert-Butyl (4-Vinylphenyl) Carbonate
中文名称4-(叔丁氧基羰基氧基)苯乙烯
IUPAC名称tert-butyl (4-vinylphenyl) carbonate
其它别名4-叔丁氧羰基苯乙烯; Carbonic Acid, 1,1-Dimethylethyl 4-Ethenylphenyl Ester
CAS编号87188-51-0
MFCD编号:MFCD00145182
EINECS号:689-292-4
分子式:C13H16O3
分子量:220.26
产品CID: 1877640
产品分类有机原料→材料科学→电子材料→光刻胶单体

相似结构搜索
InChIKey: GJWMYLFHBXEWNZ-UHFFFAOYSA-N
InChI=1S/C13H16O3/c1-5-10-6-8-11(9-7-10)15-12(14)16-13(2,3)4/h5-9H,1H2,2-4H3…
计算化学: 氢键受体数3.0氢键供体数0可旋转键数2

相似化合物

87188-50-9 6627-89-0 127175-62-6

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别皮肤致敏类别1
警示词Warning(警告)
危险描述H317 |可能引起皮肤过敏反应.
防范说明P264-P280-P302+P352-P362
危险品标志Xi
WGK Germany2

欧盟法规

C&L通报

上下游产品

CAS号2628-16-2 对乙酰氧基苯乙烯 | CAS号24424-99-5 二碳酸二叔丁酯 | CAS号2472-88-0 四丁基硫酸铵

合成工艺路线路线简述

合成目标产物 Tert-Butyl 4-Vinylphenyl Carbonate 主要起始原料 Di-Tert-Butyl Dicarbonate And 4-Hydroxycinnamic Acid
87188-50-9 = 87188-51-0
反应条件:1.1 Reagents: Triphenylphosphine,Potassium Tert-Butoxide Solvents: Diethyl Ether; 10 Min,Rt; 10 Min,Rt1.2 Solvents: Tetrahydrofuran; Rt; 1 H,Rt
标题:Synthetic Improvement Of [[(Tert-Butoxy)Carbonyl]Oxy]Styrene Intermediate Of Monomer Of Poly (P-Hydroxystyrene)
作者:Liu,Jian-Guo; Et Al
参考文献:Yingyong Huaxue 日期:2007 卷标:24(3) 页码:361-364]

= 87188-51-0
反应条件:1.1 Catalysts: Potassium Tert-Butoxide Solvents: Tetrahydrofuran; 1 H,Rt -> 40 °C1.2 Reagents: Water; Cooled
标题:A Novel Synthesis Of P-Tert-Butoxycarbonyloxystyrene
作者:Liu,Jian-Guo; Et Al
参考文献:Yingyong Huaxue 日期:2008 卷标:25(4) 页码:424-428]

2628-16-2 = 87188-51-0
反应条件:1.1 Reagents: Ammonium Acetate Solvents: Methanol,Water; 24 H,Rt2.1 Reagents: Potassium Carbonate Solvents: Tetrahydrofuran; 24 H,Rt
标题:Effect Of Glass Transition Temperature On Heat-Responsive Gas Bubbles Formation From Polymers Containing Tert-Butoxycarbonyl Moiety
作者:Iseki,Masashi; Et Al
参考文献:Journal Of Applied Polymer Science 日期:2018 卷标:135(19)]

2628-16-2 + 24424-99-5 = 87188-51-0
反应条件:1.1 Reagents: Tetramethylammonium Hydroxide Solvents: Water; 10 Min,0 °C; 1 H,0 °C -> 20 °C; 20 °C -> 0 °C1.2 24 H,0 °C
标题:Mesoscale Block Copolymers
作者:Barber,Dylan M.; Et Al
参考文献:Advanced Materials (Weinheim 日期:2018 卷标:30(13)]

2628-16-2 + 24424-99-5 = 87188-51-0
反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Tetrahydrofuran1.2 Solvents: Tetrahydrofuran
标题:Synthesis Of Para-Tert-Butoxycarbonyloxystyrene
参考文献:European Patent Organization]

24424-99-5 + 2628-17-3 = 87188-51-0
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Tetrahydrofuran; 24 H,Rt
标题:Effect Of Glass Transition Temperature On Heat-Responsive Gas Bubbles Formation From Polymers Containing Tert-Butoxycarbonyl Moiety
作者:Iseki,Masashi; Et Al
参考文献:Journal Of Applied Polymer Science 日期:2018 卷标:135(19)]

