CAS: 131-79-3; (E)-1-(O-Tolyldiazenyl)Naphthalen-2-Amine
该化合物是以其氯化萘核心和正对方替代成分为特征的氮化合物,通过二二苯基功能组相连,具有稳定性和独特的电子特性,在染色合成和协调化学等应用中有用.该化合物由于其同化的系统而表现出强烈的染色光学行为,能够吸收到可见频谱中.其僵硬分子框架增强了热和光化学稳定性,而地雷组则为进一步功能化提供了再活性.该化合物在研究中特别受到重视,因为其具有在有机和有机金属合成中作为木质或中间体的潜力.建议在惰性条件下进行适当处理,以维护其完整性.
- 英文名称(E)-1-(O-Tolyldiazenyl)Naphthalen-2-Amine
- 中文名称1-(2-甲基苯基)偶氮萘-2-胺
- IUPAC名称(E)-1-(o-tolyldiazenyl)naphthalen-2-amine
- 其它别名1-((2-Methylphenyl)Azo)-2-Naphthalenamine; 1-(2-Methylphenyl)Azo-2-Naphthalenamine; 1-(2-Methylphenyl)Azo-2-Naphthylamine; 1-(2-O-Tolylazo)-2-Naphthylamine; 1-(O-Tolylazo)-2-Naphthylamin; 1-(O-Tolylazo)-2-Naphthylamine; 1-[(2-Methylphenyl)Azo]Naphthalen-2-Amine
- CAS编号131-79-3
- MFCD编号:MFCD00046381
- EINECS号:205-039-9
- FDA UNII编号:QE535CBH7S
- 分子式:C17H15N3分子量:261.33
- 产品CID: 484760
- 产品分类有机原料 → 苯类化合物 → 萘
物理性质
MSDS等安全信息
合成工艺路线路线简述
- 合成目标产物 Oil Yellow Ob 主要起始原料 O-Toluidine Hydrochloride And 2-Naphthalenediazonium, Chloride (1:1)
- (文献来源)合成步骤主要原料 O-Toluidine Hydrochloride 和 2-Naphthalenediazonium, Chloride (1:1)
📜2-甲基苯胺 盐酸盐,Naphthalene-2-Diazonium Chloride置于水,Sodium Acetate体系中,化学反应生成1-(2-甲基苯基)偶氮萘-2-胺
参考文献:Norman,Journal Of The Chemical Society,1912,Vol. 101,P. 1922,1923
标题:Norman,Journal Of The Chemical Society,1912,Vol. 101,P. 1922,1923
海关参考信息
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主要参考文献
1: Larder CE, Abergel M, Kubow S, Donnelly DJ. Freeze-drying affects the starch digestibility of cooked potato tubers. Food Res Int. 2018 Jan;103:208-214. doi: 10.1016/j.foodres.2017.10.034. Epub 2017 Oct 24. doi: 10.1016/j.jphotobiol.2017.10.015. Epub 2017 Oct 12. doi: 10.4315/0362-028X.JFP-16-516. Available from http://www.ncbi.nlm.nih.gov/books/NBK430769/ doi: 10.1080/19440049.2017.1290829. Epub 2017 Feb 20. doi: 10.1039/c6fo01592a. doi: 10.1016/j.talanta.2016.07.011. Epub 2016 Jul 5. doi: 10.1016/j.talanta.2015.10.075. Epub 2015 Oct 27. doi: 10.2166/wst.2015.412. doi: 10.1016/j.aca.2015.06.013. Epub 2015 Jul 9. doi: 10.1021/jf5045052. Epub 2014 Nov 24. doi: 10.1080/19393210.2014.945195. Epub 2014 Aug 13. Chinese. Chinese. doi: 10.1371/journal.pone.0092132. eCollection 2014.
16: Weisz A, Ridge CD, Roque JA, Mazzola EP, Ito Y. Preparative separation of two subsidiary colors of FD&C Yellow No. 5 (Tartrazine) using spiral high-speed counter-current chromatography. J Chromatogr A. 2014 May 23;1343:91-100. doi: 10.1016/j.chroma.2014.03.059. Epub 2014 Mar 29.
17: Gan T, Sun J, Meng W, Song L, Zhang Y. Electrochemical sensor based on graphene and mesoporous TiO2 for the simultaneous determination of trace colourants in food. Food Chem. 2013 Dec 15;141(4):3731-7. doi: 10.1016/j.foodchem.2013.06.084. Epub 2013 Jun 28. doi: 10.1111/1750-3841.12068. Epub 2013 Mar 6. doi: 10.1002/elps.201200425. Epub 2013 Feb 19. doi: 10.1007/s11033-012-1873-8. Epub 2012 Jul 7.
合成参考文献
摘要:Journal of Biological Chemistry., 27(403), 1916
摘要:Prehled Prumyslove Toxikologie; Organicke Latky, Marhold, J., Prague, Czechoslovakia, Avicenum, 1986, -(1315), 1986
摘要:Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 7-4, 7-5, 8-12 (1990)
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
摘要:21 CFR 81.10 (USFDA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of April 3, 2012: https://www.ecfr.gov
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