CAS: 10294-31-2; Gold(I) Iodide

该化合物是一种化学化合物,由加1氧化状态的黄金组成,含碘为1氧化状态;它是在水中溶解性低的黄色至橙色固体,适合在水中需要稳定的应用;AuI 主要是用于催化,特别是有机合成,在有机合成中,它可成为混合和循环反应的温和选择性催化剂;高热稳定性和对氧化的抗药性在高温工艺中是有利的;此外,Gold(I) 碘化物因其独特的电子特性,被用于材料科学,用于制备含黄金的半导体和光电子装置.

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gold gold(I) oxide iodine potassium iodideN,N'-diphenylformamidinato gold(I) 3ammonium-bis{2,4,6-tri(isopropyl)thiophenolato}aurate(I)*3NH3 iodo[tris(2,4,6-trimethoxyphenyl)phosphine]gold(I) 22H16AuI2PC22H16AuI2P

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    专利信息


    专利号:US-8641798-B2
    优先权日:2010-07-13
    标 题 :One-step synthesis of monodisperse AU-CU nanocubes
    发明人:HIGHT-WALKER ANGELA R; LIU YONGLIN
    权利人:HIGHT-WALKER ANGELA R; LIU YONGLIN; US OF AMERICA AS REPRESENTED BY THE SECRETARY OF COMMERCE NIST
    摘要:A one-step process for synthesizing gold-copper bimetallic nanocubes. The process comprises the step of simultaneously reducing a copper II salt and a gold halide by 1,2-hexadecanediol in diphenyl ether, and 1-dodecanethiol as well as surfactants 1-adamantanecarboxylic acid and 1-hexadecylamine. The copper II salt may be copper (II) acetylacetonate, copper chloride, copper sulfate, or copper phosphate. The gold halide may be chloroauric acid, gold chloride, gold bromide, or tetrabromoauric acid. The reduction may occur at a temperature between about 160 and 180 degrees Celsius. The copper II salt may be copper (II) acetylacetonate and the gold halide may be chloroauric acid.

    专利号:US-9822053-B2
    优先权日:2016-01-28
    标题:Single step conversion of N-butyraldehyde to 2-ethylhexanal
    发明人:BOPPANA Venkata Bharat; HAMPTON JR KENNETH WAYNE; LIU ZHUFANG; SUMNER JR CHARLES EDWAN; TUSTIN GERALD C; STEINMETZ GUY RALPH; STEFFEY MELISSA PAGE
    权利人:EASTMAN CHEM CO
    摘要:Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.

    专利号:US-9217088-B2
    优先权日:2006-08-03
    标 题:Particles and inks and films using them
    发明人:PARASHAR SACHIN; SARKAR SIULI; KHASELEV OSCAR; LEWIS BRIAN G; MARCZI MICHAEL T; SINGH BAWA; DESAI NITIN; LIBERATORE MICHAEL
    权利人:PARASHAR SACHIN; SARKAR SIULI; KHASELEV OSCAR; LEWIS BRIAN G; MARCZI MICHAEL T; SINGH BAWA; DESAI NITIN; LIBERATORE MICHAEL; ALPHA METALS
    摘要:Particles and particle films are provided. In certain examples, particles produced from a single phase process may be used to provide industrial scale synthesis of particles for use in devices such as printed wiring boards.

    专利号:US-9365666-B2
    优先权日:2012-05-30
    标题 :Polymerization catalyst composition, method for producing synthetic polyisoprene, and synthetic polyisoprene
    发明人:KAITA SHOJIRO; TAMAKI SATORU
    权利人:BRIDGESTONE CORP
    摘要:A polymerization catalyst composition that, without accompanying excessive gelation, allows efficient synthesis of high molecular weight polyisoprene under industrial conditions is provided. The polymerization catalyst composition contains:n a rare earth element compound (component (A)) represented by the following general formula (i):n nM-(NQ 1 )(NQ 2 )(NQ 3 )  (i);n at least one (component (B)) selected from an ionic compound and a halogen compound; and a compound (component (C)) represented by the following general formula (X):n nYR 1 a R 2 b R 3 c   (X).

    专利号:CN-103288121-A
    优先权日:2012-02-22
    标题 :Synthesis of monovalent gold complexes by reverse disproportionation reaction

    专利号:US-2011283834-A1
    优先权日:2010-07-13
    标题:One-step synthesis of monodisperse au-cu nanocubes

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    合成参考文献


    摘要:Hopkinson, M. N.; Gouverneur, V., Science of Synthesis Knowledge Updates, (2011) 2, 109.
    摘要:Banert, K., Science of Synthesis Knowledge Updates, (2015) 2, 286.
    摘要:Tius, M. A., Science of Synthesis Knowledge Updates, (2022) 1, 474.
    摘要:Phelps, A. M.; Alderson, J. M.; Schomaker, J. M., Science of Synthesis: Metal-Catalyzed Cyclization Reactions, (2016) 1, 342.
    摘要:Patil, N. T.; Tathe, A. G.; Bhoyare, V. W., Science of Synthesis, (2019) , 127.
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