CAS: 83724-41-8; Tris(2-Methoxyphenyl)Bismuthine

该化合物是一种有机体化合物,由三组2-甲基苯基组成,与中双氧原子结合,该化合物对合成和协作化学感兴趣,因为电子施放混合氧基组影响其反应性和稳定性.该化合物是基于二氟苯基催化剂和离心剂的前体,特别是在需要温和的刘易斯酸性或红氧化活性行为的反应中.甲基氧替代成分可提高有机溶剂的溶性,促进其在同质系统中的使用.其定义明确的结构使其适合在双氧介质变异中进行机械学研究.由于对空气和湿度的潜在敏感性,建议谨慎处理.

结构式图片

相似化合物

603-33-8 121899-81-8 10050-08-5

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报

上下游产品

4-methoxyphenyl magnesium bromide bismuth 2-methoxybenzenediazonium chloride bismuth(III) chloridetris(2-methoxyphenyl)bismuth difluoride tris(2-methoxyphenyl)bismuth dichloride (dimethyl sulfide)(2-methoxyphenyl)gold(I) tetrakis(2-methoxyphenyl)bismuthonium bromide monohydrate

合成工艺路线路线简述

  • 16750-63-3 = 83724-41-8
    反应条件:1.1 Reagents: Bismuth Trichloride Solvents: Tetrahydrofuran; 0 °C; 1 H,Rt; 30 Min,Rt -> 65 °C; 65 °C -> Rt1.2 Reagents: Sodium Chloride; Rt
    标题:High Efficient Copper-Promoted N-Arylation Of Secondary And Primary Amines With Triarylbismuth Reagents Under Mild Conditions
    作者:Zhou,Xuehao; Et Al
    参考文献:Journal Of Molecular Structure 日期:2023 卷标:1294]

    16750-63-3 = 83724-41-8
    反应条件:1.1 Reagents: Bismuth Trichloride
    标题:Estimation Of The Magnitude Of Quadrupole Relaxation Enhancement In The Context Of Magnetic Resonance Imaging Contrast
    作者:Kruk,Danuta; Et Al
    参考文献:Journal Of Chemical Physics 日期:2019 卷标:150(18) 页码:184306/1-184306/9]

    529-28-2 = 83724-41-8
    反应条件:1.1 Reagents: Calcium Carbonate,Copper,Bismuth,Cuprous Iodide; 12 H,Rt
    标题:A Novel Dry Route To Ortho-Functionalized Triarylbismuthanes That Are Difficult To Access By Conventional Wet Routes
    作者:Urano,Mika; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2003 卷标:(10) 页码:1202-1203]

    = 83724-41-8 + 791-28-6
    反应条件:1.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480]

    = 83724-41-8 + 791-28-6
    反应条件:1.1 Solvents: Chloroform-D
    标题:Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant For The Conversion Of Alcohols To Carbonyl Compounds
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(26) 页码:6443-6444]

    603-36-1 = 83724-41-8 + 4756-75-6
    反应条件:1.1 Solvents: Chloroform-D
    标题:Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant For The Conversion Of Alcohols To Carbonyl Compounds
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(26) 页码:6443-6444]

    121899-81-8 = 83724-41-8 + 1153-05-5
    反应条件:1.1 Reagents: Potassium Tert-Butoxide,Water Solvents: Dichloromethane; 2 H,0 °C2.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480]

    121899-81-8 = 83724-41-8 + 791-28-6
    反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Dichloromethane1.2 Solvents: Acetonitrile2.1 Solvents: Chloroform-D
    标题:Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant For The Conversion Of Alcohols To Carbonyl Compounds
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(26) 页码:6443-6444]

    = 83724-41-8 + 1153-05-5
    反应条件:1.1 Reagents: Potassium Tert-Butoxide,Water Solvents: Dichloromethane; 2 H,0 °C2.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480]

    762-42-5 = 83724-41-8
    反应条件:1.1 Solvents: Dichloromethane2.1 -
    标题:Stabilized Bismuthonium Ylides Bearing A Highly Cross-Conjugated Ylidic Carbon Atom: Synthesis,Structures,And Reactions
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of Organometallic Chemistry 日期:2000 卷标:611(1-2) 页码:89-99]

    762-42-5 + 313973-99-8 = 83724-41-8 + 162999-92-0
    反应条件:1.1 Solvents: Dichloromethane2.1 -
    标题:Stabilized Bismuthonium Ylides Bearing A Highly Cross-Conjugated Ylidic Carbon Atom: Synthesis,Structures,And Reactions
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of Organometallic Chemistry 日期:2000 卷标:611(1-2) 页码:89-99]

    = 83724-41-8
    反应条件:1.1 Solvents: Benzene
    标题:Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant For The Conversion Of Alcohols To Carbonyl Compounds
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(26) 页码:6443-6444]

    578-57-4 = 83724-41-8
    反应条件:1.1 Reagents: Zinc Catalysts: Trifluoroacetic Acid,Allyl Chloride,Cobalt Dibromide Solvents: Acetonitrile; 15 Min,20 °C1.2 20 °C1.3 Reagents: Bismuth Trichloride Solvents: Acetonitrile; 18 H,20 °C
    标题:Advanced Preparation Of Functionalized Triarylbismuths And Triheteroaryl-Bismuths: New Scope And Alternatives
    作者:Urgin,Karene; Et Al
    参考文献:Tetrahedron Letters 日期:2012 卷标:53(15) 页码:1894-1896]

