CAS: 5470-80-4; Isoquinoline-3-Carbaldehyde

相似化合物

203626-75-9 27104-73-0 50458-79-2

上下游产品

3-methylisoquinoline methyl isoquinoline-3-carboxylate 3-Hydroxymethylisoquinoline ethyl isoquinoline-3-carboxylate c-[3]isoquinolyl-acrylonitrile2-(3,4-dimethoxy-phenyl)-3c-[3]isoquinolyl-acrylonitrile 3-Hydroxymethylisoquinoline methyl (2Z)-2-{[(benzyloxy)carbonyl]amino}-3-(isoquinolin-3-yl)prop-2-enoate phenyl (2R,3R)-2-benzyloxy-3-hydroxy-3-(2-oxyisoquinolin-3-yl)propionate

📜Ethyl 2-Azido-3-[(2-Formyl)Phenyl]Prop-2-Enoate置于sodium Tetrahydroborate,草酰氯,二甲基亚砜,N,N-二异丙基乙胺,Calcium Chloride,三甲氧基磷体系中,用 四氢呋喃,乙醇,二氯甲烷,苯 作为反应溶剂,化学反应 0.75H,反应生成 异喹啉-3-甲醛
参考文献:Homochiral Isoquinolines By Lipase-Catalysed Resolution And Their Diastereoselective Functionalisation
标题:Homochiral Isoquinolines By Lipase-Catalysed Resolution And Their Diastereoselective Functionalisation
摘要:Kinetic Resolution Of Racemic Isoquinoline Alcohols And Acetates Has Been Successfully Accomplished Using Lipases As Chiral Catalysts,The Diastereoselective Functionalisation Of The Isoquinoline Moiety Through The Addition Of C-Nucleophiles To O-Protected Alcohol 9A In The Presence Of Phenyl Chloroformate Has Been Carried Out And Dihydroquinolyl Alcohol Derivatives With High Diastereomeric Excess Have Been Prepared. (C) 2001 Elsevier Science Ltd. All Rights Reserved.
DOI:10.1016/s0957-4166(01)00178-1