CAS: 82-86-0; Acenaphthylene-1,2-Dione
该化合物是来自丙烯的多环芳烃五角酮,广泛用作有机合成和染料生产的中间体,其硬板结构及同质碳基组对光化学,催化和材料科学的应用具有价值,该化合物显示出明显的稳定性和再氧化活动,促进了其在电化学研究中的使用,并成为功能化芳香系统的前体,其高纯度和连续的再活动确保了研究和工业过程的可靠性能.
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- InChI=1S/C12H6O2/c13-11-8-5-1-3-7-4-2-6-9(10(7)8)12(11)14/h1-6H…
- 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数0.0
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CAS号83-32-9 苊 | CAS号208-96-8 苊烯 | CAS号14209-08-6 Acenaphthylene,... | CAS号13093-45-3 1,2-Didehydroac... | CAS号103457-73-4 Ethyl 2-oxo-3'-... | CAS号2963-86-2 1,2-Acenaphthyl... | CAS号2963-87-3 (±)-trans-acena... | CAS号2235-15-6 1-苊酮 | CAS号5116-63-2 迫萘合環己三酮 | CAS号18931-20-9 2,2-dihydroxyph... | CAS号14619-86-4 Propanedinitril... | CAS号17976-92-0 1,2-Acenaphthyl... | CAS号4141-50-8 Phosphine oxide... | CAS号23177-30-2 3-aminophenalen... | CAS号20485-57-8 8-methylfluoranthene | CAS号19274-72-7 Methanone,1,1'-... | CAS号187605-59-0 2-[2,6-di(propa... | CAS号1932-10-1 (2Z)-2-hydrazin... | CAS号1932-06-5 N-[[2-(phenylhy...合成工艺路线路线简述
- 合成目标产物 Acenaphthenequinone 主要起始原料 Acenaphthylene
- 2235-15-6 = 82-86-0
反应条件:1.1 Reagents: Dimethyl Sulfoxide,Pyridinium Tribromide
标题:A Convenient One-Pot Synthesis Of Acenaphthenequinones From 1-Acenaphthenones By N-Bromosuccinimide-Dimethyl Sulfoxide Oxidation
作者:Tatsugi,Jiro; Et Al
参考文献:Bulletin Of The Chemical Society Of Japan 日期:1986 卷标:59(10) 页码:3311-13]
= 82-86-0
反应条件:1.1 Reagents: Phenylseleninyl Benzeneseleninate Solvents: Chlorobenzene
标题:Benzeneseleninic Anhydride Oxidation Of 1,2-Diarylethanes And 1,2-Diarylethylenes To 1,2-Diaryl Diketones
作者:Clayton,Mark D.; Et Al
参考文献:Tetrahedron Letters 日期:1998 卷标:39(50) 页码:9127-9130]
= 82-86-0
反应条件:1.1 Reagents: Trifluoromethanesulfonic Anhydride,Tetrabutylammonium Nitrite Solvents: Dichloromethane; 15 Min,-78 °C; 45 Min,-78 °C1.2 Reagents: Nitrogen Monoxide,1,1,1-Trifluoromethanesulfonate (1:1) Solvents: Dichloromethane; 10 Min,-78 °C; 30 Min,-78 °C1.3 Reagents: Triethylamine; 40 Min,-78 °C1.4 Reagents: Sodium Bicarbonate Solvents: Water; 30 Min,-78 °C
标题:Synthetically Useful Transformations Of Olefins Via Cationic 1,2-Oxazetium Intermediates
作者:Reddy,G. Sudhakar; Et Al
参考文献:Organic Letters 日期:2023 卷标:25(39) 页码:7160-7164]
= 82-86-0
反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Dimethyl Sulfoxide,Water; Rt1.2 Reagents: 2-Iodoxybenzoic Acid; 5 H,60 - 70 °C1.3 Solvents: Water
标题:Oxidations With Ibx: Benzyl Halides To Carbonyl Compounds,And The One-Pot Conversion Of Olefins To 1,2-Diketones
作者:Moorthy,Jarugu Narasimha; Et Al
参考文献:Tetrahedron Letters 日期:2006 卷标:47(11) 页码:1757-1761]
= 82-86-0
反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide,Sodium Hypochlorite Solvents: Ethyl Acetate,Water; 9 - 10 H,2 - 5 °C
