专利号:US-6472539-B1 优先权日:2000-01-07 标题 :Production process of diphosphine oxide and diphosphonate 发明人:YOKOZAWA TOHRU; SAITO TAKAO; SAYO NOBORU; ISHIZAKI TAKERO 权利人:TAKASAGO PERFUMERY CO LTD 摘要:A process for producing a diphosphine oxide or diphosphonate represented by formula (1) as defined, which comprises treating, with a base, a phosphine compound represented by formula (2) as defined and adding the thus-treated phosphine compound to a nonpolar solvent having an oxidative metal compound suspended therein so as to effect dimerization. The present invention makes it possible to produce, conveniently, in a high yield and safely, a diphosphine oxide or diphosphonate which is an intermediate for producing a diphosphine compound useful as a ligand of a metal complex serving as a catalyst for asymmetric synthesis reaction.
专利号:US-9062085-B2 优先权日:2010-09-10 标 题 :Biaryl diphosphine ligands, intermediates of the same and their use in asymmetric catalysis 发明人:ABDUR-RASHID KAMALUDDIN; JIA WENLI; LU SHUIMING; GUO RONGWEI; CHEN XUANHUA; AMOROSO DINO 权利人:ABDUR-RASHID KAMALUDDIN; JIA WENLI; LU SHUIMING; GUO RONGWEI; CHEN XUANHUA; AMOROSO DINO; KANATA CHEMICAL TECHNOLOGIES INC 摘要:The present disclosure relates to biaryl diphosphine ligands of the formula (B), processes for the production of the ligands and the use of the ligands in metal catalysts for asymmetric synthesis. The disclosure also relates to intermediates used for the production of the biaryl diphosphine ligand. (Formula (B))
专利号:CN-119119115-A 优先权日:2024-09-12 标题:Synthesis of allylic sulfur Process for the preparation of phosphorothioates
专利号:US-6878665-B2 优先权日:2001-09-28 标题:Diphosphines, their complexes with transisition metals and their use in asymmetric synthesis 发明人:DUPRAT DE PAULE SEBASTIEN; CHAMPION NICOLAS; VIDAL VIRGINIE; GENET JEAN-PIERRE; DELLIS PHILIPPE 权利人:SYNKEM 摘要:The invention relates to novel diphosphines, in optically pure or racemic form, of formula (I): n n nin which:n R 1 and R 2 are a (C 5 -C 7 )cycloalkyl group, an optionally substituted phenyl group or a 5-membered heteroaryl group; and A is (CH 2 —CH 2 ) or CF 2 . nn The invention further relates to the use of a compound of formula (I) as a ligand for the preparation of a metal complex useful as a chiral catalyst in asymmetric catalysis, and to the chiral metal catalysts comprising at least one ligand of formula (I).
专利号:CN-112920220-B 优先权日:2021-02-03 标 题:Method for aqueous phase synthesis of trifluoromethyl-containing C-2 phosphonoindole
专利号:CN-114591364-B 优先权日:2022-03-15 标 题 :A kind of synthesis method of thiophosphonate compounds