CAS: 930-29-0; 1-Chloro-1-Cyclopentene

• 英文名称1-Chloro-1-Cyclopentene
• 中文名称1-氯-1-环戊烯
• IUPAC名称1-chlorocyclopentene
• CAS编号930-29-0
• MFCD编号:MFCD00010247
• EINECS号:627-005-6
• 分子式:C5H7Cl
• 分子量:102.56
• 产品CID: 1969122
• 产品分类有机原料→分子砌块→脂肪环类化合物→环戊烷类化合物

• 相似结构搜索
• InChIKey: UJUIJZWQFDQKHO-UHFFFAOYSA-N
• InChI=1S/C5H7Cl/c6-5-3-1-2-4-5/h3H,1-2,4H2…
• 计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数0.0

相似化合物

物理性质

• 沸点113-115 °C at 760 mmHg
• 闪点49 °F
• 密度1.035 g/mL at 25 °C (文献)
• PSA:0.0
• LogP:2.293
• 折射率n 20/D 1.4651(文献)
• 蒸汽压22.7 mmHg at 25 °C
• 储存条件2-8°C

MSDS等安全信息

• GHS象形图
• GHS符号GHS02 & GHS07;
  注释: Flame & Exclamation mark
• 危险类别易燃液体 类别2
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Danger(危险)
• 危险描述H225 |高度易燃液体和蒸气.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P210-P233-P240-P241
• 危险等级3.2
• UN编号UN 1993 3/PG 2
• 危险品标志F,Xi
• 包装等级III
• 安全声明16-26-36/37/39
• 危险类别码11-36/37/38
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 1-Chloro-1-Cyclopentene 主要起始原料 Cyclopentene, 1-Bromo-2-Chloro-
• 27784-30-1 = 930-29-0
  反应条件:1.1 Solvents: Dichloromethane
  标题:Photochemistry Of Alkyl Halides. 10. Vinyl Halides And Vinylidene Dihalides
  作者:Kropp,Paul J.; Mcneely,Steven A.; Davis,Robert Drummond
  参考文献:Journal Of The American Chemical Society 日期:1983 卷标:105(23) 页码:6907-15]
  
  = 930-29-0 [标题:Reaction Conditions
  标题:Photochemistry Of Alkyl Halides. 3. Generation Of Vinyl Cations
  作者:Mcneely,Steven A.; Kropp,Paul J.
  参考文献:Journal Of The American Chemical Society 日期:1976 卷标:98(14) 页码:4319-20]
  
  = 930-29-0 [标题:Reaction Conditions
  标题:Cleavage Of Spiran Ether Bonds By Boron Halides
  作者:Cabiddu,Salvatore; Maccioni,Antonio; Mura,Luigi; Secci,Mario
  参考文献:Rendiconti Del Seminario Della Facolta Di Scienze Dell'Universita Di Cagliari 日期:1975 卷标:45(3-4) 页码:113-16]
  
  = 930-29-0 [标题:Reaction Conditions
  标题:Conformation Of Nonaromatic Ring Compounds. Xli. Dipole Moments And Nuclear Magnetic Resonance Spectra Of 1,1,2-Trihalocyclohexanes And-Cyclopentanes
  作者:Buys,H. R.; Altona,Cornelis; Havinga,E.
  参考文献:Recueil Des Travaux Chimiques Des Pays-Bas 日期:1967 卷标:86(11) 页码:1007-17]
  
  120-92-3 = 930-29-0 + 39547-03-0
  反应条件:1.1 Reagents: Triphenylphosphine
  标题:Triphenylphosphine-Carbon Tetrachloride
  作者:Taschner,Michael J.
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]
  
  1204206-13-2 + 14874-70-5 = 930-29-0 + 1204206-16-5 + 402-43-7 + 27415-42-5
  反应条件:1.1 Solvents: 1,2-Dichloroethane; 14 D,20 °C
  标题:Facile Generation Of A Strained Cyclic Vinyl Cation By Thermal Solvolysis Of Cyclopent-1-Enyl-λ3-Bromanes
  作者:Miyamoto,Kazunori; Shiro,Motoo; Ochiai,Masahito
  参考文献:Angewandte Chemie 日期:2009 卷标:48(47) 页码:8931-8934]
  
  120-92-3 = 930-29-0
  反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: Heptane; 2 H,70 °C; 0.5 H,70 °C; 70 °C -> 0 °C1.2 Reagents: Sodium Hydroxide Solvents: Water
  标题:Synthesis Of Cycloalkenyl-1-Boronic Acid Pinacol Ester
  参考文献:China]
  
  120-92-3 = 930-29-0
  反应条件:1.1 Reagents: Phosphorus Pentachloride Solvents: Heptane; 2 H,70 - 74 °C; 0.5 H,70 - 74 °C; 74 °C -> 0 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; 1 H,0 °C
  标题:Method For Manufacturing Cyclopentene/cyclohexene-1-Pinacol Borate
  参考文献:China]
  
