CAS: 191-30-0; Naphtho[1,2,3,4-Pqr]Tetraphene

该化合物是一种多环芳烃(PAH),其特点是有引信的芳香环结构,具有显著的稳定性和独特的电子特性,该化合物因其扩展的融合,对材料科学和有机电子具有重大兴趣,有利于在光排放有机二极管和光伏电池等光电子设备的应用,其硬板结构也使它成为合成化学中建造复杂的芳香系统的宝贵中间体.Dibenzodef,pchrysene展示高热性和氧化性稳定性,使其适合高性能材料.研究人员重视其可预见的再活动性和功能化潜力,并允许对具体应用进行有针对性的修改.

结构式图片

欧盟法规

统一分类与标签ECHA物质ECHA物质工作场所安全标识要求化妆品禁用物质清单C&L通报食品接触材料-禁用CMR物质REACH预注册废弃物危险特性清单

上下游产品

Pentahelicen-3-carbonsaeure-methylester benz[a]anthracene benzene anthracen1-Phenylbenzanthracenpyren10-Formyl-dibenzopyren

合成工艺路线路线简述

  • 合成目标产物 Dibenzo(A,I)Pyrene 主要起始原料 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
  • (文献来源)合成步骤主要原料 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
📜9-(2-Methoxy-Vinyl)-Benzo[g]Chrysene置于甲烷磺酸体系中,用 二氯甲烷 用作溶剂,化学反应 2.5H,以75%的收率获得二苯并(A,L)芘
参考文献:二苯并[def,P]],其活性代谢产物及其13C标记类似物的合成.
标题:二苯并[def,P]],其活性代谢产物及其13C标记类似物的合成.
摘要:二苯并[def,P]((dbc)是一种高度致癌的多环芳烃,被怀疑与吸烟者的肺癌发病有关.报道了dbc,其活性代谢物[dbc二醇(1),Dbc二酮(2),Dbc二醇环氧化物(3)]以及它们先前未知的13C2标记的类似物的高效新合成方法.需要13C2标记的类似物作为使用稳定同位素稀释液相色谱/串联质谱法分析人细胞中dna加合物的灵敏方法的标准品.
Doi:10.1021/ol7029323

海关参考信息

专利信息


专利号:US-8288497-B2
优先权日:2008-02-27
标 题 :Synthesis of poly-(P-aryleneethynylene)s in neat water under aerobic conditions
发明人:KANG YOUN K; DERIA PRAVAS; THERIEN MICHAEL J
权利人:KANG YOUN K; DERIA PRAVAS; THERIEN MICHAEL J; UNIV PENNSYLVANIA
摘要:Provided are ethyne synthons comprising boron and related methods. Also provided are related water-soluble arylethynylene polymers capable of being synthesized in neat water under aerobic conditions.

专利号:US-3965049-A
优先权日:1972-10-24
标 题 :One-step synthesis of aromatic organic diselenides
发明人:GRUSHKIN BERNARD; SALZMAN MICHAEL N
权利人:XEROX CORP
摘要:Disclosed is a novel method for the preparation of aromatic organic diselenide compounds. The method involves reacting an alkali metal diselenide with certain halogenated aromatic compounds in dimethylformamide to form the corresponding aromatic diselenide. The use of dimethylformamide enables one to prepare certain aromatic diselenide compounds containing two replaceable halogen atoms in a one-step process.

专利号:US-2009326150-A1
优先权日:2008-02-27
标题:Synthesis of poly-(p-aryleneethynylene)s in neat water under aerobic condit

专利号:US-2011257356-A1
优先权日:2008-02-27
标题:Synthesis of Poly-(P-Aryleneethynylene)s in Neat Water Under Aerobic Conditions

专利号:US-2006211792-A1
优先权日:2003-08-01
标 题:Triangulenium fluorescent dyes and polymers comprising such dyes
发明人:LAURSEN BO W
权利人:LAURSEN BO W
摘要:The invention relates to fluorescent dyes comprising a triangulene structure in the form of a ring system of six, six-membered rings fused in a triangular fashion. The dyes are useful for visualisation of chemical compounds including polymer matrices for e.g. chromatographic separation and isolation of desirable chemical moieties, and for chemical library synthesis.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

参考标题:A Highly Abbreviated Synthesis Of Dibenzo[Def,P]Chrysene And Its 12-Methoxy Derivative, A Key Precursor For The Synthesis Of The Proximate And Ultimate Carcinogens Of Dibenzo[Def,P]Chrysene
作者:Arun K. Sharma,Subodh Kumar,Shantu Amin |发布日期:2004.5.1
摘要:Dibenzo[def,P]Chrysene (Dbc) (1), Is By Far The Most Mutagenic And Toxic Polycyclic Aromatic Hydrocarbon Identified. Its Metabolic Activation Leads To Trans-11,12-Dihydroxy-11,12-Dihydro-Dbc (2), Which Is Further Metabolized To The Ultimate Metabolite, Anti-Trans-11,12-Dihydroxy-13,14-Epoxy-11,12,13,14-Tetrahydro-Dbc (3), That Binds To Dna Causing Mutations And Ultimately Tumor Induction. We Report

合成参考文献


参考文献:10.1021/es201443z
摘要:Wang W, Jariyasopit N, Schrlau J, Jia Y, Tao S, Yu T, Dashwood RH, Zhang W, Wang X, Simonich SLM. Concentration and Photochemistry of PAHs, NPAHs, and OPAHs and Toxicity of PM2.5 during the Beijing Olympic Games. Environ. Sci. Technol. 2011 Jul 18;45(16):6887–95. doi: 10.1021/es201443z.
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