标题:An Economical And Green Approach For The Oxidation Of Olefins To Enones
作者:Marwah,Padma; Et Al
参考文献:Green Chemistry 日期:2004 卷标:6(11) 页码:570-577]
14209-08-6 = 82-86-0
反应条件:1.1 Reagents: Dimethyl Sulfoxide Solvents: Dimethyl Sulfoxide
标题:Oxidation By Dmso. Ii. An Efficient Synthesis Of α,β-Diketones From α,β-Dibromides
作者:Villemin,Didier; Et Al
参考文献:Synthetic Communications 日期:1995 卷标:25(20) 页码:3145-8]
14209-08-6 = 82-86-0
反应条件:1.1 Reagents: Dimethyl Sulfoxide Solvents: Dimethyl Sulfoxide
标题:Convenient One-Pot Oxidation Of Acenaphthene To Acenaphthenequinone Using N-Bromosuccinimide And Dmso
作者:Krasnokutskaya,E. A.; Et Al
参考文献:Izvestiya Vysshikh Uchebnykh Zavedenii 日期:2002 卷标:45(3) 页码:52-54]
13093-45-3 = 82-86-0
反应条件:1.1 Reagents: Oxygen
标题:Acenaphthyne
作者:Chapman,O. L.; Et Al
参考文献:Journal Of The American Chemical Society 日期:1981 卷标:103(23) 页码:7033-6]
872-36-6 + 17135-74-9 = 82-86-0
反应条件:1.1 Reagents: Cesium Carbonate Catalysts: Triphenylphosphine,Palladium Diacetate Solvents: Dimethylformamide; 1 H,120 °C
标题:Oxidation Of O-Dioxime By (Diacetoxyiodo)Benzene: Green And Mild Access To Furoxans
作者:Zhang,Qi; Et Al
参考文献:New Journal Of Chemistry 日期:2022 卷标:46(4) 页码:1489-1493]
33928-29-9 = 82-86-0
反应条件:1.1 Reagents: Potassium Carbonate,Iodine Solvents: Tert-Butanol
标题:Synthesis Of New Chiral Keto Alcohols By Baker'S Yeast
作者:Yildiz,Tulay; Et Al
参考文献:Tetrahedron: Asymmetry 日期:2014 卷标:25(4) 页码:340-347]
= 82-86-0
反应条件:1.1 Reagents: Hydrochloric Acid
标题:Acenaphthene Derivatives. Xxix. Reaction Of Carbonyl-Stabilized Sulfonium And Phosphonium Ylides With 2-Diazoacenaphthenone
作者:Tsuge,Otohiko; Et Al
参考文献:Organic Preparations And Procedures International 日期:1975 卷标:7(4) 页码:173-7]
6306-07-6 = 82-86-0 [标题:Reaction Conditions
标题:Bacterial Oxidation Of The Polycyclic Aromatic Hydrocarbons Acenaphthene And Acenaphthylene
作者:Schocken,Mark J.; Et Al
参考文献:Applied And Environmental Microbiology 日期:1984 卷标:48(1) 页码:10-16]
= 82-86-0 + 2235-15-6
反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: 2-[3-(Triethoxysilyl)Propyl]-1,2-Benzisoselenazol-3(2H)-One (Silica Supported) Solvents: Tert-Butanol,Water; 30 H,80 °C
标题:New Recoverable Organoselenium Catalyst For Hydroperoxide Oxidation Of Organic Substrates
作者:Wojtowicz,Halina; Et Al
参考文献:Synthetic Communications 日期:2008 卷标:38(12) 页码:2000-2010]
= 82-86-0 + 119951-85-8
反应条件:1.1 Catalysts: Butylpyridinium Bromide Solvents: Chlorobenzene
标题:Oxidation Of Acenaphthene In The Presence Of Butylpyridinium Bromide
作者:Opeida,I. A.; Et Al
参考文献:Neftekhimiya 日期:1988 卷标:28(4) 页码:544-51]
= 82-86-0
反应条件:1.1 Reagents: Phenylseleninyl Benzeneseleninate Solvents: Chlorobenzene; Heated
标题:Benzeneseleninic Acid And Benzeneseleninic Anhydride
作者:Back,Thomas G.
