CAS: 1711-10-0; 3-Iodobenzoyl Chloride

该化合物是一种有机碘化合物,通常用作有机合成的多功能中间体,其主要功能组--反应性丙烷和碘替代体--在交叉反应(如铃木,松木,松木芝拉)和电解过程中可有效衍生,碘会促进通过卤素交换或金属催化变异进一步功能化,而乙基氯组则提供高抗核素(胺,酒精)以形成氨化物或酯的再活性,这一化合物在建立复杂的芳香框架的制药和材料科学研究中特别有用.在惰性条件下的稳定以及与普通有机溶剂的兼容性增强了其在多步骤合成物中的效用.

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CAS号618-51-9 间碘苯甲酸 | CAS号101-83-7 二环己胺 | CAS号58313-23-8 3-碘苯甲酸乙酯 | CAS号39115-94-1 3-碘苯甲酰肼 | CAS号395-11-9 4-FLUORO-3'-IOD... | CAS号696-41-3 3-碘苯甲醛 | CAS号68332-33-2 (3-碘苯甲酰基)乙酸乙酯 | CAS号64358-32-3 4-N-BUTYL-3'-IO... | CAS号107622-31-1 3-IODO-4'-METHY... | CAS号10388-19-9 间碘苯甲酰胺 | CAS号170282-53-8 3-碘-n-甲氧基-n-甲基苯甲酰胺 | CAS号15930-60-6 N,N-diethyl-3-i...

合成工艺路线路线简述

    📜3-碘苯甲酸置于草酰氯,N,N-二甲基甲酰胺体系中,用 二氯甲烷 用作溶剂,化学反应生成3-碘苯甲酰氯
    参考文献:轻度铑(III)催化的c h活化和丙二烯的分子间环化
    标题:轻度铑(III)催化的c h活化和丙二烯的分子间环化
    摘要:所有(烯)都很棒!在温和条件下,新型的rh Iii催化的与丙二烯的氧化偶联提供了带有环外双键的杂环.该反应具有低催化剂负载,高区域选择性和立体选择性以及出色的底物范围等特点.产品已衍生化,并进行了初步的力学研究.
    Doi:10.1002/anie.201201273

    海关参考信息

    专利信息


    专利号:US-6603070-B2
    优先权日:2000-07-21
    标题 :Convergent synthesis of multiporphyrin light-harvesting rods
    发明人:LINDSEY JONATHAN S; LOEWE ROBERT S
    权利人:UNIV NORTH CAROLINA STATE
    摘要:The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A 1 (A b+1 ) b , wherein b is at least 1, A 1 through A b+1 are covalently coupled rod segments, and each rod segment A 1 through A 1+b comprises a compound of the formula X 1 (X m+1 ) m wherein m is at least 1 and X 1 through X m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.

    专利号:US-9452425-B2
    优先权日:2002-09-26
    标 题 :Compositions containing ionic liquids and their uses, in particular in organic synthesis
    发明人:VAULTIER MICHEL; GMOUH SAID
    权利人:VAULTIER MICHEL; GMOUH SAID; CENTRE NAT RECH SCIENT; UNIV RENNES
    摘要:An ionic liquid is used as liquid matrix for organic synthesis in homogeneous phase on soluble support, the ionic liquid being presented in liquid or solid form at ambient temperature, of formula A 1 + X 1 − , A 1 + representing a cation, functional or non-functional, or a mixture of cations in which either none of the cations is functional or at least one of the cations is functional, and X 1 − an anion, functional or non-functional, or a mixture of anions in which either none of the anions is functional or at least one of the anions is functional.

    专利号:US-2003111108-A1
    优先权日:2000-07-21
    标题:Convergent synthesis of multiporphyrin light-harvesting rods

    专利号:WO-2015088565-A1
    优先权日:2013-12-13
    标题:P2x4 receptor modulating compounds and methods of use thereof
    发明人:NEWCOM JASON S; SPEAR KERRY L
    权利人:SUNOVION PHARMACEUTICALS INC
    摘要:Provided herein are P2X4 receptor modulating compounds, methods of their synthesis, pharmaceutical compositions comprising the compounds, and methods of their use. The compounds provided herein are useful for the treatment, prevention, and/or management of various disorders, including but not limited to, chronic pain, neuropathy, inflammatory diseases and central nervous system disorders.

    专利号:US-4252729-A
    优先权日:1978-05-12
    标 题 :Steroids and process for their manufacture
    发明人:ALIG LEO; FUERST ANDOR; MUELLER MARCEL; KERB ULRICH; WIECHERT RUDOLF
    权利人:HOFFMANN LA ROCHE
    摘要:The present disclosure is concerned with 9α-chloro-17-(m-iodobenzyloxy) steroids and a process for their manufacture. The subject compounds are useful as intermediates in the synthesis of pharmacologically-active substances and have themselves been found to exhibit pharmacological activity.

    专利号:WO-03019621-A2
    优先权日:2001-08-24
    标题:Convergent synthesis of multiporphyrin light-harvesting rods

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    合成参考文献


    摘要:Crousse, B., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 9.
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