合成目标产物 Melamine 主要起始原料 Cyanamide And Guanidine, Cyano-, (E)- (9CI)
108-78-1 + 71-48-7 = 108-78-1 反应条件:1.1S:Etoh,24 H,Rt1.2R:Carbon,24 H,Rt 标题:Reusable Cobalt-Catalyzed Selective Transfer Hydrogenation Of Azoarenes And Nitroarenes 作者:By Dey,Sadhan Et Al 参考文献:Journal Of Organic Chemistry 日期:2023 卷标:88(14) 页码:10048-10057]
= 108-78-1 + 638-16-4 反应条件:1.160 Min,550°C 标题:Sulfur-Doped Graphitic-Carbon Nitride (S@g-C3N4) As Bi-Functional Catalysts For Hydrazine Sensing And Hydrogen Production Applications 作者:By Ahmad,Khursheed Et Al 参考文献:Synthetic Metals 日期:2022 卷标:288 页码:117100]
25014-41-9 + 143334-20-7 = 108-78-1 反应条件:1.1S:Dmf,2 H,50°C; Overnight 标题:Preparation Of Flexible Pan-C3N4-Zif-8 Photocatalytic Nanofibers And Visible Light Catalytic Properties 作者:By Li,Zhiang Et Al 参考文献:Optical Materials (Amsterdam 日期:2022 卷标:132 页码:112762]
= 108-78-1 反应条件:1.1R:Nh32.1 标题:Sustainable Industrial Ecology And Environmental Analysis: A Case Of Melamine Etherified Resin Fibres 作者:By Vujanovic,Annamaria Et Al 参考文献:Journal Of Cleaner Production 日期:2022 卷标:369 页码:133301]
108-78-1 + 3375-31-3 = 108-78-1 反应条件:1.1S:H2O,2 H,80°C 标题:"Doubly Orthogonal" Labeling Of Peptides And Proteins 作者:By Tessier,Romain Et Al 参考文献:Chem 日期:2019 卷标:5(8) 页码:2243-2263]
= 108-78-1 反应条件:1.1R:Nh32.1 标题:Achieving Absolute Sustainability Across Integrated Industrial Networks - A Case Study On The Ammonia Process 作者:By Samaroo,Nicholas Et Al 参考文献:Green Chemistry 日期:2020 卷标:22(19) 页码:6547-6559]
461-58-5 + 503-29-7 + 109-76-2 = 108-78-1 + 5807-14-7 反应条件:1.1160°C2.12 H,200°C 标题:Method For Synthesizing Bicyclic Guanidine 作者:By Cui,Zhaoshan Et Al 参考文献:Faming Zhuanli Shenqing 日期:From Faming Zhuanli Shenqing,112094273,18 Dec 2020 卷标:112094273 页码:18 Dec 2020]
75-13-8 + 57-13-6 = 108-78-1 反应条件:1.11.12.13.1 标题:Integration Of Nickel Complex As A Cocatalyst Onto In-Plane Benzene Ring-Incorporated Graphitic Carbon Nitride Nanosheets For Efficient Photocatalytic Hydrogen Evolution 作者:By Zhang,Yun-Xiao Et Al 参考文献:Chemical Engineering Journal (Amsterdam 日期:2020 卷标:381 页码:122635]
37330-39-5 + 108-78-1 = 108-78-1 + 37330-39-5 反应条件:1.1 1 - 1.5 H,60 °C; 60 °C -> 90 °C; 2 - 3 H,90 °C 标题:Synthesis And Fire Properties Of Rigid Polyurethane Foams Made From A Polyol Derived From Melamine And Cardanol 作者:Zhang,Meng; Zhang,Jinwen; Chen,Shuigen; Zhou,Yonghong 参考文献:Polymer Degradation And Stability 日期:2014 卷标:110 页码:27-34]
108-78-1 + 100-21-0 = 108-78-1 反应条件:1.1R:Fecl2,S:Dmf,2 H,Rt; 24 H,150°C 标题:Graphitic Carbon-Wrapped Iron Nanoparticles Derived From A Melamine-Modified Metal-Organic Framework As Efficient Friedel-Crafts Acylation Catalysts 作者:By Zhao,Chen Et Al 参考文献:Catalysis Today 日期:2022 卷标:402 页码:220-227]
25014-41-9 = 108-78-1 反应条件:1.1R:Et3N,4 H,85°C,Ph 10.51.2Ph 5.5 标题:Toughening Agent For Melamine Formaldehyde Resin: A New Method For Recycling Chrome Shavings 作者:By Xu,Weixing Et Al 参考文献:Polymer 日期:2022 卷标:253 页码:124979]
57-13-6 = 108-78-1 反应条件:1.12.1R:Nh3 标题:Benzenesulfonyl Chloride-Incorporated G-C3N4 For Photocatalytic Hydrogen Generation By Using The Hydrolysate Of Poly(Lactic Acid) As Sacrificial Reagent 作者:By Sun,De-Wen Et Al 参考文献:Applied Catalysis 日期:2021 卷标:628 页码:118397]
108-78-1 = 108-78-1 反应条件:1.1R:Rucl3,S:H2O,30 Min,80°C 标题:High-Efficiency Catalysis Of Ru-Based Catalysts Assisted By Triazine-Based Ligands Containing Different Heteroatoms (N,O,S) For Acetylene Hydrochlorination 作者:By Li,Jian Et Al 参考文献:Molecular Catalysis 日期:2022 卷标:519 页码:112142]
