CAS: 18202-10-3; Dodec-11-Yn-1-Ol

该化合物是长链烷醇,其特点是线性结构,具有终端氢氧基(-OH)组和碳碳三联结,该化合物属于脂肪酒精类,通常由分子式C12H22O代表.在室内温度下,它无色可粉黄黄色液体,由于水分碳链,在水中表现出低溶性,但在乙醇和乙醇等有机溶剂中可溶性. 烷功能组的存在具有独特的再活动性,允许各种化学变异,包括氧化和添加反应.11-Dodecyn-1-ol在有机合成中被使用,并可作为表面活性剂,乳化剂和其他化学化合物生产的中间体.此外,其特性使其对材料科学和功能化聚合物的开发具有兴趣.在处理时,应参考安全数据,因为如果浸入或吸入,可能会对健康造成风险.

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16900-60-0 871-91-0 10160-28-8

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    专利号:US-10202620-B2
    优先权日:2014-05-16
    标 题:Synthesis of olefinic alcohols via enzymatic terminal hydroxylation
    发明人:COELHO PEDRO; CHEN MIKE M Y; MEINHOLD PETER; CHO CATHERINE MEE-HIE; BUI VU; HEEL THOMAS
    权利人:PROVIVI INC
    摘要:In certain aspects, the present invention provides methods for producing terminally hydroxylated alkenes and alkynes by contacting an unsaturated or saturated hydrocarbon substrate with a hydroxylase enzyme. Exemplary terminal hydroxylases useful for carrying out the methods of the invention exhibit strong selectivity towards one terminal carbon of a hydrocarbon substrate and include, but are not limited to, non-heme diiron alkane monooxygenases, cytochromes P450 (e.g., cytochromes P450 of the CYP52 and CYP153 family), as well as long chain alkane hydroxylases. In some embodiments, the terminally hydroxylated alkene or alkyne is further converted to a terminal alkenal. In certain embodiments, terminally hydroxylated alkenes and alkynes are useful as insect pheromones which modify insect behavior. In other embodiments, terminally hydroxylated alkenes and alkynes are useful intermediates for producing pheromones via acetylation or oxidation of the alcohol moiety.

    专利号:US-4228093-A
    优先权日:1979-10-18
    标 题:(11Z,13Z)-11,13-Hexadecadiyn-1-ol and (11Z,13Z)-11,13-hexadecadien-1-ol and trimethylsilyl ethers thereof
    发明人:CARNEY ROBERT L; HENRICK CLIVE A
    权利人:ZOECON CORP
    摘要:Synthesis of an attractant (11Z,13Z)-11,13-hexadecadienal for the navel orangeworm Amyelois transitella, and intermediates therefor.

    专利号:US-2016108436-A1
    优先权日:2014-05-16
    标题:Synthesis of olefinic alcohols via enzymatic terminal hydroxylation

    专利号:WO-2015176020-A1
    优先权日:2014-05-16
    标题 :Synthesis of olefinic alcohols via enzymatic terminal hydroxylation

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    摘要:Heaney, H.; Christie, S., Science of Synthesis, (2004) 3, 448.
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