CAS: 614-14-2; 1-Phenyl-1-Butanol

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CAS号233773-39-2 1-phenylbutyl n... | CAS号80735-94-0 1-苯基-3-丁烯-1-醇 | CAS号292638-84-7 phenylene-ethylene | CAS号563-43-9 二氯乙基铝 | CAS号495-40-9 苯丁酮 | CAS号108-86-1 溴苯 | CAS号123-72-8 正丁醛 | CAS号100-52-7 苯甲醛 | CAS号106-94-5 溴代丙烷 | CAS号67-63-0 异丙醇 | CAS号34176-47-1 2-氨基-5-乙基-4-苯基噻唑 | CAS号15074-24-5 4-hydroxy-3-(1-... | CAS号495-40-9 苯丁酮 | CAS号22144-60-1 (R)-(+)-1-苯基-1-丁醇 | CAS号22135-49-5 (S)-(-)-1-苯基-1-丁醇 | CAS号100-52-7 苯甲醛 | CAS号119-61-9 二苯甲酮 | CAS号91-01-0 二苯甲醇 | CAS号22731-65-3 2-Methylene-1-p... | CAS号104-51-8 丁基苯

📜(R)-(+)-1-苯基-1-丁醇置于ru-Macho,Potassium Tert-Butylate体系中,用 甲基叔丁基醚 作为反应溶剂,化学反应 0.25H,反应生成 1-苯基-1-丁醇
参考文献:评估fe和ru Pincer型配合物作为仲苄醇外消旋化的催化剂
标题:评估fe和ru Pincer型配合物作为仲苄醇外消旋化的催化剂
摘要:Fe和ru夹钳型催化剂用于苄醇的外消旋化.在温和的反应条件下,在30分钟内用fe催化剂进行外消旋,催化剂负载量低至2 Mol%.该反应构成了铁催化的外消旋醇的第一个例子.对于各种仲苄醇,评估了fe催化剂及其ru类似物的外消旋效率.市场上可买到的ru配合物被证明是高度坚固的,甚至可以耐受反应混合物中水的存在.
DOI:10.1002/chem.201601793

专利信息

专利号:US-4774331-A
优先权日:1986-08-22
标 题:Process for ortho-cyanation of phenols or phenylamines
发明人：ADACHI MAKOTO; MATSUMURA HIROMU; SUGASAWA TSUTOMU
权利人:SHIONOGI & CO
摘要:A process for ortho-cyanation of phenols or phenylamines which comprises reacting a phenyl compound having a hydroxy group or an optionally substituted amino or cyclic amino group, of which the ortho position is vacant, with trichloroacetonitrile, a C1-C5 alkyl thiocyanate or a C6 - C12 aryl thiocyanate in the presence of a boron trihalide and treating the resultant product with an alkali is provided, and said process is useful in the synthesis of intermediates for medicinals or pesticides.

专利号:US-4857645-A
优先权日:1986-11-06
标 题:Process for introducing a thiocarboxylic ester group at the orthoposition of phenols or phenylamines
发明人：MAKOTO ADACHI; MATSUMURA HIROMU; SUGASAWA TSUTOMU
权利人:SHIONOGI & CO
摘要:A process for introducing thiocarboxylic ester at ortho-position of phenols or phenylamines which comprises reacting a phenyl compound having group or optionally substituted amino or cyclic amino group, of which at least one ortho-position is vacant, with C 1 -C 5 alkyl thiocyanate, C 7 -C 13 aralkyl thiocyanate or C 6 -C 12 aryl thiocyanate in the presence of a boron trihalide and hydrolyzing the resultant product under acidic conditions is provided, and said process is useful in the synthesis of medicinals, pesticides and dyes.

专利号:ES-2288114-B1
优先权日:2006-04-26
标题:NEW SYNTHESIS PROCEDURE OF (6- (4-PHENYLBUTOXY) HEXIL) N-SUBSTITUTED AMINES AND ITS USE IN THE SYNTHESIS OF SALMETEROL XINAFOATO.

专利号:US-7811556-B2
优先权日:2003-03-24
标题 :Polymeric modifiers and pharmaceutical compositions
发明人：KASUYA YUJI; HONMA MASASHI
权利人:SANKYO CO
摘要:A copolymer or a pharmacologically acceptable salt thereof is provided, which contains, as constitutional units, (a) one or more structural units of formula (I): wherein m is an integer of from 3 to 100, Alk represents alkyline, and R 1 and R 2 are the same or different and each represents hydrogen or optionally substituted alkyl, and (b) one or more structural units of formula (II): wherein R 3 represents hydroxyl, optionally substituted alkoxy, optionally substituted aryloxy, or a group represented by the formula —NR 4 R 5 , wherein R 4 and R 5 are the same or different and each represents hydrogen or optionally substituted alkyl. There is further provided a pharmaceutical composition comprising said copolymer, a protein modifier comprising said copolymer, a complex of said copolymer with a protein, and method of preventing or treating diseases using said complex, use of said complex in the manufacture of a medicament for preventing or treating diseases and methods for the synthesis of said copolymers and said complexes.

专利号:WO-2014057500-A1
优先权日:2012-10-08
标题 :One step process for synthesis of cyclic carbonates

专利号:ES-2288114-A1
优先权日:2006-04-26
标 题:NEW SITENSIS PROCEDURE OF (6- (4-PHENYLBUTOXY) HEXYL) AMINAS N-S USTITUIDAS AND ITS USE IN THE SYNTHESIS OF SALMETEROL XINAFOATO.