57-13-6 = 108-78-1 反应条件:1.1R:Fecl3,550°C 标题:Colorimetric Assay Using Mesoporous Fe-Doped Graphitic Carbon Nitride As A Peroxidase Mimetic For The Determination Of Hydrogen Peroxide And Glucose 作者:By Peng,Yage Et Al 参考文献:Acs Applied Bio Materials 日期:2020 卷标:3(1) 页码:59-67
氢氰酸置于pd-Mgo 氨体系中,400.0 °C,5.0 Mpa 条件下,以0.32%的收率获得三聚氰胺 参考文献:Process For The Preparation Of Melamine 标题:Process For The Preparation Of Melamine 摘要:该发明涉及一种制备三聚氰胺的方法,该方法至少包括以下步骤:A. 将氨和氰化氢分别或结合地加入含有至少一种11族元素催化剂的第一反应器中,该反应器保持在至少2巴的压力和300-500oc的温度下,空间速度在102至106 Ml/(G.Hr)之间,从而形成至少包含三聚氰胺的气态混合物(A),B. 可选地纯化混合物(A)产生含有三聚氰胺的混合物(B),C. 分离至少部分形成的三聚氰胺,从而形成反应混合物(C)和分离的三聚氰胺.该发明还涉及一种制备三聚氰胺的方法,该方法至少包括以下步骤:I. 将甲烷和氨加入预反应器,该预反应器保持在700至1500oc的温度下,从而形成至少含有氰化氢的气态混合物(I),Ii. 纯化混合物(I)从而形成至少含有氰化氢的混合物(II),A. 从混合物(II)中将氰化氢和氨分别或结合地加入含有催化剂的第一反应器,该反应器保持在至少2巴的压力和300-500oc的温度下,空间速度在102至106 Ml/(G.Hr)之间,从而形成至少包含三聚氰胺的气态混合物(A),B. 可选地纯化混合物(A)产生含有三聚氰胺的混合物(B),C. 分离至少部分形成的三聚氰胺,从而形成反应混合物(C)和分离的三聚氰胺.该发明还涉及通过这些方法获得的三聚氰胺.
专利信息
专利号:WO-2025015696-A1 优先权日:2023-07-17 标题:β-CYC-ASSISTED SYNTHESIS OF IN-V GROUP QUANTUM DOT, AND SYNTHESIS METHOD THEREFOR AND USE THEREOF 发明人:LI GUOQIANG; LIANG JIEHUI; WANG JUNKUN; GUO JIANSEN; LIU PEIXIN 权利人:UNIV SOUTH CHINA TECH 摘要:Provided are β-cyc-assisted synthesis of an In-V group quantum dot, and a synthesis method therefor and the use thereof. The method for β-cyc-assisted synthesis of an In-V group quantum dot comprises: preparing a β-cyc-containing precursor solution of an In source and a V group element source, and subjecting it to a hydrothermal reaction; extracting a stock solution after the hydrothermal reaction by using an organic solvent; removing β-cyc from the stock solution, washing same with water and then extracting same; and heating and concentrating same to obtain a high-concentration In-V group quantum dot solution. With regard to the β-cyc-assisted synthesis of an In-V group quantum dot, the In-V group quantum dot synthesized with the assistance of β-cyc is prepared by using the method for β-cyc-assisted synthesis of an In-V group quantum dot. The use of β-cyc-assisted synthesis of an In-V group quantum dot is the use of the β-cyc-assisted synthesis of an In-V group quantum dot in the field of photovoltaics, and the field of photovoltaics comprises solar cells, photoelectrochemical hydrogen production and photoelectric detectors. Compared with traditional synthesis methods, this synthesis method has the advantages of green and environmentally friendly raw materials, a simple and safe process, a simple and convenient device, efficient and economic synthesis, and being low cost.
专利号:US-11643387-B2 优先权日:2019-07-18 标题 :Process for the synthesis of urea 发明人:MARRONE LEONARDO; BERTINI PAOLO 权利人:CASALE SA 摘要:A process for synthesis of urea from ammonia and carbon dioxide comprising the synthesis of urea in parallel in a first urea reactor ( 1 ) at a first urea synthesis pressure and in a second urea reactor ( 2 ) at a second and lower urea synthesis pressure; a stripping step of the reaction effluent of the first reactor, which is performed in a stripper ( 4 ) operating at a stripping pressure lower than the first urea synthesis pressure; the reaction effluent ( 21 ) of the second reactor ( 2 ) and the stripper liquid effluent ( 11 ) are sent to a recovery section ( 13 ) where a carbamate-containing recycle solution ( 17 ) is produced, and said recycle solution ( 17 ) is sent partly to said first reactor and partly to said second reactor.
