CAS: 112883-29-1; Fmoc-D-Tyr-Oh

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📜Fmoc-D-Tyr-Otbu置于水体系中,化学反应生成Fmoc-D-酪氨酸
参考文献:支持的用于连续流化学的催化活性超分子水凝胶.
标题:支持的用于连续流化学的催化活性超分子水凝胶.
摘要:受生物学启发,超分子化学的当前目标之一是控制分子自组装产生的新功能的出现.特别地,一些肽可以自组装并产生能够支撑水凝胶的异常催化活性的纤维网络.不幸的是,这些材料的机械脆性与工艺发展是不相容的,这将这一令人兴奋的领域传递给了学术界的好奇心.在这里,我们表明可以通过支持多孔材料壁上的酶促肽自组装来克服这一缺陷.我们应用此策略在开孔聚合物泡沫中生长了酯酶样催化活性超分子水凝胶(cash),填充了整个内部空间.我们支持的cash材料对灭活的酯具有很高的效率,并能实现外消旋物的动力学拆分.这种混合材料足够坚固,可用于连续流反应器,并且可重复使用且在数月内稳定.
Doi:10.1002/anie.201909424

专利信息

专利号:US-2024287106-A1
优先权日:2021-06-09
标题 :Method for Producing Fluorescent Probe Library Using Solid-Phase Extraction and Method of Measuring Enzyme Activity Using Same
发明人：KOMATSU TORU; URANO YASUTERU; SAKAMOTO SHINGO; WATANABE RIKIYA; KAGAMI YU
权利人:UNIV TOKYO; RIKEN
摘要:To provide a synthesis scheme capable of easily synthesizing various kinds of fluorescent probes. A method for preparing a compound represented by Formula (III) below, the method including steps (1) to (5).

专利号:US-7147856-B2
优先权日:1996-08-28
标题 :Stable radioiodine conjugates and methods of their synthesis
发明人：GOVINDAN SERENGULAM V
权利人:IMMUNOMEDICS INC
摘要:Methods are described for conjugating radioiodinated peptides or carbohydrate structures to proteins with improved yields and qualities of conjugates. In one method, specially designed radioiodinated bifunctional peptides containing nonmetabolizable amide bonds are coupled to antibodies. In a second method, radioiodinated nonmetabolizable bifunctional peptides, which also contain aminopolycarboxylates, are coupled to antibodies. In a third method, radioiodinated bifunctional aminopolycarboxylates are coupled to antibodies. In a fourth method, a hydrazide-appended antibody is coupled to a radioiodinated carbohydrate or a thiolated antibody is coupled to a hydrazide-appended and radioiodinated carbohydrate. In a fifth method a monoderivatized cyanuric chloride is used to conjugate thiolated antibody. Radioiodinated residualizing antibody conjugates made by these methods are particularly stable in vivo and are suitable for radioimmunodetection and radioimmunotherapy.

专利号:US-8338565-B2
优先权日:2008-08-20
标 题 :Macrocyclic compounds for inhibition of tumor necrosis factor alpha
发明人：LEE JINBO; BOND JULIAN F; TERRETT NICHOLAS; FAVALORO JR FRANK G; WANG DANIEL; BRIGGS TIMOTHY F; SEIGAL BENJAMIN ADAM; SUN WEI-CHUAN; HALE STEPHEN P
权利人:LEE JINBO; BOND JULIAN F; TERRETT NICHOLAS; FAVALORO JR FRANK G; WANG DANIEL; BRIGGS TIMOTHY F; SEIGAL BENJAMIN ADAM; SUN WEI-CHUAN; HALE STEPHEN P; ENSEMBLE THERAPEUTICS CORP
摘要:Disclosed herein are macrocyclic compounds and methods for their synthesis and use. In particular, macrocyclic compounds are disclosed that modulate the activity of tumor necrosis factor alpha and/or are useful in the treatment of medical conditions, such as, rheumatoid arthritis, psoriasis, and asthma.

专利号:US-6663866-B1
优先权日:1996-08-28
标题:Stable radioiodine conjugates and methods for their synthesis
发明人：GOVINDAN SERENGULAM V
权利人:IMMUNOMEDICS INC
摘要:Methods are described for conjugating radioiodinated peptides to non-metabolizable carbohydrates with improved yields and qualities of conjugates. Radioiodinated residualizing antibody conjugates comprising a carbohydrate-appended peptide are also provided. The instant radioiodinated residualizing antibody conjugates are particularly stable in vivo and are suitable for radioimmunodetection and radioimmunotherapy.

专利号:EP-0915710-B1
优先权日:1996-08-28
标 题:Stable radioiodine conjugates and methods for their synthesis
发明人：GOVINDAN SERENGULAM V; GRIFFITHS GARY L
权利人:IMMUNOMEDICS INC
摘要:Methods are described for conjugating radioiodinated peptides or carbohydrate structures to proteins with improved yields and qualities of conjugates. In one method, specially designed radioiodinated bifunctional peptides containing nonmetabolizable amide bonds are coupled to antibodies. In a second method, radioiodinated nonmetabolizable bifunctional peptides, which also contain aminopolycarboxylates, are coupled to antibodies. In a third method, radioiodinated bifunctional aminopolycarboxylates are coupled to antibodies. In a fourth method, a hydrazide-appended antibody is coupled to a radioiodinated carbohydrate, or a thiolated antibody is coupled to a hydrazide-appended and radioiodinated carbohydrate. In a fifth method, a monoderivatized cyanuric chloride is used to conjugate thiolated antibody. Radioiodinated residualizing antibody conjugates made by these methods are particularly stable in vivo and are suitable for radioimmunodetection and radioimmunotherapy.

专利号:US-2004022725-A1
优先权日:1996-08-28
标题:Stable radioiodine conjugates and methods of their synthesis