24424-99-5 + 2628-17-3 = 87188-51-0
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Tetrahydrofuran; 24 H,Rt
标题:Thermal Degradation Behavior Of Polymers Containing Tert-Butoxycarbonyl Group In Side Chain And Application To Dismantlable Adhesion Materials
作者:Suzuki,Fumiya; Et Al
参考文献:Nippon Setchaku Gakkaishi 日期:2017 卷标:53(1) 页码:4-10]

74-95-3 + 87188-50-9 = 87188-51-0
反应条件:1.1 Reagents: Acetyl Chloride,Zinc Solvents: Dimethylformamide
标题:Method For Producing Hydroxystyrene Derivatives From Hydroxybenzaldehyde Derivatives And Dibromomethane
参考文献:Japan]

24424-99-5 + 7400-08-0 = 87188-51-0
反应条件:1.1 Reagents: Hydroquinone,Potassium Acetate Solvents: Dimethylformamide; Rt -> 130 °C; 1.5 H,130 °C; 130 °C -> 50 °C1.2 50 °C; 2 H,50 °C1.3 Reagents: Water; Cooled
标题:Study On The Synthetic Process Of Monomers Of P-Hydroxystyrene And Its Derivatives For 248 Nm Photoresist
作者:Song,Guoqiang; Et Al
参考文献:Huagong Xinxing Cailiao 日期:2011 卷标:39(7) 页码:85-87]

141-82-2 + 123-08-0 = 87188-51-0
反应条件:1.1 Catalysts: Piperidine Solvents: 4-Methylpyridine; Rt -> 85 °C; 1.5 H,85 °C; Cooled1.2 Reagents: Potassium Carbonate Solvents: Water1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 22.1 Reagents: Hydroquinone,Potassium Acetate Solvents: Dimethylformamide; Rt -> 130 °C; 1.5 H,130 °C; 130 °C -> 50 °C2.2 50 °C; 2 H,50 °C2.3 Reagents: Water; Cooled
标题:Study On The Synthetic Process Of Monomers Of P-Hydroxystyrene And Its Derivatives For 248 Nm Photoresist
作者:Song,Guoqiang; Et Al
参考文献:Huagong Xinxing Cailiao 日期:2011 卷标:39(7) 页码:85-87]

224824-55-9 = 87188-51-0
反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Benzoyl Peroxide Solvents: Carbon Tetrachloride; Rt -> 90 °C; 90 °C; 90 °C -> Rt2.1 Catalysts: Potassium Tert-Butoxide Solvents: Tetrahydrofuran; 1 H,Rt -> 40 °C2.2 Reagents: Water; Cooled
标题:A Novel Synthesis Of P-Tert-Butoxycarbonyloxystyrene
作者:Liu,Jian-Guo; Et Al
参考文献:Yingyong Huaxue 日期:2008 卷标:25(4) 页码:424-428]

24424-99-5 + 58765-11-0 = 87188-51-0
反应条件:1.1 Solvents: Tetrahydrofuran; 1 H,Rt1.2 Reagents: Water; Cooled2.1 Reagents: Triphenylphosphine,Potassium Tert-Butoxide Solvents: Diethyl Ether; 10 Min,Rt; 10 Min,Rt2.2 Solvents: Tetrahydrofuran; Rt; 1 H,Rt
标题:Synthetic Improvement Of [[(Tert-Butoxy)Carbonyl]Oxy]Styrene Intermediate Of Monomer Of Poly (P-Hydroxystyrene)
作者:Liu,Jian-Guo; Et Al
参考文献:Yingyong Huaxue 日期:2007 卷标:24(3) 页码:361-364]

2628-16-2 = 87188-51-0
反应条件:1.1 Reagents: Ammonium Hydroxide Solvents: Methanol; 24 H,Rt2.1 Reagents: Potassium Carbonate Solvents: Tetrahydrofuran; 24 H,Rt
标题:Thermal Degradation Behavior Of Polymers Containing Tert-Butoxycarbonyl Group In Side Chain And Application To Dismantlable Adhesion Materials
作者:Suzuki,Fumiya; Et Al
参考文献:Nippon Setchaku Gakkaishi 日期:2017 卷标:53(1) 页码:4-10]

