CAS: 2160-94-3; Cyclohex-3-Ene-1,1-Diyldimethanol

该化合物是一种双倍反应性二醇,是有机合成和聚合化学的多功能中间体,其双功能氢氧基组能够参与多凝聚反应,有助于生产高性能树脂,涂层和粘合剂.环己烷基骨使衍生聚合物具有僵硬性和热稳定性,而不饱和的基质则允许进一步的功能化或交叉连接.这一化合物因其反应性和结构稳定性的平衡而特别受到重视,使之适合需要定制的机械和化学特性的应用.它与各种工业工艺的兼容性进一步增强了其在先进材料开发中的效用.

结构式图片

相似化合物

1679-51-2 38511-09-0 50552-10-8

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

formaldehyd 3-Cyclohexene-1-carboxaldehyde cyclohex-3-ene-1,1-dicarboxylic acid diethyl ester 1,1-bis(hydroxymethyl)cyclohexane -1-cyclohexene4,4-bis(mesyloxy)methyl-1-cyclohexene 4,4-Bis(brommethyl)-1-cyclohexen 4,4-ditrityloxymethylcyclohexene

合成工艺路线路线简述

    📜Cyclohex-3-Ene-1,1-Dicarboxylic Acid Diethyl Ester置于lithium Aluminium Tetrahydride体系中,用 四氢呋喃 用作溶剂,化学反应 7.0H,反应生成3-环己基-1,1-二甲醇
    参考文献:Synthesis Of 4,4-Disubstituted 2-Aminocyclopentanecarboxylic Acid Derivatives And Their Incorporation Into 12-Helical β-Peptides
    标题:Synthesis Of 4,4-Disubstituted 2-Aminocyclopentanecarboxylic Acid Derivatives And Their Incorporation Into 12-Helical β-Peptides
    摘要:An Enantioselective Synthetic Route Is Reported For Trans-2-Aminocyclopentanecarboxylic Acids (Acpc) Bearing Geminal Side Chain Pairs At The 4-Position. Beta-Peptides Containing The 4,4-Disubstituted Acpc Residues Adopt The 12-Helical Conformation,As Demonstrated By 2D NMR Analysis In Aqueous Solution. These 4,4-Disubstituted Acpc Residues Display Functional Groups,Including Acidic And Hydrogen Bond Donating Groups,In A Geometrically Defined Fashion,Which Should Be Useful For The Design Of Beta-Peptides For Specific Applications.
    Doi:10.1021/ol0483293

    海关参考信息

    专利信息


    专利号:US-6410807-B1
    优先权日:2000-05-10
    标 题:Synthesis of cyclohexene dimethanol compounds
    发明人:YANG HU; CHING TA YEN; CAI GANGFENG
    权利人:CHEVRON PHILLIPS CHEMICAL CO
    摘要:A process for producing cyclohexene dimethanol or cyclohexane dimethanol compounds is provided. By controlling the rates of addition of certain reaction components and/or by controlling reaction solution temperatures at specific stages during synthesis, this invention provides a process for producing high purity cyclohexene dimethanol or cyclohexane dimethanol compounds without the need for solvent extraction and/or recrystallization procedures.

    专利号:US-11292873-B2
    优先权日:2013-11-05
    标 题 :Etheramines prepared from a mixture of two or more multifunctional alcohol initiators, and their use as curatives or intermediates for polymer synthesis
    发明人:ZHOU HUI; LEWIS DAVID C; KLEIN HOWARD P; RENKEN TERRY L; PATTERSON LEAH
    权利人:HUNTSMAN PETROCHEMICAL LLC
    摘要:Implementations described herein generally relate to etheramine mixtures formed from a mixture of two or more multifunctional alcohol initiators, processes for the etheramine mixtures production, and its use as a curing agent or as a raw material in the synthesis of polymers. In one implementation, the process comprises mixing a polyol initiator having a melting point greater than a processing temperature and a polyol initiator having a melting point less than the processing temperature to form a polyol initiator mixture having a melting point less than the processing temperature, charging the polyol initiator mixture to an alkoxylation reaction zone, contacting the polyol initiator mixture with an alkylene oxide in the alkoxylation reaction zone to provide a mixture of alkoxylated precursor polyols and charging the mixture of alkoxylated precursor polyols to a reductive amination zone and reductively aminating the mixture of alkoxylated precursor polyols to form the etheramine mixture.

    专利号:US-11015015-B2
    优先权日:2016-01-12
    标 题 :Co-preparation of polyetheramines and alklyene amines
    发明人:ZHOU HUI; KLEIN HOWARD P; LEWIS DAVID C
    权利人:HUNTSMAN PETROCHEMICAL LLC
    摘要:The present disclosure provides a process for the co-preparation of a polyetheramine and an alkylene amine mixture by aminating a liquid polyol initiator mixture comprising an alkoxylated alcohol and a solid high melting polyol. The polyetheramine and alkylene amine mixture may be used in a variety of applications, such as a curing agent for epoxy resin formulations or as a raw material in the synthesis of polyurea.

    专利号:US-9067865-B2
    优先权日:2009-12-22
    标题:Etheramines and their use as intermediates for polymer synthesis
    发明人:KLEIN HOWARD P; RENKEN TERRY L; RENNER MARTIN J; BURTON BRUCE L; DARRAGAS KATTY
    权利人:KLEIN HOWARD P; RENKEN TERRY L; RENNER MARTIN J; BURTON BRUCE L; DARRAGAS KATTY; HUNTSMAN PETROCHEMICAL LLC
    摘要:The present invention relates to an etheramine mixture containing a monoether diamine and its method of production by alkoxylating an initiator with an alkylene oxide to produce a precursor polyol and reductively aminating the precursor polyol to form the etheramine mixture. The etheramine mixture may be used in variety of applications including as a curing agent for an epoxy resin or as a reactant in the production of polyurea.

    专利号:US-9822215-B2
    优先权日:2013-10-18
    标题 :Etheramines with enhanced thermal stability and their use as curatives or intermediates for polymer synthesis
    发明人:ZHOU HUI; LEWIS DAVID C; KLEIN HOWARD P; RENKEN TERRY L
    权利人:HUNTSMAN PETROCHEMICAL LLC
    摘要:Implementations described herein relate to an etheramine mixture containing a cyclobutane based amine and its method of production by alkoxylating an initiator with an alkylene oxide to produce a precursor polyol and reductively aminating the precursor polyol to form the ehteramine mixture. The etheramine mixture may be used in a variety of applications including as a curing agent for an epoxy resin or as a reactant in the production of polyurea materials.

    专利号:US-5310943-A
    优先权日:1991-03-11
    标题 :Aromatic trisanhydrides
    发明人:BLYAKHMAN YEFIM
    权利人:CIBA GEIGY CORP
    摘要:Aromatic trisanhydrides of the formula (I) ##STR1## wherein R is hydrogen, C 1 -C 4 alkyl or aryl are useful for the synthesis of star-branched and star-burst polyester-imides and polyesterimide-amides and as curing agents for epoxy resins, phenolics and polyesters.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(27), 1982
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