CAS: 14812-59-0; 1,3,2-Dioxaphospholane, 2-Chloro-4,4,5,5-Tetramethyl-

该化合物是一种循环磷酸酯衍生物,广泛用作有机合成和磷酸反应的关键中间体,其僵硬的,受到严酷阻碍的结构能够增强稳定性,适合于在温和条件下的受控反应.该化合物在为高纯度和反应性至关重要的寡聚二氯胺酯合成而准备磷胺时特别宝贵.其氯代成分可以进一步功能化,使医药化学和材料科学中能够应用多种用途.四甲基替代模式有助于提高有机溶剂的溶性,便利实验室和工业环境中的处理.该剂有利于其在立体选择性转化中持续发挥作用.

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CAS号76-09-5 频哪醇 | CAS号16352-18-4 4,4,5,5-四甲基-1,3... | CAS号14812-61-4 4,4,5,5-tetrame... | CAS号14812-60-3 2-METHOXY-4,4,5... | CAS号72666-66-1 2-IS°CYANATO-4,... | CAS号38206-24-5 1,3,2-Dioxaphos...

合成工艺路线路线简述

    📜频哪醇置于吡啶,三氯化磷体系中,用 乙醚 用作溶剂,化学反应 4.0H,反应生成2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷
    参考文献:环氧大豆油酸甲酯衍生溶剂的化学表征和物理性质
    标题:环氧大豆油酸甲酯衍生溶剂的化学表征和物理性质
    摘要:环氧大豆油酸甲酯(ems)与醇,二氧化碳和丙酮的反应产生的液体具有溶剂性质,使其比大豆油酸甲酯更适合溶解极性物质.Ems中的amberlyst-15与醇的存在下的反应,包括甲醇,乙醇,ñ丁醇和2-甲氧基乙醇产生了一系列含有醚(-or)和醇(-oh)基团的溶剂.Ems与二氧化碳和丙酮的反应分别得到具有碳酸酯和酮官能团的产物.通过ms和NMR研究表征了由ems与meoh反应产生的产物ems(meoh)中存在的化合物的复杂混合物.除了由横跨环氧化物的meoh加成所产生的产物外,还有大量的环状四氢呋喃衍生物,它们是由亚油酸甲酯(18:2)与meoh的反应衍生而来的.所有溶剂的特征在于高沸点和低蒸气压.它们的粘度高于大豆酸甲酯的粘度.尤其值得注意的是它们的贝壳杉醇丁醇值很高,介于280至852之间,所有这些都比大豆油甲酯的(57)高得多.如此高的kb值表明这些溶剂具有非常有利的增溶剂性能,这可由em
    Doi:10.1007/s11746-015-2607-6

    海关参考信息

    专利信息


    专利号:US-12291489-B2
    优先权日:2016-07-01
    标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition
    发明人:BISWAS PRATIM; RALIYA RAMESH
    权利人:BISWAS PRATIM; RALIYA RAMESH; WASHINGTON UNIVERSITY ST LOUIS
    摘要:The present disclosure is related to the development of improved fertilizer for precision and sustainable agriculture. A method was developed wherein efficient NPK nanocomposite for plant nutrition was synthesized in a single step using aerosol science and technology concepts. Further a formulation was prepared by addition of ZnO, TiO 2 and other nanoparticles to the NPK nanocomposite. Also, an aerosol based foliar application technique was developed for the precise delivery of nanoparticles to the plants.

    专利号:US-2023340200-A1
    优先权日:2020-06-04
    标 题:Non-isocyanate polyurethanes from bio-based polyols
    发明人:PILLA SRIKANTH; STERNBERG JAMES SCOTT
    权利人:UNIV CLEMSON RES FOUNDATION
    摘要:Bio-based polymer precursors and non-isocyanate polyurethanes (NIPU) and non-isocyanate polyurethane foams (NIPUF) that can be formed from the precursors, as well as methods for the synthesis of the precursors and the polyurethane products are described. The bio-based polymer precursors are formed through functionalization of a bio-based polyol, e.g., lignin, with cyclic carbonates. The bio-based polyol starting materials need not be pre-processed and can include Kraft lignin. NIPU/NIPUF can be synthesized through a ring opening curing reaction of cyclic carbonates of the bio-based polyol precursor with diamines. The carbonates and diamines can include non-toxic bio-based carbonates.

    专利号:US-2019202750-A1
    优先权日:2016-07-01
    标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition

    专利号:US-11453670-B2
    优先权日:2018-06-11
    标 题:Substituted heterocycle fused gamma-carbolines synthesis
    发明人:LI PENG; ZHANG QIANG
    权利人:INTRA CELLULAR THERAPIES INC
    摘要:The present invention provides improved methods for the preparation of substituted heterocycle fused gamma-carbolines, intermediates useful in producing them and methods for producing such intermediates and such heterocycle fused gamma-carbolines.

    专利号:CN-110831941-A
    优先权日:2018-06-11
    标 题 :Synthesis of substituted heterocycle fused gamma-carboline compound

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s002530000561
    摘要:Lund M, Ragauskas AJ. Enzymatic modification of kraft lignin through oxidative coupling with water-soluble phenols. Applied Microbiology and Biotechnology. 2001 Jun 01;55(6):699–703. doi: 10.1007/s002530000561.
    参考文献:10.1007/s12010-011-9284-1
    摘要:Zhang B, Yin X, Wu C, Qiu Z, Wang C, Huang Y, Ma L, Wu S. Structure and Pyrolysis Characteristics of Lignin Derived from Wood Powder Hydrolysis Residues. Applied Biochemistry and Biotechnology. 2011 May 21;168(1):37–46. doi: 10.1007/s12010-011-9284-1.
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