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2007 卷标:1 页码:1-8]
2963-86-2 = 82-86-0
反应条件:1.1 Reagents: 2-Iodoxybenzoic Acid Solvents: Dimethyl Sulfoxide; 1 H,30 °C
标题:Oxidative Cleavage Of Vicinal Diols: Ibx Can Do What Dess-Martin Periodinane (Dmp) Can
作者:Moorthy,Jarugu Narasimha; Et Al
参考文献:Organic & Biomolecular Chemistry 日期:2007 卷标:5(5) 页码:767-771]
2963-86-2 = 82-86-0 [标题:Reaction Conditions
标题:Liquid-Phase Oxidation Of Acenaphthene With A Cobalt-Manganese-Bromide Catalyst
作者:Digurov,N. G.; Et Al
参考文献:Izvestiya Vysshikh Uchebnykh Zavedenii 日期:1990 卷标:33(7) 页码:43-7]
2963-86-2 = 82-86-0 [标题:Reaction Conditions
标题:Bacterial Oxidation Of The Polycyclic Aromatic Hydrocarbons Acenaphthene And Acenaphthylene
作者:Schocken,Mark J.; Et Al
参考文献:Applied And Environmental Microbiology 日期:1984 卷标:48(1) 页码:10-16]
2963-87-3 = 82-86-0
反应条件:1.1 Reagents: 2-Iodoxybenzoic Acid Solvents: Dimethyl Sulfoxide; 1 H,30 °C
标题:Oxidative Cleavage Of Vicinal Diols: Ibx Can Do What Dess-Martin Periodinane (Dmp) Can
作者:Moorthy,Jarugu Narasimha; Et Al
参考文献:Organic & Biomolecular Chemistry 日期:2007 卷标:5(5) 页码:767-771]
24171-73-1 = 82-86-0
反应条件:1.1 Reagents: Dimethyl Sulfoxide Solvents: Carbon Tetrachloride
标题:Convenient One-Pot Oxidation Of Acenaphthene To Acenaphthenequinone By Dmso
作者:Krasnokutskaja,Elena A.; Et Al
参考文献:Proceedings - Korus 2000 日期:2000 卷标:1 页码:182-185]
14209-08-6 = 82-86-0
反应条件:1.1 Reagents: Dimethyl Sulfoxide Solvents: Carbon Tetrachloride
标题:Convenient One-Pot Oxidation Of Acenaphthene To Acenaphthenequinone By Dmso
作者:Krasnokutskaja,Elena A.; Et Al
参考文献:Proceedings - Korus 2000 日期:2000 卷标:1 页码:182-185]
6306-07-6 = 82-86-0 [标题:Reaction Conditions
标题:Liquid-Phase Oxidation Of Acenaphthene With A Cobalt-Manganese-Bromide Catalyst
作者:Digurov,N. G.; Et Al
参考文献:Izvestiya Vysshikh Uchebnykh Zavedenii 日期:1990 卷标:33(7) 页码:43-7]
17216-14-7 = 82-86-0
反应条件:1.1 Reagents: Potassium Cyanide Solvents: Ethanol,Water2.1 Reagents: Potassium Carbonate,Iodine Solvents: Tert-Butanol
标题:Synthesis Of New Chiral Keto Alcohols By Baker'S Yeast
作者:Yildiz,Tulay; Et Al
参考文献:Tetrahedron: Asymmetry 日期:2014 卷标:25(4) 页码:340-347]
= 82-86-0
反应条件:1.1 Reagents: Potassium Bromide,Oxygen Catalysts: Cobalt Diacetate,Manganese Diacetate; 105 °C
标题:Catalytic Oxidation Of Acenaphthene And Its Derivatives In Acetic Acid
作者:Bukharkina,Tatiana V.; Et Al
参考文献:Organic Process Research & Development 日期:2002 卷标:6(4) 页码:394-400]
= 82-86-0
反应条件:1.1 Reagents: Ceric Ammonium Nitrate,Polyethylene Glycol Solvents: Acetic Acid,Water
标题:New Method For The Synthesis Of 5-Nitroacenaphthene
作者:Zhu,Huiqin
参考文献:Huaxue Shiji 日期:2002 卷标:24(1) 页码:45-46]
= 82-86-0 + 2051-98-1
反应条件:1.1 Reagents: Bromine Solvents: Dimethyl Sulfoxide
标题:Convenient One-Pot Oxidation Of Acenaphthene To Acenaphthenequinone By Dmso
作者:Krasnokutskaja,Elena A.; Et Al
参考文献:Proceedings - Korus 2000 日期:2000 卷标:1 页码:182-185
1,2-Dibromoacenaphthene置于2-碘酰基苯甲酸体系中,用 二甲基亚砜 作为反应溶剂,化学反应 4.0H,以50%的收率获得产物苊醌
参考文献:Ibx氧化:将苄基卤化物转化为羰基化合物,以及将烯烃一锅法转化为1,2-二酮
标题:Ibx氧化:将苄基卤化物转化为羰基化合物,以及将烯烃一锅法转化为1,2-二酮
摘要:Ibx在dmso中于65oc将各种苄基卤化物以可观的收率转化为相应的醛/酮.在dmso中使用nbs-H2O进行的烯烃的溴代醇反应可以很好地适应ibx介导的苄基卤的氧化反应,从而可以一锅法将烯烃以非常好的分离产率转化为相应的1,2-二酮.
