CAS: 2167-51-3; 4,4'-(1,4-Phenylenediisopropylidene)Bisphenol

该化合物是属于双酚家族的有机化合物,其特征是两个由连接的碳链连接的苯酚组,在结构上类似于其他双酚,如Bisphol A,但其化学特性和应用却各不相同.双酚P通常用于生产聚碳酸塑料和环氧树脂,这些塑料和树脂因其强度,热稳定性和对化学品的耐受性而备受重视.该化合物显示出一个高熔点,在正常条件下一般稳定.然而,与其他双酚一样,它引起了人们对其潜在的内分泌干扰效应和环境影响的关切.正在对其安全和监管状况进行研究,因为它可能带来与Bisphenol A相类似的风险.

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CAS号2948-46-1 二羟基-1,4-二异丙基苯 | CAS号108-95-2 苯酚

合成工艺路线路线简述

    📜1,4-双(1-甲基-1-羟乙基)苯,苯酚置于盐酸体系中,化学反应 3.5H,以65%的收率获得α,α'-二(4-羟基苯基)-1,4-二异丙基苯
    参考文献:新型对苯二酸苯并环芳基受体的合成与评价
    标题:新型对苯二酸苯并环芳基受体的合成与评价
    摘要:作为苯甲酸客体的潜在受体,合成了各自具有π电子富集部分和含有吡啶环的部分的新的二位环芳基主体分子.通过红外光谱,质子磁共振滴定实验和固态结构测定,探讨了潜在的分子受体与苯甲酸客体的络合作用.版权所有©2005 John Wiley&sons,Ltd.
    Doi:10.1002/poc.981

    海关参考信息

    专利信息


    专利号:US-4404363-A
    优先权日:1981-05-02
    标题 :Separation of diphasic mixtures containing aromatic polyesters
    发明人:FREITAG DIETER; SERINI VOLKER; GOOSSENS JOHN; BOTTENBRUCH LUDWIG; HUCKS UWE
    权利人:BAYER AG
    摘要:Diphasic mixtures obtained from the synthesis of aromatic polyesters by the diphasic interface process may be separated into an aqueous phase and an organic phase by the addition of selected compounds.

    专利号:US-6596840-B1
    优先权日:1999-07-19
    标题 :Method for producing modified polycarbonates
    发明人:KRATSCHMER SILKE; HUCKS UWE; BUNZEL LOTHAR
    权利人:BAYER AG
    摘要:A process for the synthesis of polycarbonate is disclosed. The process entails reacting in the presence of at least one phosphonium salt as catalyst, at least one diphenol, at least one carbonic acid diester, and at least one alkyl group-substituted phenol chain terminator. The chain terminator is introduced in free form or as a transesterifiable compound under the conditions of the synthesis. The polycarbonate thus produced is suitable for preparing a variety of molded articles.

    专利号:US-9850345-B2
    优先权日:2012-05-24
    标题:Polycarbonate polyol compositions and methods
    发明人:FARMER JAY J
    权利人:SAUDI ARAMCO TECH CO
    摘要:In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO 2 , wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.

    专利号:US-9809678-B2
    优先权日:2008-09-08
    标 题:Polycarbonate polyol compositions and methods
    发明人:ALLEN SCOTT D; COATES GEOFFREY W; CHERIAN ANNA E; SIMONEAU CHRIS A; GRIDNEV ALEXEI A; FARMER JAY J
    权利人:NOVOMER INC; SAUDI ARAMCO TECH CO
    摘要:In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

    专利号:US-12410280-B2
    优先权日:2020-04-15
    标 题:Synthesis, purification, and properties of ring-opened benzoxazine thermoplastic
    发明人:ZHOU TIANLEI; YAO HAIQING; MIYAUCHI MASAHIKO
    权利人:KANEKA CORP
    摘要:A crosslinkable thermoplastic resin composition may include a polymer formed from the reaction between a bis-benzoxazine monomer and a bifunctional comonomer having phenol, amine, and/or thiol functional groups, wherein the polymer contains at least one crosslinkable group. A method of forming a crosslinkable thermoplastic resin composition may include reacting a bis-benzoxazine monomer and a bifunctional comonomer to form a polymer containing at least one crosslinkable group. A method of forming a cured thermoplastic resin may include curing the crosslinkable thermoplastic resin composition by applying an external stimulus.

    专利号:US-4338429-A
    优先权日:1979-07-13
    标 题 :Process for working up polycarbonates
    发明人:SERINI VOLKER; GOOSSENS JOHN; BOTTENBRUCH LUDWIG; FREITAG DIETER
    权利人:BAYER AG
    摘要:The present invention relates to a process for working up alkaline two-phase mixtures which have been obtained in the synthesis of polycarbonates by the two-phase boundary process, characterized in that for the separation of the alkaline two-phase mixture into an organic phase and an aqueous phase, the mixture is supplied with shearing energy and/or added are one or more cationic emulsifying agents and/or dispersing agents and/or in that, for the separation of the acidified two-phase mixture into an organic phase and an aqueous phase, the mixture is supplied with shearing energy and/or added are one or more cationic emulsifying agents and/or dispersing agents and/or in that the organic phase which was separated off after the acidification is washed with water to which one or more water-soluble, organic anionic compounds have been added.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Jorge Regueiro, Et Al. Derivatization Of Bisphenol A And Its Analogues With Pyridine-3-Sulfonyl Chloride: Multivariate Optimization And Fragmentation Patterns By Liquid Chromatography/orbitrap Mass Spectrometry. Rapid Commun Mass Spectrom. 2015 Aug 30;29(16):1473-84.
    [参考文献]: Jorge Regueiro, Et Al. Determination Of Bisphenols In Beverages By Mixed-Mode Solid-Phase Extraction And Liquid Chromatography Coupled To Tandem Mass Spectrometry. J Chromatogr A. 2015 Nov 27:1422:230-238.

    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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