CAS: 108180-34-3; 1-(Tert-Butyl)-3,5-Bis(2-Methoxypropan-2-yl)Benzene

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106594-40-5 1999-85-5 71522-57-1

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上下游产品

1-Bis(1-Hydroxy-1-Methylethyl)-5-(1,1-Dimethylethyl)Benzene 75894-05-2
2-Bromo-5-T-Butyl-1,3-Bis(1-Methoxy-1-Methylethyl)Benzene 259197-86-9

合成工艺路线路线简述

    📜2-Bromo-5-T-Butyl-1,3-Bis(1-Methoxy-1-Methylethyl)Benzene置于正丁基锂,水体系中,用 四氢呋喃,正己烷 用作溶剂,化学反应 0.33H,以96%的收率获得1-叔丁基-3,5-二(2-甲氧基-2-丙烷基)苯
    参考文献:带有庞大的4-叔丁基-2,6-双(甲氧基烷基)苯基的二硫代-和二硒代氧膦类化合物的形成和重排
    标题:带有庞大的4-叔丁基-2,6-双(甲氧基烷基)苯基的二硫代-和二硒代氧膦类化合物的形成和重排
    摘要:[4-叔丁基-2,6-双(1-甲氧基-1-甲基乙基)苯基]膦,[4-叔丁基-2,6-双(2-甲氧基-1,1-二甲基乙基)苯基]制备了膦和[4-叔丁基-2,6-双(3-甲氧基-1,1-二甲基丙基)苯基]膦,并使其与硫或硒反应,得到含磷-氧键的杂环化合物,通过甲氧基的甲基部分的重排.
    Doi:10.1016/s0040-4020(99)00771-1

    专利信息


    专利号:US-2013190525-A1
    优先权日:2012-01-24
    标题:Synthetic methods pertaining to tert-butyl-benzene-based compounds
    发明人:DELANEY JR JOSEPH THOMAS; SEETHAMRAJU KASYAP; GROSSO PAUL VINCENT
    权利人:BOSTON SCIENT SCIMED INC; BOSTON SCIENT SCIMED INC
    摘要:According to some aspects, the present disclosure pertains to methods of forming dimethyl 5-tert-butylisophthalate which comprise comprising converting 5-tert-butylisophthalic acid into dimethyl 5-tert-butylisophthalate in synthesis procedures that comprises methanol and a dehydrating agent as chemical reagents. In other aspects, the present disclosure pertains to methods of forming 5-tert-butyl-1,3-bis(1-methoxy-1-methylethyl)benzene that comprise deprotonating 5-tert-butyl-1,3-bis(1-hydroxy-1-methylethyl)benzene with a Brønsted-Lowry superbase and methylating the deprotonated 5-tert-butyl-1,3-bis(1-hydroxy-1-methylethyl)benzene to form the 5-tert-butyl-1,3-bis(1-methoxy-1-methylethyl)benzene.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/bf00285351|10.1007/bf00285352|10.1007/bf00955713
    摘要:Mishra MK, Wang B, Kennedy JP. Living carbocationic polymerization. Polymer Bulletin. 1987 Apr;17(4):307–14. doi: 10.1007/bf00955713.
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