专利号:US-7557099-B2 优先权日:2004-03-01 标题 :Pyrrolobenzodiazepines as key intermediates in the synthesis of dimeric cytotoxic pyrrolobenzodiazepines 发明人:HOWARD PHILIP WILSON; KANG GYOUNG-DONG 权利人:SPIROGEN LTD 摘要:Compounds and a method of synthesis of compounds of formula (Ia) or (Ib): and salts, solvates, and chemically protected forms thereof, wherein the dotted lines indicate the optional presence of a double bond between C1 and C2 or C2 and C3; R 2 and R 3 are independently selected from —H, â•?O, â•?CH 2 , —CN, —R, OR, halo, â•?CH—R, O—SO 2 —R, CO 2 R and COR; R 10 is a carbamate-based nitrogen protecting group; and R 11 is an oxygen protecting group.
专利号:US-9783634-B2 优先权日:2012-02-15 标题 :Synthesis of photovoltaic conjugated polymers 发明人:WANG SHUANGXI; SHI CHENJUN; CHEN RUBY; ZHANG JUNLIAN; WANG WEI; WU YUE; HUANG HUI; PALKAR AMIT; HE TING 权利人:PHILLIPS 66 CO; SOLARMER ENERGY INC 摘要:A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.
专利号:US-10236457-B2 优先权日:2016-06-29 标题 :Synthesis of porphyrin materials for highly efficient organic photovoltaics 发明人:ZHU XUNJIN; CHEN SONG; WONG WAI YEUNG; WONG WAI KWOK 权利人:UNIV HONG KONG BAPTIST UNIV 摘要:The present disclosure relates to porphyrin small molecules that can be represented by, e.g., a compound of Formula IV designed and synthesized for bulk heterojunction (BHJ) organic solar cells (OSCs). Provided are synthesized materials with strong and ordered self-assembly property, leading to form bi-continuous, interpenetrating networks which are required for efficient charge separation and transport in organic solar cells. The power conversion efficiency (PCE) of the solar cells devices based on the embodiments of the present disclosure have the highest PCE among the solution-processed BHJ solar cell based on porphyrin small molecules to date.
专利号:US-10787537-B2 优先权日:2018-01-29 标 题:Synthesis of polymers for organic photovoltaics 发明人:BULLOCK JOE; WORFOLK BRIAN; EARMME TAESHIK; PAN HUALONG; WOODY KATHY 权利人:PHILLIPS 66 CO 摘要:A method of coupling n nand 5,5-Y-3,3′-difluoro-2,2′-bithiophene to producen n n n n n n n n n n n n wherein X can be any known compound capable of coupling with the Y-difluorothiophene and Y is selected from the group consisting of Br, a stannyl group, a boronic ester and a H.
专利号:US-9595676-B2 优先权日:2013-08-27 标 题:Synthesis of water soluble doped conjugated polyelectrolytes for applications in organic electronics 发明人:BAZAN GUILLERMO C; MAI CHENG-KANG 权利人:UNIV CALIFORNIA 摘要:A method of fabricating a composition of matter, including fabricating one or more conjugated polyelectrolytes each comprising a donor-acceptor copolymer backbone and one or more anionic side groups, wherein the one or more conjugated polyelectrolytes are self doped. The doped conjugated polyelectrolytes can be used in a hole transport layer in a solar cell.
专利号:US-9735365-B2 优先权日:2014-07-21 标题:Low band gap polymer compound, synthesis of thereof, and organic photovoltaic cell containing the same 发明人:KIM BONG SOO; LEE HYO SANG; KIM HONG GON; KO MIN JAE; LEE DOH-KWON; KIM JIN YOUNG; SON HAE JUNG 权利人:KOREA INST SCI & TECH 摘要:The present disclosure relates to a novel polymer compound and a method for preparing the same. More particularly, the present disclosure relates to a novel conductive low band gap electron donor polymer compound having high photon absorptivity and improved hole mobility, a method for preparing the same and an organic photovoltaic cell containing the same. Since the conductive polymer compound as a low band gap electron donor exhibits high photon absorptivity and superior hole mobility, it can be usefully used as a material for an organic optoelectronic device such as an organic photodiode (OPD), an organic thin-film transistor (OTFT), an organic light-emitting diode (OLED), an organic photovoltaic cell, etc. as well as in the development of a n-type material.
[参考文献]: Jiyun Song, Et Al. Nanostructured Electron-Selective Interlayer For Efficient Inverted Organic Solar Cells. Acs Appl Mater Interfaces. 2015 Aug 26;7(33):18460-6. [参考文献]: Qian Liu, Et Al. 9-Arylidene-9H-Fluorene-Containing Polymers For High Efficiency Polymer Solar Cells. Acs Appl Mater Interfaces. 2014 Feb 12;6(3):1601-7. [参考文献]: Xing Fan, Et Al. 1,8-Diiodooctane As The Processing Additive To Improve The Efficiency Of P3Ht:Pc61Bm Solar Cells. J Nanosci Nanotechnol. 2014 May;14(5):3592-6.
合成参考文献
摘要:Bao, Z.; Wang, J., Science of Synthesis: Knowledge Updates, (2023) 2, 34. 参考文献:10.1038/srep05071 摘要:Zhang L, Xing X, Zheng L, Chen Z, Xiao L, Qu B, Gong Q. Vertical phase separation in bulk heterojunction solar cells formed by in situ polymerization of fulleride. Scientific Reports. 2014 May 27;4(1):5071. doi: 10.1038/srep05071. 参考文献:10.1038/ncomms9547 摘要:Kim T, Kim J, Kang TE, Lee C, Kang H, Shin M, Wang C, Ma B, Jeong U, Kim T, Kim BJ. Flexible, highly efficient all-polymer solar cells. Nature Communications. 2015 Oct 09;6(1):8547. doi: 10.1038/ncomms9547.