    31600-86-9 = 83724-41-8
    反应条件:1.1 Reagents: Bismuth Trichloride Solvents: Tetrahydrofuran
    标题:Aryl Bismuth Phosphinates [biar2(O(O)Prr')]: Structure-Activity Relationships For Antibacterial Activity And Cytotoxicity
    作者:Herdman,Megan E.; Et Al
    参考文献:Dalton Transactions 日期:2022 卷标:51(24) 页码:9323-9335]

    121899-81-8 = 83724-41-8
    反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Dichloromethane1.2 Solvents: Acetonitrile2.1 Solvents: Benzene
    标题:Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant For The Conversion Of Alcohols To Carbonyl Compounds
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(26) 页码:6443-6444]

    = 83724-41-8 [标题:Reaction Conditions
    标题:Stabilized Bismuthonium Ylides Bearing A Highly Cross-Conjugated Ylidic Carbon Atom: Synthesis,Structures,And Reactions
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of Organometallic Chemistry 日期:2000 卷标:611(1-2) 页码:89-99]

    = 83724-41-8 + 162999-92-0 [标题:Reaction Conditions
    标题:Stabilized Bismuthonium Ylides Bearing A Highly Cross-Conjugated Ylidic Carbon Atom: Synthesis,Structures,And Reactions
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of Organometallic Chemistry 日期:2000 卷标:611(1-2) 页码:89-99]

    603-32-7 = 83724-41-8 + 1153-05-5
    反应条件:1.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480]

    603-32-7 = 83724-41-8 + 1153-05-5
    反应条件:1.1 Solvents: Chloroform-D
    标题:Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant For The Conversion Of Alcohols To Carbonyl Compounds
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(26) 页码:6443-6444]

    603-36-1 = 83724-41-8 + 4756-75-6
    反应条件:1.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480]

    121899-81-8 = 83724-41-8 + 1153-05-5
    反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Dichloromethane1.2 Solvents: Acetonitrile2.1 Solvents: Chloroform-D
    标题:Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant For The Conversion Of Alcohols To Carbonyl Compounds
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(26) 页码:6443-6444]

    121899-81-8 = 83724-41-8 + 4756-75-6
    反应条件:1.1 Reagents: Potassium Tert-Butoxide,Water Solvents: Dichloromethane; 2 H,0 °C2.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480]

    121899-81-8 = 83724-41-8 + 4756-75-6
    反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Dichloromethane1.2 Solvents: Acetonitrile2.1 Solvents: Chloroform-D
    标题:Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant For The Conversion Of Alcohols To Carbonyl Compounds
    作者:Matano,Yoshihiro; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(26) 页码:6443-6444]

    121899-81-8 = 83724-41-8 + 791-28-6
    反应条件:1.1 Reagents: Potassium Tert-Butoxide,Water Solvents: Dichloromethane; 2 H,0 °C2.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480]

    = 83724-41-8 + 4756-75-6
    反应条件:1.1 Reagents: Potassium Tert-Butoxide,Water Solvents: Dichloromethane; 2 H,0 °C2.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480]

    = 83724-41-8 + 791-28-6
    反应条件:1.1 Reagents: Potassium Tert-Butoxide,Water Solvents: Dichloromethane; 2 H,0 °C2.1 Solvents: Dichloromethane; 30 Min,Rt
    标题:Diverse Structures And Remarkable Oxidizing Ability Of Triarylbismuthane Oxides. Comparative Study On The Structure And Reactivity Of A Series Of Triarylpnictogen Oxides
    作者:Matano,Yoshihiro; Et Al
    参考文献:Organometallics 日期:2004 卷标:23(23) 页码:5471-5480
📜2-溴苯甲醚置于正丁基锂,Bismuth(Iii) Chloride体系中,用 四氢呋喃,正己烷 作为反应溶剂,化学反应 2.0H,反应生成 三(2-甲氧苯基)铋
参考文献:Herbicide Composition
标题:Herbicide Composition
摘要:提供一种除草剂组合物,含有由化学式(i)表示的环己酮化合物和至少一种来自a组的化合物. A组:包括苯氧草酮,氯喹托西酮-甲醇,氰甲胺,二氯胺,乙基氟唑醇,氟唑胺,氟唑胺,呋唑胺,二乙基甲基苯酯,奥萨贝特林,乙基异氧苯酮,环丙磺胺,氟苯咪,1,8-萘酐和ad-67.

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专利信息


专利号:US-12043893-B2
优先权日:2017-08-24
标题:Manufacturing processes to synthesize, functionalize, surface treat and/or encapsulate powders, and applications thereof
发明人：KING DAVID; DAMERON ARRELAINE; TREVEY JAMES; LICHTY PAUL; ARGO ANDREW; BOURGOIS KYLE; RAGONESI JAMES; INGHAM KYLE; JACKSON DAVID; TRACY RYON; NGUYEN NGHI; LYON ADAM; VILLAGOMEZ JOSE; CURRY GARRETT
权利人:FORGE NANO INC
摘要:A system, apparatus and method are provided for processing articles. The system includes subsystems for synthesizing, pre-treating, conducting a vapor phase coating process and post-treating articles in the form of powders and solid or porous workpieces. The apparatus permits vapor phase synthesis, treatment and deposition processes to be performed with high efficiency and at high overall throughput. The methods include converting solids, liquids or gases into gaseous and solid streams that can be separated or exchanged with or without treatment and/or coating steps, and produce optimized composite articles for specific applications.

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合成参考文献


摘要:Gagnon, A.; Benoit, E.; Le Roch, A., Science of Synthesis Knowledge Updates, (2018) 4, 15.
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