专利号:US-9957239-B2 优先权日:2014-04-28 标题 :Process and plant for the synthesis of urea and melamine 发明人:BERTINI PAOLO; DI CARLO GABRIELE 权利人:CASALE SA 摘要:An integrated process for the synthesis of urea and melamine, wherein: urea is synthesized with a stripping process in a high-pressure synthesis loop comprising a reactor, a stripper and a carbamate condenser, and the urea solution leaving said stripper is sent to a recovery section to produce a concentrated urea product and a recovered carbamate solution; at least part of said urea product is converted to melamine, and the off-gas from the synthesis of melamine are recycled to the urea synthesis by mixing with the gas phase from the stripper and with said recovered carbamate solution, thus forming a mixed flow which is then condensed in said carbamate condenser, and the condensate is eventually directed to the reactor.
专利号:WO-2024188890-A1 优先权日:2023-03-10 标 题:A process and plant for the synthesis of urea and melamine 发明人:MARRONE LEONARDO; GAMBA SIMONE; BENEDETTI ALBERTO 权利人:CASALE SA 摘要:An integrated process for the synthesis of urea and melamine, wherein urea synthesized in a urea plant is used to produce melamine in a melamine plant connected to the urea plant, according to a high-pressure non-catalytic melamine synthesis process, wherein melamine is synthesized at a pressure higher than urea synthesis pressure and offgas liberated during the synthesis of melamine are returned, as a gas, to the high-pressure synthesis section of the urea plant.
专利号:US-2024262798-A1 优先权日:2021-07-09 标 题:A process and plant for the synthesis of urea and melamine 发明人:BERTINI PAOLO; FUMAGALLI MATTEO 权利人:CASALE SA 摘要:A process for the synthesis of urea and melamine, wherein urea synthesized in a urea plant is used to produce melamine in a melamine plant connected to the urea plant, according to a high-pressure non-catalytic melamine synthesis process, and offgas ( 16 ) liberated during the synthesis of melamine are returned to the urea plant after offgas processing ( 8 ) which includes a condensation and a urea formation step so that a urea-containing recycle stream ( 19 ) is returned to the synthesis section of the urea plant.
专利号:US-11666883-B2 优先权日:2018-01-26 标题:Plant for the synthesis of melamine with offgas recovery in a tied-in urea plant 发明人:SCOTTO ANDREA; FUMAGALLI MATTEO 权利人:CASALE SA 摘要:Plant for the synthesis of melamine starting from urea, wherein the stream of offgas containing NH3 and CO2 produced by the synthesis of melamine is converted into urea in a dedicated urea plant.
[参考文献]: Melamine [参考文献]: Ghee Hwan Kim, Et Al. Nephrotoxic Potential And Toxicokinetics Of Melamine Combined With Cyanuric Acid In Rats. J Toxicol Environ Health A. 2014;77(22-24):1346-58. [参考文献]: Honggang Tu, Et Al. Genotoxicity Assessment Of Melamine In The In Vivo Pig-A Mutation Assay And In A Standard Battery Of Assays. Mutat Res Genet Toxicol Environ Mutagen. 2015 Jan 1:777:62-7. [参考文献]: Hwa Jung Noh, Et Al. Melamine Nanosensing With Chondroitin Sulfate-Reduced Gold Nanoparticles. J Nanosci Nanotechnol. 2013 Dec;13(12):8229-38. [参考文献]: Jon Draher, Et Al. Validation Of A Rapid Method Of Analysis Using Ultrahigh-Performance Liquid Chromatography - Tandem Mass Spectrometry For Nitrogen-Rich Adulterants In Nutritional Food Ingredients. J Chromatogr A. 2014 Dec 19:1373:106-13.
合成参考文献
参考文献:10.4103/0974-7796.82171 摘要:Lu X, Wang J, Cao X, Li M, Xiao C, Yasui T, Gao B. Gender and urinary pH affect melamine-associated kidney stone formation risk. Urol Ann. 2011 May;3(2):71–4. 参考文献:10.1107/s1600536811009147 摘要:Wang S, Zhong K. Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate. Acta Crystallogr E Struct Rep Online. 2011 Mar 15;67(4):m446. doi: 10.1107/s1600536811009147. 参考文献:10.1107/s1600536811008488 摘要:Pasdar H, Shakiba S, Aghabozorg H, Notash B. Propane-1,2-diaminium tris(pyridine-2,6-dicarboxylato-κ3O2,N,O6)zirconate(IV) trihydrate. Acta Crystallogr E Struct Rep Online. 2011 Apr 13;67(5):m587. doi: 10.1107/s1600536811008488. 参考文献:10.1107/s1600536811015194 摘要:Yang J, Dai J. Tetrakis(μ-4-tert-butylbenzoato)-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[aqua(4-tert-butylbenzoato-κ2O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)]. Acta Crystallogr E Struct Rep Online. 2011 May 07;67(6):m666–7. doi: 10.1107/s1600536811015194. 参考文献:10.4061/2011/518258 摘要:Calderano SG, de Melo Godoy PD, da Cunha JP, Elias MC. Trypanosome prereplication machinery: a potential new target for an old problem. Enzyme Res. 2011;2011():518258.