24424-99-5 + 123-07-9 = 87188-51-0
反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Tetrahydrofuran; > 1 Min,Rt1.2 1 H,Rt1.3 Reagents: Water; Cooled2.1 Reagents: N-Bromosuccinimide Catalysts: Benzoyl Peroxide Solvents: Carbon Tetrachloride; Rt -> 90 °C; 90 °C; 90 °C -> Rt3.1 Catalysts: Potassium Tert-Butoxide Solvents: Tetrahydrofuran; 1 H,Rt -> 40 °C3.2 Reagents: Water; Cooled
标题:A Novel Synthesis Of P-Tert-Butoxycarbonyloxystyrene
作者:Liu,Jian-Guo; Et Al
参考文献:Yingyong Huaxue 日期:2008 卷标:25(4) 页码:424-428

4-乙酰氧基苯乙烯,二碳酸二叔丁酯置于四甲基氢氧化铵体系中,用54 %的收率获得产物叔丁基4-乙烯基苯基碳酸酯
参考文献:烯烃的铜 (I) 光催化溴硝基烷基化:高效内球通路的证据
标题:烯烃的铜 (I) 光催化溴硝基烷基化:高效内球通路的证据
摘要:在 Cu I-光催化剂存在下,具有广泛范围的活化和未活化烯烃的光催化溴硝基烷基化成为可能.这种转化成功的关键是 Cu Ii与自由基中间体的高效相互作用,它甚至可以胜过从瞬态自由基到持久自由基的高度有利的环化.
DOI:10.1002/anie.202219086

海关参考信息

2901210000-乙烯
2902300000-甲苯
2902500000-苯乙烯
2905122000-异丙醇
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-2004110228-A1
优先权日:2002-04-01
标题:Combinatorial organic synthesis of unique biologically active compounds
发明人：MCALPINE SHELLI R; TAYLOR RACHEL E; BOLLA MEGAN L; SEGALL ANCA M
摘要:The invention provides a method for making a combinatorial library of cyclic compounds, such as Holliday junction-trapping compounds, comprising the steps of (a) obtaining a plurality of trimers according to the generic structure X 1- X 2- X 3 , wherein X 1 , X 2 and X 3 can be independently any naturally or nonnaturally occurring amino acids or peptidomimetics thereof; (b) optionally coupling a spacer S to the trimer at either end; (c) cyclizing two trimers or trimer-spacer conjugates in a head-to-tail orientation; thereby obtaining a combinatorial library of compounds, wherein the library does not include an unmodifed or naturally occurring Holliday Junction-trapping compounds. The invention additionally provides methods macrocyclic compounds that are synergimycin derivatives.

专利号:US-10407676-B2
优先权日:2014-12-09
标题 :High efficiency, small volume nucleic acid synthesis
发明人：POEHMERER THOMAS; KUHN PHILLIP; NOTKA FRANK; ZEIDLER ANDREAS; HEIL KORBINIAN; TREFZER AXEL; FONNUM GEIR; KATZEN FEDERICO; ANDERSSON KRISTIAN
权利人:LIFE TECHNOLOGIES CORP; THERMO FISHER SCIENT GENEART GMBH; LIFE TECH AS
摘要:The disclosure generally relates to compositions and methods for the production of nucleic acid molecules. In some aspects, the invention allows for the microscale generation of nucleic acid molecules, optionally followed by assembly of these nucleic acid molecules into larger molecules. In some aspects, the invention allows for efficient production of nucleic acid molecules (e.g., large nucleic acid molecules such as genomes).

专利号:EP-0498630-A3
优先权日:1991-02-05
标题 :Synthesis of para-tert-butoxycarbonyloxystyrene
摘要:Para-tert-butoxycarbonyloxystyrene is nsynthesized by reacting para-acetoxystyrene nwith an alkali metal alkoxide to form an alkali nmetal para-vinyl phenolate in a reactor, and ntertiary carbonyloxylating the alkali metal npara-vinyl phenolate in the same reactor. This nprocess can synthesize the end product in high nyields and is thus suitable for large scale ncommercial manufacture.

专利号:EP-0498630-A2
优先权日:1991-02-05
标题:Synthesis of para-tert-butoxycarbonyloxystyrene

专利号:AU-2009233757-A1
优先权日:2008-04-08
标题 :Triterpene saponins, methods of synthesis, and uses thereof

专利号:CN-116854592-A
优先权日:2023-06-15
标题 :A kind of synthesis method of tert-butyl carbonate compounds