CAS: 34054-55-2; Yttrium(Iii) Phosphate Hydrate

该化合物是一种无机化合物,其特点是由ytrium,磷和水分子组成,通常看起来像白色或非白色固体,以其晶状结构著称,该化合物经常用于各种用途,包括陶瓷,磷,以及作为合成其他含有氧元素的材料的前体.Yttrium(III)磷酸盐水合物在正常条件下相对稳定,但在取暖时可能会脱水,失去水含量.该化合物一般在水中溶解,在大多数有机溶剂中表现出低溶性.该化合物可通过涉及亚特林盐和磷酸的降水方法合成.从安全角度讲,最好处理亚特林(III)磷酸盐,并小心处理,如同许多无机化合物一样,避免吸入或皮肤接触.

结构式图片

合成工艺路线路线简述

    📜磷酸,氯化钇置于hcl,Nh4Oh体系中,用 水 用作溶剂,化学反应生成水合磷酸钇
    参考文献:Mechanochemical Changes Of Weinschenkite-Type Rpo4.2H2O (R = Dy,Y,Er,Or Yb) By Grinding And Thermal Reactions Of The Ground Specimens
    标题:Mechanochemical Changes Of Weinschenkite-Type Rpo4.2H2O (R = Dy,Y,Er,Or Yb) By Grinding And Thermal Reactions Of The Ground Specimens
    摘要:It Is Reported That,On Mechanochemical Treatment,Weinschenkite‐type Rpo4.2H2O (R = Dy,Y,Or Er) Gradually Transforms Into Rhabdophane‐type Rpo4. Nh2O (N = 0.5 To 1) And Weinschenkite‐type Ybpo4.2H2O Into Xenotime‐type Ybpo4,At Room Temperature In Air. Rhabdophane‐type Ypo4.0.8H2O And Erpo4.0.9H2O Obtained By Grinding Weinschenkite‐type Rpo4.2H2O (R=y Or Er) Are New. The New Rhabdophane‐type Ypo4.0.8H2O And Erpo4.0.9H2O Gradually Transform To Xenotime‐type Ypo4 And Erpo4 When Heated Above 900oc (R = Y) And 700oc (R = Er) In Air.
    Doi:10.1111/j.1151-2916.1989.Tb06276.X

    专利信息


    专利号:US-8425871-B2
    优先权日:2006-06-05
    标 题 :Single phase yttrium phosphate having the xenotime crystal structure and method for its synthesis
    发明人:GRAY SANDRA LEE; WITHAM RICHARD DONALD
    权利人:GRAY SANDRA LEE; WITHAM RICHARD DONALD; CORNING INC
    摘要:Methods for producing substantially single phase yttrium phosphate which exhibits the xenotime crystal structure are disclosed. The methods can be practiced without the use of high temperatures (e.g., the methods can be practiced at temperatures less than 1000° C.). The resulting yttrium phosphate can be in the form of particles which comprise interwoven strands of crystals of yttrium phosphate and/or nanoparticles prepared from such particles.

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    主要参考文献

    参考标题:Self-Assembly Of Uniform Hexagonal Yttrium Phosphate Nanocrystals
    作者:Ziyang Huo,Chen Chen,Yadong Li
    摘要:We Report A Facile Chemical Route For The Synthesis Of Uniform Hexagonal Yttrium Phosphate Hydrate Nanocrystals And Their Assembly Into Close-Packed Regular Superstructures Through Noncovalent Interactions Of Long Chain Molecules Attached To The Surfaces Of Inorganic Nanocrystals.
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