CAS: 2584-47-6; 1,4-Dimethylquinolin-2(1H)-One

相似化合物

15112-98-8 606-43-9 56062-93-2

上下游产品

CAS号201230-82-2 carbon monoxide | CAS号7117-17-1 N-methyl-2-(1-m... | CAS号607-66-9 4-甲基喹诺酮 | CAS号74-88-4 碘甲烷 | CAS号141-97-9 乙酰乙酸乙酯 | CAS号100-61-8 N-甲基苯胺 | CAS号937184-70-8 2-[(4-methoxyph... | CAS号2216-51-5 (-)-薄荷醇 | CAS号333-27-7 三氟甲烷磺酸甲酯 | CAS号98-85-1 苏合香醇 | CAS号2584-46-5 2(1H)-Quinoline... | CAS号15112-98-8 1-甲基-2-氧代-1,2-二... | CAS号62542-44-3 1-甲基-2-氧代-1,2-二...

📜2-甲氧基-4-甲基喹啉 600.0 °C,1.33 Pa 条件下,反应生成1,4-二甲基喹啉酮
参考文献:2-烷氧基吡啶热诱导重排为 N-烷基吡啶酮
标题:2-烷氧基吡啶热诱导重排为 N-烷基吡啶酮
摘要:2-甲氧基吡啶的类似物在快速真空热解 (Fvp) 条件下重排为 N-甲基吡啶酮.乙氧基衍生物经历竞争性乙基迁移和乙烯消除.4-甲氧基吡啶的类似物在 Fvp 条件下不会发生重排,但在二氧化硅上可能会发生去甲基化.重排的容易程度在一定程度上遵循烷氧基杂环的碱性.气相重排与凝聚相热解形成对比,计算支持前者的四中心过渡态.重排允许对来自 2,4-二氯喹啉与吡咯烷反应的两种产物进行结构分配.
Doi:10.1071/ch03044

专利信息

专利号:US-11286240-B2
优先权日:2017-03-10
标 题:Catalyst bound alpha radical and synthesis of OXO compounds using the same
发明人：MAITY PRADIP; MOTALEB ABDUL; BERA ASISH
权利人:COUNCIL SCIENT IND RES
摘要:The present invention discloses in situ generated catalyst bound alpha radical compound represented by formula (I) or (II) and a single pot process for the preparation of oxo compounds by using in situ generated catalyst bound alpha radical compound of formula (I) or (II).

专利号:US-7960553-B1
优先权日:2006-10-02
标 题 :Reagent for synthesis of para-methoxbenzyl (PMB) ethers and associated methods
发明人：DUDLEY GREGORY B
权利人:UNIV FLORIDA STATE RES FOUND
摘要:A newly synthesized compound designated lepidine ether 2-(4-Methoxybenzyloxy)-4-methylquinoline reacts with methyl triflate in the presence of alcohols to generate a neutral organic salt that transfers the para-methoxybenzyl (PMB) protecting group onto alcohols in high yield and under mild conditions.

专利号:US-2021147364-A1
优先权日:2017-03-10
标 题:A catalyst bound alpha radical and synthesis of oxo compounds using the same