CAS: 14606-42-9; Triphenylsilanethiol

该化合物是有机硅化合物,其特点是三联苯基组和硫醇功能组存在硅原子,这种化合物一般是无色的,可粉黄液或固体,视其纯度和具体条件而定;其独特性能为人所知,包括由于硫醇组而具有的核素行为能力,可参与各种化学反应,如硫醇-乙烯反应和金属协调;三联苯硅硝基醇在材料科学中的潜在应用,特别是在开发硅基涂层和聚合化学中的混合剂方面,也值得注意;此外,该化合物在有机溶剂中表现出中等溶解性,使其适应各种合成过程;然而,与许多有机硅化合物一样,应谨慎处理,因为其潜在的毒性和再活性,特别是在存在强氧化剂的情况下.

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物理性质

MSDS等安全信息

上下游产品

CAS号789-25-3 三苯基硅烷 | CAS号76-86-8 三苯基氯硅烷 | CAS号7783-06-4 硫化氢

合成工艺路线路线简述

    📜三苯基氯硅烷置于硫化氢,三乙胺体系中,用 苯 用作溶剂,化学反应生成三苯基硅烷硫醇
    参考文献:Etienne,Bulletin De La Societe Chimique De France,1953,P. 791
    标题:Etienne,Bulletin De La Societe Chimique De France,1953,P. 791

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    专利信息


    专利号:US-2024199569-A1
    优先权日:2022-11-30
    标 题:Process for the manufacture of inhibitors of kras
    发明人：ZHANG YONGDA; CHONG EUGENE; REEVES JONATHAN TIMOTHY; WHITE JADA A H; LEI ZHEN
    权利人:BOEHRINGER INGELHEIM INT
    摘要:This invention relates to an efficient and enantioselective synthesis of the spiro-compounds of formula (1) as common intermediate, featuring an asymmetric introduction of the all-carbon quaternary centre in high selectivity and a very efficient one-pot procedure for the C2 elongation to generate the spiro-structure.For the all-carbon quaternary centre, a Tsuji-Trost asymmetric allylic alkylation (AAA) process was designed to develop a sustainable procedure with very low catalyst loading, thereby also facilitating the Pd content control in the product, under practically solvent free conditions. Furthermore, multiple synthetic transformations in a one-pot procedure were implemented by using a one-pot procedure either in form of a three-transformation sequence comprising Hydroboration-Alkylation-Dieckmann Condensation to compound of formula (1) or in form of a five-transformation sequence comprising Hydroboration-Alkylation-Dieckmann Condensation-Hydrolysis-Decarboxylation to compound of formula (9).

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    主要参考文献

    参考标题:Reactions Of Monodithiolene Tungsten(Vi) Sulfido Complexes With Copper(I) In Relation To The Structure Of The Active Site Of Carbon Monoxide Dehydrogenase
    作者:Stanislav Groysman,Amit Majumdar,Shao-Liang Zheng,R. H. Holm |发布日期:2010.2.1
    摘要:Reactions Directed At The Synthesis Of Structural Analogues Of The Active Site Of Molybdenum-Containing Carbon Monoxide Dehydrogenase Have Been Investigated Utilizing [wo2S(Bdt)]2− (1) And [wos2(Bdt)]2− (2) And Sterically Hindered [cu(R)L] Or [cu(Ssir′3)2]− As Reactants. All Successful Reactions Of 2 Afford The Binuclear Wvi/cui Products [wo(Bdt)(μ2-S)2Cu(L)]2−/− With L = Carbene (3), Ar*s (4), Ar*

    合成参考文献


    摘要:Tang, R.-Y., Science of Synthesis: Knowledge Updates, (2024) 1, 346.
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