DOI:10.1016/j.Tetlet.2006.01.039
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专利信息
专利号:WO-2024260915-A1
优先权日:2023-06-19
标题:Dynamic covalent chemistry of spiropyrans for synthesis of photoswitchable photoinitiators and uses thereof
发明人：GARMSHAUSEN YVES
权利人:XOLO GMBH
摘要:The present invention relates to spiropyrans and process for the manufacture of them. In particular, a method is provided to exchange the indole and salicylaldehyde part of a spiropyran in a reversible reaction. The method is used for the synthesis of dual color photoinitiators with specific substituents and substitution patterns, which result in improved dual color volumetric printing (xolography). Furthermore, a process for locally polymerizing a starting material by dual color photopolymerization is disclosed.
专利号:WO-9856796-A1
优先权日:1997-06-09
标题 :Delivery and scavenging agents for combinatorial synthesis
发明人：BOUSSIE THOMAS; HALL KEITH A; LAPOINTE ANNE M; MURPHY VINCE; POWERS TIMOTHY; BEEK JOHANNES A M VAN
权利人:SYMYX TECHNOLOGIES INC
摘要:Delivery and scavenging agents are provided for the combinatorial synthesis of organometallic compounds in a solution or suspension, where the agents are constructed from a solid support allowing for easy separation of unreacted reagents or unwanted materials from a synthesis reaction. Use of these solid supported agents also allows otherwise unfavorable reactions to be driven to completion by the use of large excesses of reactants and minimizes the chances for competing bimolecular side reactions in parallel or rapid serial synthesis.
专利号:US-7271231-B2
优先权日:1995-01-24
标 题 :Polymerization of olefins
发明人：BROOKHART MAURICE S; JOHNSON LYNDA KAYE; KILLIAN CHRISTOPHER MOORE
权利人:DU PONT
摘要:Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected α-diimine nickel complexes with ethylene.
专利号:US-8137822-B2
优先权日:2005-04-28
标题 :Synthesis of phenyl-substituted polyfluoroanthenes and the use thereof
发明人：DOETZ FLORIAN; NORD SIMON; WEISS HORST; ROESCH JOACHIM
权利人:DOETZ FLORIAN; NORD SIMON; WEISS HORST; ROESCH JOACHIM; BASF AG
摘要:The invention relates to a method for producing polyfluoroanthenes containing repeat units of general formula (I), said method consisting of the following steps: a) a monomer fluoroanthene derivative of formula IIa is produced; b) optionally the monomer fluoroanthene derivative of formula IIa is converted into another monomer fluoroanthene derivative of formula IIb; and c) the monomer fluoroanthene derivative of formula IIa or IIb is polymerised, optionally together with at least one other comonomer. The invention also relates to polyfluoroanthenes that can be produced according to the inventive method, films, a light-emitting layer containing or consisting of at least one inventive polyfluoroanthene, OLEDs containing at least one inventive polyfluoroanthene, OLEDs containing an inventive light-emitting layer, a device containing an inventive OLED, and the use of the inventive polyfluoroanthene emitter substances in OLEDs.
