专利号:US-4404363-A 优先权日:1981-05-02 标题 :Separation of diphasic mixtures containing aromatic polyesters 发明人:FREITAG DIETER; SERINI VOLKER; GOOSSENS JOHN; BOTTENBRUCH LUDWIG; HUCKS UWE 权利人:BAYER AG 摘要:Diphasic mixtures obtained from the synthesis of aromatic polyesters by the diphasic interface process may be separated into an aqueous phase and an organic phase by the addition of selected compounds.
专利号:US-6596840-B1 优先权日:1999-07-19 标题 :Method for producing modified polycarbonates 发明人:KRATSCHMER SILKE; HUCKS UWE; BUNZEL LOTHAR 权利人:BAYER AG 摘要:A process for the synthesis of polycarbonate is disclosed. The process entails reacting in the presence of at least one phosphonium salt as catalyst, at least one diphenol, at least one carbonic acid diester, and at least one alkyl group-substituted phenol chain terminator. The chain terminator is introduced in free form or as a transesterifiable compound under the conditions of the synthesis. The polycarbonate thus produced is suitable for preparing a variety of molded articles.
专利号:US-9850345-B2 优先权日:2012-05-24 标题:Polycarbonate polyol compositions and methods 发明人:FARMER JAY J 权利人:SAUDI ARAMCO TECH CO 摘要:In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO 2 , wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.
专利号:US-9809678-B2 优先权日:2008-09-08 标 题:Polycarbonate polyol compositions and methods 发明人:ALLEN SCOTT D; COATES GEOFFREY W; CHERIAN ANNA E; SIMONEAU CHRIS A; GRIDNEV ALEXEI A; FARMER JAY J 权利人:NOVOMER INC; SAUDI ARAMCO TECH CO 摘要:In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.
专利号:US-12410280-B2 优先权日:2020-04-15 标 题:Synthesis, purification, and properties of ring-opened benzoxazine thermoplastic 发明人:ZHOU TIANLEI; YAO HAIQING; MIYAUCHI MASAHIKO 权利人:KANEKA CORP 摘要:A crosslinkable thermoplastic resin composition may include a polymer formed from the reaction between a bis-benzoxazine monomer and a bifunctional comonomer having phenol, amine, and/or thiol functional groups, wherein the polymer contains at least one crosslinkable group. A method of forming a crosslinkable thermoplastic resin composition may include reacting a bis-benzoxazine monomer and a bifunctional comonomer to form a polymer containing at least one crosslinkable group. A method of forming a cured thermoplastic resin may include curing the crosslinkable thermoplastic resin composition by applying an external stimulus.
专利号:US-4338429-A 优先权日:1979-07-13 标 题 :Process for working up polycarbonates 发明人:SERINI VOLKER; GOOSSENS JOHN; BOTTENBRUCH LUDWIG; FREITAG DIETER 权利人:BAYER AG 摘要:The present invention relates to a process for working up alkaline two-phase mixtures which have been obtained in the synthesis of polycarbonates by the two-phase boundary process, characterized in that for the separation of the alkaline two-phase mixture into an organic phase and an aqueous phase, the mixture is supplied with shearing energy and/or added are one or more cationic emulsifying agents and/or dispersing agents and/or in that, for the separation of the acidified two-phase mixture into an organic phase and an aqueous phase, the mixture is supplied with shearing energy and/or added are one or more cationic emulsifying agents and/or dispersing agents and/or in that the organic phase which was separated off after the acidification is washed with water to which one or more water-soluble, organic anionic compounds have been added.
[参考文献]: Jorge Regueiro, Et Al. Derivatization Of Bisphenol A And Its Analogues With Pyridine-3-Sulfonyl Chloride: Multivariate Optimization And Fragmentation Patterns By Liquid Chromatography/orbitrap Mass Spectrometry. Rapid Commun Mass Spectrom. 2015 Aug 30;29(16):1473-84. [参考文献]: Jorge Regueiro, Et Al. Determination Of Bisphenols In Beverages By Mixed-Mode Solid-Phase Extraction And Liquid Chromatography Coupled To Tandem Mass Spectrometry. J Chromatogr A. 2015 Nov 27:1422:230-238.
合成参考文献
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198