专利号:US-8933181-B2 优先权日:2006-10-06 标题:Branched polymers and methods for their synthesis and use 发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA 权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP 摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.
专利号:US-7829654-B2 优先权日:2004-05-11 标 题 :Method for producing elastomeric copolyesters 发明人:KAEMPF RUDOLF 权利人:LURGI ZIMMER GMBH 摘要:A process for continuous or discontinuous synthesis of elastomeric copolyesters from polybutylene terephthalate (PBT) and polyoxytetramethylene glycol is described in which the tetrahydrofuran (THF) obtained as a byproduct in synthesis of polybutylene terephthalate from 1,4-butanediol is rectified and then reacted by ring-opening polymerization to form polyoxytetramethylene glycol which condenses with the free or esterified carboxyl groups of PBT to form the copolyester, whereby chain termination and catalyst deactivation are accomplished by adding 1,4-butanediol without separating the catalyst.
专利号:US-11767388-B1 优先权日:2019-09-18 标 题 :Silicon-functionalized rubber 发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING 权利人:GOODYEAR TIRE & RUBBER 摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.
专利号:CN-1796434-A 优先权日:2004-12-23 标题 :A kind of catalyst system and its application for the synthesis of degradable polyester
专利号:CN-101704943-A 优先权日:2009-11-12 标 题:Rare earth catalysts for synthesis of polyesters and linear functionalized polyesters by condensation polymerization and their applications
参考文献:10.1134/s1560090424601080 摘要:Saliha Loughmari, Visseaux M, El Bouadili A. The Polymerization of β-Ocimene by Using the Borohydrido–Neodymium as Pre-catalyst. Polym. Sci. Ser. B. 2024 Jun;66(3):315–20. doi: 10.1134/s1560090424601080.