专利号:US-2009191394-A1
优先权日:2005-10-07
标题:Oarganic Compound, Optical Crystal Film and Method of Production Thereof
发明人：LAZAREV PAVEL I; SIDORENKO ELENA N
权利人:LAZAREV PAVEL I; SIDORENKO ELENA N
摘要:The present invention is related to the synthesis of acenaphthoquinoxaline sulfonamide derivatives and the manufacture of optical crystal films based on these compounds. Said acenaphthoquinoxaline sulfonamide heterocyclic derivatives have the general structural formula: where n is 1, 2 or 3; X is an acid group; m is 1, 2 or 3; Y is a counterion selected from the list consisting of H + , NH4 + , Na + , K + , and Li + ; p is the number of counterions providing neutral state of the molecule; R is a substituent selected from the list consisting of —CH 3 , —C 2 H 5 , —NO 2 , —Cl, —Br, —F, —CF 3 , —CN, —OH —OCH 3 , —OC 2 H 5 , —OCOCH 3 , —OCN, —SCN, —NH 2 , —NHCOCH 3 , —CONH 2 ; and z is 1, 2, 3 or 4.
专利号:US-4224034-A
优先权日:1978-09-07
标 题 :Assay of iron and iron binding protein reagents and methods
发明人：DENNEY JERRY W; OUTCALT MARK C
权利人:AMERICAN MONITOR CORP
摘要:The discovery of 9-(2-pyridyl)-acenaphtho[1,2-e]-as-triazine and its sulfonated form, having particular advantages when used as both a chelator and indicator of ferrous ions in organic or aqueous mediums; a process for the synthesis of those compounds in which hydrazine is used as both a reactant and as a solvent in production of intermediate compounds, eliminating the need of ethanol and the disadvantageous ether-extraction step; the use of N,N-dimethylformamide as a reaction solvent in the production of triazines; the use of the new triazine compounds to measure iron, transferrin, and UIBC/TIBC in biological systems; the use of dimethylsulfoxide and certain processes to eliminate the interferences commonly encountered in these assays; and the use of the triazine compounds to measure both total and/or reduced iron in a variety of matrices.
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主要参考文献
[参考文献]: D A Razborov, Et Al. Addition Of Phenylacetylene To A Magnesium Complex Of Monoiminoacenaphtheneone (Dpp-Mian). Dalton Trans. 2015 Dec 21;44(47):20532-41.[参考文献]: Hamid Reza Safaei, Et Al. Cacl(2) As A Bifunctional Reusable Catalyst: Diversity-Oriented Synthesis Of 4H-Pyran Library Under Ultrasonic Irradiation. Mol Divers. 2012 Nov;16(4):669-83.
[参考文献]: Janice L Hyatt, Et Al. Planarity And Constraint Of The Carbonyl Groups In 1,2-Diones Are Determinants For Selective Inhibition Of Human Carboxylesterase 1. J Med Chem. 2007 Nov 15;50(23):5727-34.
[参考文献]: Sang Woon Chung, Et Al. Activation Of 5-Lipoxygenase And Nf-Kappa B In The Action Of Acenaphthenequinone By Modulation Of Oxidative Stress. Toxicol Sci. 2008 Jan;101(1):152-8.
[参考文献]: Sang Woon Chung, Et Al. An Environmental Quinoid Polycyclic Aromatic Hydrocarbon, Acenaphthenequinone, Modulates Cyclooxygenase-2 Expression Through Reactive Oxygen Species Generation And Nuclear Factor Kappa B Activation In A549 Cells. Toxicol Sci. 2007 Feb;95(2):348-55.
合成参考文献
摘要:Lin, W.-C.; Wu, Y.-T., Science of Synthesis, (2010) 45, 1029.
摘要:Isovitsch, R., Science of Synthesis Knowledge Updates, (2021) 2, 239.
摘要:Isovitsch, R., Science of Synthesis Knowledge Updates, (2021) 2, 250.
摘要:Shaabani, A.; Sarvary, A.; Shaabani, S., Science of Synthesis: Multicomponent Reactions, (2013) 2, 79.
摘要:Moody, T. S.; Mix, S.; Brown, G.; Beecher, D., Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 2, 429.
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