CAS: 85329-59-5; (1R,2R,4A'S,5'R,7'S,9A'S)-5'-Hydroxy-3,3-Dimethyl-8'-Methylene-1',9'-Dioxohexahydro-1'H,3'H-Spiro[cyclohexane-1,4'-[7,9A]Methanocyclohepta[c]Pyran]-2-Carbaldehyde
该化合物是一种复杂的有机化合物,其特点是具有独特的结构特征,包括多环和功能组.它含有一种氢氧基化合物,有助于其在极地溶剂中的潜在再活性和溶解性.二氧和甲醚的功能表明它可能参与各种化学反应,例如氧化或凝聚.1,4a'S,5'R,7'R)配置表明原子的具体空间安排,能够影响化合物的生物活动以及与其他分子的相互作用.这种化合物可能表现出令人感兴趣的物理特性,使其完全了解其化学特性.
- 英文名称(1R,2R,4A'S,5'R,7'S,9A'S)-5'-Hydroxy-3,3-Dimethyl-8'-Methylene-1',9'-Dioxohexahydro-1'H,3'H-Spiro[cyclohexane-1,4'-[7,9A]Methanocyclohepta[c]Pyran]-2-Carbaldehyde
- 中文名称毛果香茶菜醛 A
- IUPAC名称(1R,2R,4a'S,5'R,7'S,9a'S)-5'-hydroxy-3,3-dimethyl-8'-methylene-1',9'-dioxohexahydro-1'H,3'H-spiro[cyclohexane-1,4'-[7,9a]methanocyclohepta[c]pyran]-2-carbaldehyde
- 其它别名Trichorabdal A; (1S,2R,4'Aβ,7'R,9'As)-4'A,5',6',7',8',9'-Hexahydro-5'α-Hydroxy-3,3-Dimethyl-8'-Methylene-1',9'-Dioxospiro[cyclohexane-1,4'(3'H)-[1H-7,9A]-Methanocyclohepta[c]Pyran]-2α-Carbaldehyde; Camellia Aldehyde A; Spiro[cyclohexane-1,4'(3'H)-[1H-7,9A]Methanocyclohepta[c]Pyran]-2-Carboxaldehyde,Hexahydro-5'-Hydroxy-3,3-Dimethyl-8'-Methylene-1',9'-Dioxo-,(1R,2R,4'As,5'R,7'S,9'As)-
- CAS编号85329-59-5
- MFCD编号:MFCD20260646
- 分子式:C20H26O5分子量:346.42
- 产品CID: 1848936
- 产品分类天然产物 → 萜类
MSDS等安全信息
上下游产品
(2'R,4S,4Ar,5R,7S,8Ar)-2'-[[tert-Butyl(Dimethyl)Silyl]Oxymethyl]-5-(Methoxymethoxy)-3',3'-Dimethyl-7-Prop-2-Enylspiro[4A,5,6,7,8,8A-Hexahydro-3H-Isochromene-4,1'-Cyclohexane]-1-One 1448616-45-2合成工艺路线路线简述
- 合成目标产物 Trichorabdal A 主要起始原料 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
- (文献来源)合成步骤主要原料 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
📜(2'R,4S,4Ar,5R,7S,8Ar)-2'-[[tert-Butyl(Dimethyl)Silyl]Oxymethyl]-5-(Methoxymethoxy)-3',3'-Dimethyl-7-Prop-2-Enylspiro[4A,5,6,7,8,8A-Hexahydro-3H-Isochromene-4,1'-Cyclohexane]-1-One置于盐酸,Silver Tetrafluoroborate,2,2,6,6-四甲基哌啶氧化物,碘苯二乙酸,氧气,乙酸酐,双(三甲基硅烷基)氨基钾,臭氧,Palladium Dichloride体系中,用 四氢呋喃,1,4-二氧六环,二氯甲烷,水,二甲基亚砜,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 10.0H,反应生成 毛果香茶菜醛a
参考文献:A Unified Strategy For The Synthesis Of (−)-Maoecrystal Z,(−)-Trichorabdal A,And (−)-Longikaurin E
标题:A Unified Strategy For The Synthesis Of (−)-Maoecrystal Z,(−)-Trichorabdal A,And (−)-Longikaurin E
摘要:
DOI:10.1016/j.Tet.2014.03.071
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905399002-1,4-丁二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1016/s0031-9422(02)00073-0
摘要:Na Z, Xiang W, Niu XM, Mei SX, Lin ZW, Li CM, Sun HD. Diterpenoids from Isodon enanderianus. Phytochemistry. 2002 May;60(1):55–60. doi: 10.1016/s0031-9422(02)00073-0.
📝 需求与反馈
尽可能描述清楚需求与问题信息
