Alfa,Alfa-二甲基苄氯置于乙醚,氢溴酸体系中,化学反应生成 4-肉桂苯酚 参考文献:Highlights Of Drought Policy And Related Science In Australia And The U.S.A. 标题:Highlights Of Drought Policy And Related Science In Australia And The U.S.A. 摘要:Patterns Of Water Supply And Use In Australia And The U.S.A. Differ In Many Ways. This Results In Different Perceptions Concerning The Nature Of Drought And Policy Approaches To Its Management. This Paper Discusses The Differences And Similarities And Explores Lessons That Policy Makers In Both Countries Can Learn From One Another. A Key Difference Between The Two Countries Is That Whereas Drought Is Perceived In Australia Essentially In Terms Of Its Impact On Agriculture,In The U.S. Both Perceptions And Policy Are Also Heavily Influenced By The Impact Of Drought On Urban Communities. This Has Led To Different Policy Emphases. In 1992 Australia Established Its National Drought Policy; The U.S. Is Presently Considering The Adoption Of A National Drought Policy. These Policies Highlight Drought Being Accepted As Part Of Natural Climate Variability,Rather Than As A Natural Disaster. They Also Emphasize The Protection Of The Natural Resource Base. DOI:10.1080/02508060108686927
专利号:US-7335797-B2 优先权日:2002-03-14 标 题 :Process for the synthesis of cumene hydroperoxide 发明人:CODIGNOLA FRANCO 权利人:EUROTECHNICA DEV & LICENSING S 摘要:This invention refers to a process for the synthesis of cumene hydroperoxide and to the product thus obtained. n More in particular, this invention refers to a process for the production of cumene hydroperoxide by oxidating cumene with oxygen, where this process is run in the presence of a basic medium insoluble in the reaction environment, and such as not to release inorganic cations to the reaction environment. Such a basic medium is preferably a pyridinic resin. n The cumene hydroperoxide thus obtained, characterized by the fact of being free of inorganic cations, is a further object of the invention.
专利号:US-2009043069-A1 优先权日:2007-08-06 标 题 :Activated esters for synthesis of sulfonated telechelic polycarbonates 发明人:BRUNELLE DANIEL J; COLONNA MARTINO; FIORINI MAURIZIO; BERTI CORRADO; BINASSI ENRICO 权利人:GEN ELECTRIC 摘要:A process of making a sulfonated telechelic polycarbonate is described. A dihydroxy compound, a carbonate ester, and an activated ester of a sulfobenzoic acid salt are reacted together. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.
专利号:US-6096853-A 优先权日:1998-12-21 标 题 :Synthesis of phenolic monomers containing imide or diimide moieties and high heat carbonate polymers prepared therefrom 发明人:AMERIK VALENTINA; HOEKS THEODORUS L; LIKIBI PARFAIT JEAN MARIE; NELSON MARK 权利人:GEN ELECTRIC 摘要:A process has been surprisingly discovered that can produce a high heat carbonate polymer (i.e., one with a Tg greater that 150° C.), without the drawbacks encountered in attempts to produce a high heat carbonate polymer. The process of the instant invention comprises the steps of: n (1) reacting an aromatic amine with a dihydric phenol to prepare an aminophenol; n (2) reacting an anhydride or dianhydride with the aminophenol to prepare a phenolic precursor; and n (3) reacting the phenolic precursor with a carbonate precursor to prepare a high heat carbonate polymer.
专利号:US-5973183-A 优先权日:1998-08-14 标 题 :Phosphine ligand promoted synthesis of tetraaryloxyalkane 发明人:HAITKO DEBORAH ANN; GRADE MARSHA MOTTEL; LONGLEY KATHRYN LYNN; COLBORN ROBERT EDGAR 权利人:GEN ELECTRIC 摘要:Addition of phosphine ligands can produce high yields of tetraphenoxymethane, TPM, and diphenylcarbonate, DPC, in short reaction times and improved reaction rates by a copper-induced condensation of phenol and carbon disulfide, CS 2 . Either aromatic or aliphatic substituted phosphine ligands can be employed. The copper(I) oxide utilization is significantly improved in reactions containing phosphine ligands, such that yields exceeding 100% tetraphenoxymethane are observed. Some of the sulfur-containing byproduct is transferred to the phosphine in the form of phosphine sulfide.
专利号:US-5214118-A 优先权日:1990-10-05 标 题:Process for synthesis of polyestercarbonate-siloxane copolymers 发明人:HAWKINS CHRISTOPHER M; ROSENQUIST NILES R 权利人:GEN ELECTRIC 摘要:A process for synthesizing polyestercarbonate-siloxane copolymers which have a smaller concentration of low molecular weight species and greater thermal stability has been described. Essentially the process includes adding the comonomer, diacid chloride siloxane, after approximately 1/3 of the phosgene has been added, in a conventional interfacial copolymerization, (as opposed to addition at the beginning of the polymerization).
专利号:US-6482977-B1 优先权日:2000-07-28 标 题:Melt process for the synthesis of diaryl esters of aliphatic diacids 发明人:WHITNEY JOHN MORGAN; FABER REIN MOLLERUS; BOVEN GEERT; LENS JAN-PLEUN 权利人:GEN ELECTRIC 摘要:This invention relates to a method for preparing diaryl esters, comprising the step of reacting a mixture comprising diaryl carbonate and a dicarboxylic acid, wherein 2.005 to 2.2 molar equivalents of diaryl carbonate per molar equivalent of dicarboxylic acid are provided.
[参考文献]: Chiha M, Et Al. Sonolytic Degradation Of Endocrine Disrupting Chemical 4-Cumylphenol In Water. Ultrason Sonochem. 2011 Sep;18(5):943-50. [参考文献]: Ramskov Tetzlaff Cn, Svingen T, Et Al. Bisphenols B, E, F, And S And 4-Cumylphenol Induce Lipid Accumulation In Mouse Adipocytes Similarly To Bisphenol A. Environ Toxicol. 2020 May;35(5):543-552. [参考文献]: Yue W, Et Al. Biodegradation Of Bisphenol-A Polycarbonate Plastic By Pseudoxanthomonas Sp. Strain Nyz600. J Hazard Mater. 2021 Aug 15;416:125775. [参考文献]: Bin Huang, Et Al. Occurrence, Removal, And Fate Of Progestogens, Androgens, Estrogens, And Phenols In Six Sewage Treatment Plants Around Dianchi Lake In China. Environ Sci Pollut Res Int. 2014 Nov;21(22):12898-908. [参考文献]: María Cordero-Vaca, Et Al. Automated Direct-Immersion Solid-Phase Microextraction Using Crosslinked Polymeric Ionic Liquid Sorbent Coatings For The Determination Of Water Pollutants By Gas Chromatography. Anal Bioanal Chem. 2015 Jun;407(16):4615-27.
合成参考文献
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