  31038-06-9 = 930-29-0
  反应条件:1.1 Reagents: Zinc Solvents: 1,4-Dioxane
  标题:Polymethylene Cycles. Xxxvii. Transformations Of Polyhalo-Substituted Cyclopentanes
  作者:Domnin,N.A.; Obeshchalova,N. V.; Kolinskii,R. Ch.
  参考文献:Zhurnal Obshchei Khimii 日期:1961 卷标:31 页码:2768-73]
  
  27784-29-8 = 930-29-0
  反应条件:1.1 Reagents: Sodium Tert-Butoxide Solvents: Tert-Butanol
  标题:Base-Induced Reactions Of Methylenecyclobutane Derivatives
  作者:Erickson,Karen L.; Markstein,Judith; Kim,Kyongtae
  参考文献:Journal Of Organic Chemistry 日期:1971 卷标:36(8) 页码:1024-30]
  
  1427188-61-1 = 930-29-0
  反应条件:1.1 Reagents: Phosphorus Pentachloride Solvents: Diethyl Ether; 0 °C -> Rt; 3 D,Reflux
  标题:The Chemistry Of A Non-Interacting Vicinal Frustrated Phosphane/borane Lewis Pair
  作者:Elmer,Lisa-Maria; Kehr,Gerald; Daniliuc,Constantin G.; Siedow,Melanie; Eckert,Hellmut; Et Al
  参考文献:Chemistry - A European Journal 日期:2017 卷标:23(25) 页码:6056-6068]
  
  120-92-3 = 930-29-0
  反应条件:1.1 Reagents: Phosphorus Pentachloride Solvents: Toluene
  标题:A Photochromic Prototype Based On Difurylperhydrocyclopentene With Remarkable Photoswitching Behavior And In Vivo Application
  作者:Wang,Shangshang; Zhou,Yunyun; Zhu,Liangliang; Zhang,Junji; Zou,Qi; Et Al
  参考文献:Chemical Communications (Cambridge 日期:2017 卷标:53(69) 页码:9570-9573]
  
  37722-39-7 = 930-29-0 [标题:Reaction Conditions
  标题:Comparison Of Syn Dehydrohalogenations From Trans-1-Bromo-2-Chlorocycloalkanes Promoted By Complex Base And By Potassium Tert-Butoxide
  作者:Croft,Alan P.; Bartsch,Richard A.
  参考文献:Tetrahedron Letters 日期:1983 卷标:24(27) 页码:2737-40]
  
  = 930-29-0 [标题:Reaction Conditions
  标题:Reaction Of Diazonium Salts With Transition Metals. I. Arylation Of Olefins With Arenediazonium Salts Catalyzed By Zero Valent Palladium
  作者:Kikukawa,Kiyoshi; Matsuda,Tsutomu
  参考文献:Chemistry Letters 日期:1977 卷标:(2) 页码:159-62]
  
  120-92-3 = 930-29-0 [标题:Reaction Conditions
  标题:Molecular Rearrangement. Vi. Syntheses And Oxotropic Rearrangements In The Cyclopentenyl Series
  作者:Braude,E. A.; Forbes,W. F.
  参考文献:Journal Of The Chemical Society 日期:1951 卷标:1755 页码:1755-61]
  
  = 930-29-0 [标题:Reaction Conditions
  标题:Comparison Of β-Chloro-Activated,Syn And Anti Dehydrochlorinations Induced By Complex Base
  作者:Croft,Alan P.; Bartsch,Richard A.
  参考文献:Journal Of Organic Chemistry 日期:1994 卷标:59(7) 页码:1930-2]
  
  = 930-29-0 [标题:Reaction Conditions
  标题:Nickel(0)-Catalyzed Cross-Coupling Reactions Of Tricyclo[4.1.0.02,7]Hept-1-Ylmagnesium Bromide And Related Grignard Reagents With Aryl,Vinyl,And Alkynyl Halides
  作者:Kottirsch,Georg; Szeimies,Guenter
  参考文献:Chemische Berichte 日期:1990 卷标:123(7) 页码:1495-505]
  
  = 930-29-0 [标题:Reaction Conditions
  标题:Hydroboration. 57. Hydroboration With 9-Borabicyclo[3.3.1]Nonane Of Alkenes Containing Representative Functional Groups
  作者:Brown,Herbert C.; Chen,Jackson
  参考文献:Journal Of Organic Chemistry 日期:1981 卷标:46(20) 页码:3978-88]
  
  = 930-29-0 [标题:Reaction Conditions
  标题:Intermolecular Additions Of Cyclobutylchlorocarbene
  作者:Moss,Robert A.; Fantina,Mary E.; Munjal,Ramesh C.
  参考文献:Tetrahedron Letters 日期:1979 卷标:(15) 页码:1277-80]
  
  71690-88-5 = 930-29-0 + 27784-29-8
  反应条件:1.1 Solvents: Chloroform-D
  标题:Competitive Kinetics Of 1,2-Carbon And Hydride Shifts In Cyclobutylchlorocarbene
  作者:Moss,Robert A.; Ho,Guo Jie
  参考文献:Tetrahedron Letters 日期:1990 卷标:31(9) 页码:1225-8

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
  2903210000-氯乙烯
  2903110000-一氯甲烷及氯乙烷
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
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